Modal metasomatism in the Kaapvaal craton lithosphere: constraints on timing and genesis from U–Pb zircon dating of metasomatized peridotites and MARID-type xenoliths

Modal metasomatism in the Kaapvaal craton lithosphere is well documented in upper mantle xenoliths sampled by both group I (mainly late Cretaceous) and group II (mainly early Cretaceous to late Jurassic) kimberlites in the Kimberley area. The metasomatic style is characterized by introduction of K, H and large ion lithophile/high field strength (LIL/HFS) elements into the lithospheric mantle leading to the crystallization of hydrous potassic phases such as phlogopite and/or K-amphibole. Textures indicate that the hydrous phases either replace pre-existing assemblages in peridotites, forming the metasomatized peridotite suite (phlogopite–K-richterite–peridotites: PKPs) or crystallize from K-rich melts, forming the mica–amphibole–rutile–ilmenite–diopside (MARID) suite of xenoliths. These K-rich assemblages become potential low melting source components for alkaline incompatible trace element enriched magmas. The timing of metasomatism and its temporal and possible genetic relation to kimberlite magmatism is poorly constrained because of the rarity of phases in the metasomatic assemblages suitable for precise dating. Here we present precise sensitive high resolution ion microprobe (SHRIMP) U–Pb formation ages of 88 ± 2 (1σ=1 standard deviation) and 82 ± 3 Ma data for zircons from a K-richterite–phlogopite-bearing metasomatized peridotite (PKP) and a MARID xenolith respectively, sampled by a group I kimberlite. Both average PKP and MARID zircon ages are indistinguishable from emplacement ages of group I kimberlites in the Kimberley area dated at 83 ± 4 (2σ) and 84 ± 0.9 Ma. One exceptionally old age spot of 102 ± 5 Ma from a PKP zircon provides evidence for modal metasomatism predating group I kimberlite emplacement by several millions of years with minor resetting of the U–Pb isotopic system of most analyzed PKP zircons to a group I emplacement age. Detailed textural and mineral chemical analysis, including high energy X-ray mapping and analysis of fluid inclusion daughter crystals, indicates a complex reaction history for both PKPs and MARIDs. U–Pb zircon ages from this study combined with literature data and experimentally derived models for MARID formation are used to suggest that MARID-formation is concurrent and genetically related to both group I and II kimberlite magmatism in the Kimberley area. MARID and PKP zircon ages are also consistent with the idea first proposed by Dawson and Smith (Geochim Cosmochim Acta 41: 309–323, 1977) that metasomatized peridotites may form from interaction of hydrous fluids expelled by solidifying MARID-type melts with peridotitic wall rocks. Received: 13 December 1999 / Accepted: 13 April 2000     

Constraints on Cation Order in Calcium-rich Sedimentary Dolomite

Most sedimentary Ca-rich dolomite in pre-Holocenerocks is known to exhibit a fine-scale modulation inTEM images, reflecting a domain structure of which onecomponent is a low-symmetry variant of dolomite. Thevarious structural models proposed for thelow-symmetry component involve Ca–Mg order patternsthat are different from that in dolomite. Caution istherefore required for interpretation of X-raydiffraction data, which average over the entirestructure. The average structures of two Ca-richdolomites having a structural modulation are refinedusing single-crystal intensity data. The resultsindicate a poor fit using a dolomite model, which isconsistent with the findings from TEM and electrondiffraction indicating that one component of thedomain structure is different than dolomite. Resultsalso indicate that average model A and B cation siteshave mixed Ca–Mg occupancy, which provides someconstraints on possible models for the low-symmetrydomains.     

Climatic and Demographic Consequences of the Massive Volcanic Eruption of 1258

Somewhere in the tropics, a volcanoexploded violently during the year 1258, producing amassive stratospheric aerosol veil that eventuallyblanketed the globe. Arctic and Antarctic ice coressuggest that this was the world's largest volcaniceruption of the past millennium. According tocontemporary chronicles, the stratospheric dry fogpossibly manifested itself in Europe as a persistentlycloudy aspect of the sky and also through anapparently total darkening of the eclipsed Moon. Basedon a sudden temperature drop for several months inEngland, the eruption's initiation date can beinferred to have been probably January 1258. Thefrequent cold and rain that year led to severe cropdamage and famine throughout much of Europe.Pestilence repeatedly broke out in 1258 and 1259; itoccurred also in the Middle East, reportedly there asplague. Another very cold winter followed in1260–1261. The troubled period's wars, famines,pestilences, and earthquakes appear to havecontributed in part to the rise of the Europeanflagellant movement of 1260, one of the most bizarresocial phenomena of the Middle Ages. Analogies can bedrawn with the climatic aftereffects and Europeansocial unrest following another great tropicaleruption, Tambora in 1815. Some generalizations aboutthe climatic impacts of tropical eruptions are madefrom these and other data.     

A Concise History of Dutch River Floods

Based on a brief account of 1,000 years of river floods and flood management in the Dutch Rhine delta, it is argued that vulnerability to river floods depends on the complex interaction of economics, institutions, politics and, to a limited extent, climate. Response functions and thresholds for climate change impacts should take this complexity into account rather than assuming society to be constant or evolving in a straightforward manner.     

Holocene changes in seasonal precipitation highlighted by fire incidence in eastern Canada

Postglacial fire history has been reconstructed for eastern Canada from charcoal-influx anomalies from 30 sites taken from a lacustrine charcoal database. The reconstruction exhibits coherent patterns of fire occurrence in space and time. The early Holocene is characterised by high fire incidence. There is a major change to much lower occurrence slightly after 8 ka BP. A return to more fire appears after 3 ka BP. This sequence does not fit with the hydro-climatic reconstruction deduced from lake level reconstructions for northeastern North America, which indicates a dry early and mid-Holocene, and a wet late-Holocene. Fire occurrence however closely matches summer relative humidity inferred from δ¹⁸O. The differences between fire frequency and lake level history, are due to changes in the seasonality of precipitation and drought frequency. Lake levels are essentially controlled by winter precipitation while summer precipitation controls fire occurrence. The early Holocene before 8–7.5 ka BP experienced dry summers due to higher solar radiation and dry adiabatic winds from the residual Laurentide Ice Sheet. The middle Holocene was dominated by wet summers due to stability of the Atlantic air mass over eastern Canada. After 2.5 ka BP, summers became drier, albeit not as fire-conducive as during the early Holocene. Late-Holocene summers conducive to fire are explained by more frequent incursions of dry Cool Pacific or Cold Arctic air masses over eastern Canada. Received: 25 January 1999 / Accepted: 14 December 1999     

Trophic relationships of three sunfishes (Lepomis spp.) in an estuarine bayou

We examined ontogenetic, interspecific, and seasonal trophic patterns among sympatric sunfish species, redspotted sunfish,Lepomis miniatus; redear sunfish,Lepomis microlophus; and bluegill,Lepomis macrochirus, in an estuarine bayou. In particular we studied these feeding patterns in relation to relative abundances of prey from different benthic feeding habitats. All three sunfishes showed ontogenetic divergence in their trophic niches, reflecting different ecomorphological specializations. Small fishes depended on zooplankton, whereas larger fishes of all three species shifted their diets to benthic macrofauna. A potential for trophic resource partitioning was reflected by dietary differences among the three sunfish species. One impalied mechanism for resource partitioning was feeding habitat, as redear sunfish frequently used sediment-associated prey, while bluegill showed greater use of water-column-associated prey, and redspotted sunfish often used SAV-associated prey. However, all three sunfishes apparently used each feeding habitat to some degree; and, trophic differences were more clearly based on prey type than on feeding habitat. Redear sunfish, which can crush hard-shelled prey, exhibited the most distinctive diet. An apparent seasonal shift in feeding habitat occurred in autumn/winter, as indicated by increased overlap between diets and SAV. This shift was facilitated by changes in the relative abundances of several common prey types between benthic habitats. The relative abuandance and use of freshwater and estuarine-derived prey also varied seasonally, suggesting a possible trophic benefit of consistent prey availability in the estuarine bayou.     

Effects of sediment contaminants and environmental gradients on macrobenthic community trophic structure in Gulf of Mexico estuaries

Macrobenthic communities from estuaries throughout the northern Gulf of Mexico were studied to assess the influence of sediment contaminants and natural environmental factors on macrobenthic community trophic structure. Community trophic data were also used to evaluate whether results from laboratory sediment toxicity tests were effective indicators of site-specific differences in benthic trophic structure. A multiple regression model consisting of five composite factors (principal components) was used to distinguish the effects of sediment contaminants and environmental variables on benthic community trophic structure. This model explained 33.5% of the variation in macrobenthic trophic diversity (p<0.001), a variable derived from the distribution of taxas among nine original trophic categories. A significant negative relatinship was found between principal components reflecting concentrations of sediment contaminants and macrobenthic trophic diversity. Detritivores including surface deposit-feeders (SDF), subsurface deposit-feeders (SSDF), and filter feeders (FF) were numerically dominant at 201 random sites, each group accounting for 25–30% of total macrobenthic abundance. The relative abundance of SDFs was considerably lower (12.1±2.9% to 17.1±4.4%) at sites where sediment contaminant concentrations exceeded minimum biological effects thresholds (ER-L values from Long and Morgan 1990 than at sites sampled at random (29.3±5.7%). SSDFs were proportionally more abundant at contaminated sites (42.0±7.7% to 63.6±10.3%) versus random sites (27.5±5.7%), and the relative abundance of SSDFs was positively correlated with concentrations of particular contaminants. Benthic trophic structure was also found to be a function of salinity, where the proportion of SSDFs was negatively correlated with salinity (p=0.035, r=−0.223, n=326). Silt-clay content loaded fairly strongly on the first principal component, but trophic structure parameters were not significantly correlated with sediment grain size or dissolved oxygen (perhaps due, in part, to covariation). Results from laboratory sediment toxicity tests with mysids were predictive of differences in macrobenthic trophic structure in situ (i.e., mysid survival was negatively correlated with %SSDF; p<0.001, r=−0.292, n=326). Results from laboratory sediment toxicity tests with ampeliscid amphipods were not indicative of site-specific differences in benthic trophic structure.