Structural chemistry of synthetic cordierite: Evidence for solid solutions and disordered compositional domains in Bi-flux-grown Mg-cordierites

The structure, crystal chemistry, and microstructure of disordered and ordered Mg-cordierites synthesized in a bismuth oxide flux system have been studied by a combination of x-ray and neutron powder diffraction and quantitative x-ray microanalysis using analytical electron microscopy. Microchemical data obtained on Bi-flux cordierites using energy-dispersive x-ray analysis is interpreted through comparison with data collected on stoichiometric Mg₂Al₄Si₅O₁₈ glass and α- and β-cordierite samples synthesized by subsolidus crystallization of the glass. Bi-flux cordierites crystallize in both the hexagonal and orthorhombic polymorphs and contain 5 to 10 at% occupancy of bismuth on the C1 and C2 channel sites. The microstructure of Bi-flux α-cordierite is characterized by the existence of local domains of disordered cordierite solid solutions with variable composition and significant vacancy concentrations on the octahedral site. The β-cordierites have a more homogeneous microstructure but are still Al-deficient, Si-rich solid solutions.     

Isotopic partitioning between scallop shell calcite and seawater: effect of shell growth rate

The relationship between molluscan shell growth rate and skeletal δ¹⁸O and δ¹³C was investigated in a detailed field study for the scallop, Pecten maximus. Seasonal variation in shell growth rate was found to be a governing factor influencing shell δ¹⁸O and δ¹³C. At low shell growth rates, shell δ¹⁸O were more positive (of the order +0.4‰) and δ¹³C more negative (up to −2‰) as compared with predicted values for precipitation of inorganic calcite in isotopic equilibrium with seawater. The deviations in δ¹⁸O were hypothesized as reflecting possible differences in solution carbonate chemistry at the site of mineralization in the extrapallial fluid as compared with that of the external seawater medium. The deviations in shell δ¹³C were consistent with incorporation of isotopically depleted respiratory ¹³C (i.e., a metabolic effect). A trend toward more depleted shell δ¹⁸O and δ¹³C values occurred at higher shell growth rates, with negative δ¹⁸O values as compared with predicted equilibrium at shell growth rates above 0.13 mm per day. These simultaneous negative deviations in skeletal δ¹⁸O and δ¹³C were interpreted as resulting from a kinetic effect. The implications for environmental reconstruction from molluscan isotopic records are discussed in light of a model of isotopic behavior based on the findings of the study.     

Flux and dispersion of gases from the “Drachenschlund” hydrothermal vent at 8°18' S, 13°30' W on the Mid-Atlantic Ridge

Hydrothermal emission of mantle helium appears to be directly related to magma production rate, but other processes can generate methane and hydrogen on mid-ocean ridges. In an on-going effort to characterize these processes in the South Atlantic, the flux and distribution of these gases were investigated in the vicinity of a powerful black smoker recently discovered at 8°17.9' S, 13°30.4' W. The vent lies on the shoulder of an oblique offset in the Mid-Atlantic Ridge and discharges high concentrations of methane and hydrogen. Measurements during expeditions in 2004 and 2006 show that the ratio of CH₄ to ³He in the neutrally buoyant plume is quite high, 4 × 10⁸. The CTD stations were accompanied by velocity measurements with lowered acoustic Doppler current profilers (LADCP), and from these data we estimate the methane transport to have been 0.5 mol s^− 1 in a WSW-trending plume that seems to develop during the ebb tidal phase. This transport is an order of magnitude greater than the source of CH₄ calculated from its concentration in the vent fluid and the rise height of the plume. From this range of methane fluxes, the source of ³He is estimated to be between 0.14 and 1.2 nmol s^− 1. In either case, the ³He source is significantly lower than expected from the spreading rate of the Mid-Atlantic Ridge. From the inventory of methane in the rift valley adjacent to the vent, it appears that the average specific rate of oxidation is 2.6 to 23 yr^− 1, corresponding to a turnover time between 140 and 16 days. Vertical profiles of methane in the surrounding region often exhibited Gaussian-like distributions, and the variances appear to increase with distance from the vent. Using a Gaussian plume model, we obtained a range of vertical eddy diffusivities between 0.009 and 0.08 m²m² s^− 1. These high values may be due to tidally driven internal waves across the promontory on which the vent is located.     

Origins and evolution of rhyolitic magmas in the central Snake River Plain: insights from coupled high-precision geochronology,oxygen isotope,and hafnium isotope analyses of zircon

We present new high-precision CA-ID-TIMS and in situ U–Pb ages together with Hf and O isotopic analyses (analyses performed all on the same grains) from four tuffs from the 15?10 Ma Bruneau–Jarbidge center of the Snake River Plain and from three rhyolitic units from the Kimberly borehole in the neighboring 10?6 Ma Twin Falls volcanic center. We find significant intrasample diversity in zircon ages (ranges of up to 3 Myr) and in δ¹⁸O (ranges of up to 6‰) and ε_Hf (ranges of up to 24 ε units) values. Zircon rims are also more homogeneous than the associated cores, and we show that zircon rim growth occurs faster than the resolution of in situ dating techniques. CA-ID-TIMS dating of a subset of zircon grains from the Twin Falls samples reveals complex crystallization histories spanning 10⁴–10⁶ years prior to some eruptions, suggesting that magma genesis was characterized by the cyclic remelting of buried volcanic rocks and intrusions associated with previous magmatic episodes. Age-dependent trends in zircon isotopic compositions show that rhyolite production in the Yellowstone hotspot track is driven by the mixing of mantle-derived melts (normal δ¹⁸O and ε_Hf) and a combination of Precambrian basement rock (normal δ¹⁸O and ε_Hf down to ??60) and shallow Mesozoic and Cenozoic age rocks, some of which are hydrothermally altered (to low δ¹⁸O values) by earlier stages of Snake River Plain magmatism. These crustal melts hybridize with juvenile basalts and rhyolites to produce the erupted rhyolites. We also observe that the Precambrian basement rock is only an important component in the erupted magmas in the first eruption at each caldera center, suggesting that the accumulation of new intrusions quickly builds an upper crustal intrusive body which is isolated from the Precambrian basement and evolves towards more isotopically juvenile and lower-δ¹⁸O compositions over time.     

Initial results and progress of the Mississippi delta sediment pore water pressure experiment

Abstract

This report describes the instrumentation, initial results, and progress of an experiment designed to measure and monitor submarine sediment pore water and hydrostatic pressures in a selected area of the Mississippi Delta. The experiment also is intended to monitor significant pressure perturbations during active storm periods. Initial analysis of the data revealed excess pore water pressures in the silty clay sediment at selected depths below the mudline. Continuous monitoring of the pore water and hydrostatic pressures was expected to reveal important information regarding sediment pore water pressure variations as a function of the geological processes active in the Mississippi Delta.     

Volcanic geology and eruption frequency,lower east rift zone of Kilauea volcano,Hawaii

Detailed geologic mapping and radiocarbon dating of tholeiitic basalts covering about 275 km² on the lower east rift zone (LERZ) and adjoining flanks of Kilauea volcano, Hawaii, show that at least 112 separate eruptions have occurred during the past 2360 years. Eruptive products include spatter ramparts and cones, a shield, two extensive lithic-rich tuff deposits, aa and pahoehoe flows, and three littoral cones. Areal coverage, number of eruptions and average dormant interval estimates in years for the five age groups assigned are: (I) historic, i.e. A D 1790 and younger: 25%, 5, 42.75; (II) 200–400 years old: 50%, 15, 14.3: (III) 400–750 years old: 20%, 54, 6.6; (IV) 750–1500 years old: 5%, 37, 20.8; (V) 1500–3000 years old: <1%, 1, unknown. At least 4.5–6 km³ of tholeiitic basalt have been erupted from the LERZ during the past 1500 years. Estimated volumes of the exposed products of individual eruptions range from a few tens of cubic meters for older units in small kipukas to as much as 0.4 km³ for the heiheiahulu shield. The average dormant interval has been about 13.6 years during the past 1500 years. The most recent eruption occurred in 1961, and the area may be overdue for its next eruption. However, eruptive activity will not resume on the LERZ until either the dike feeding the current eruption on the middle east rift zone extends farther down rift, or a new dike, unrelated to the current eruption, extends into the LERZ.     

THE NEW INTERNATIONAL DIVISION OF LABOR AND DEBT CRISIS IN THE THIRD WORLD

The advanced capitalist ccuntries are undergoing an industrial devolution as remarkable as the industrial revolution of the nineteenth century. The removal of high-paying jobs through automation and geographical migration destroys the main market of the center and precipitates debt crises in newly industrialized countries of the periphery which have followed export-oriented growth policies. This results in a new, internationalized form of the crises of iate capitalism and provides a new institutional foucs for crisis in the international banks. The paper examines this global process from the perspective of the geography of class struggle.     

Regional variation in springtime ichthyoplankton assemblages in the northeast Pacific Ocean

The coastal regions of the northeast Pacific support large, economically valuable fishery resources and provide nursery areas for many fish species. Over the last few decades, there have been dramatic shifts in species abundance and composition in this area. In this paper, we examine the springtime spatial patterns in the ichthyoplankton of three oceanographically different regions, the Southeast Bering Sea, the Gulf of Alaska and the U.S. West Coast. The data examined are a subset of a larger database (comprising data from cruises conducted from 1972 to 1997) that is being used to investigate spatial, seasonal and interannual patterns in ichthyoplankton of the northeast Pacific in relation to environmental conditions. Ichthyoplankton were collected during seven cruises using 60-cm bongo nets. Spatial patterns of ichthyoplankton were examined using both classification and ordination techniques. Relative Bray-Curtis dissimilarity coefficients calculated from the log₁₀ (n+1) of abundance data were used as input to the numerical classification of species and stations. Nonmetric multidimensional scaling was also applied to the abundance data to examine geometric patterns in the data. The numerical analyses of the species abundance data sets for each cruise revealed spatial patterns in the ichthyoplankton that suggest the occurrence of geographically distinct assemblages of fish larvae in each region. For all three sampling regions, the assemblage structure is primarily related to bathymetry, and Shelf, Slope, and Deep-Water assemblages are described. This shallow to deep-water gradient in species occurrence and abundance reflects the habitat preference and spawning location of the adult fish. Another degree of complexity is superimposed on this primary assemblage structure in each region and seems to be related to local topography and the prevailing current patterns. The patterns in ichthyoplankton assemblages of the three regions in the northeast Pacific Ocean described here form the basis for future investigations of spatial and temporal patterns in the ichthyoplankton of the subarctic Pacific.Regional Index Terms: Northeast Pacific Ocean, Southeast Bering Sea, Gulf of Alaska, U.S. West Coast.     

Sedimentary processes and trace metal contaminants in the buccaneer oil/gas field,northwestern gulf of Mexico

Sediments are the ultimate sink for contaminants in the marine environment, and physical processes of sedimentation influence the distribution and accumulation of these contaminants. Evaluation of contaminant levels in sediments is one approach to assessing environmental impact; data interpretation depends on consideration of sediment texture and mineralogy, however, which profoundly influence chemical composition. In this study, comparison of potentially contaminated sediments from the production field with control populations was done only within the context of similar (as to texture and organic carbon and carbonate content) sample groups as determined by cluster analysis. Ba, Cd, and Sr are identified as contaminants. Supported by the identification of a well-crystallized expandable clay—possibly bentonite—drilling fluids are a potential source of Ba. Ba and Sr may be unnaturally high because of their abundance in discharged produced formation waters, but may also be naturally controlled by the unique faunal assemblage associated with the structures. Cd is probably derived from corrosion of the structures and assorted debris on the seafloor. In general, contamination is limited to an area within 100 m of the platforms. Furthermore, substantial erosion around platforms has probably effectively removed and dispersed the bulk of the contaminants introduced into the marine environment by the offshore exploration/production operations.     

Morphology and Histology of Lattice-like Ossified Epaxial Tendons in Psittacosaurus (Dinosauria: Ceratopsia)

<正>Epaxial tendons play an important role in the study of the musculoskeletal system and locomotory style of dinosaurs.Although the ossified epaxial tendon lattice is fairly well known in Iguanodontoidea,only recently has knowledge of this complex been extended to ceratopsians.This study concerns the gross morphology and microstructure of the tendon lattice in Psittacosaurus,a basal ceratopsian.As in the neoceratopsian Chasmosaurus,the ossified tendons of Psittacosaurus form a three-layered, lattice-like structure.The microstructure of the tendons in large psittacosaur individuals retains an early stage of ossification,as in juvenile birds and nestling hadrosaurs,suggesting a slow developmental rate of ossification of the tendons in psittacosaur ontogeny.Comparative study indicates that a lattice-like arrangement of three-layered epaxial tendons is widely distributed in Cerapoda.This pattern also extends to Ankylosauria,implying a similar pattern of the epaxial muscles through the ornithischian clade.In addition,comparison with crocodiles implies that the different morphology of ossified tendons in dinosaurs may be associated with adaptive aspects of their paleobiology,not simply a side effect of skeletal ossification.In contrast to the short tendons in quadrupedal Chasmosaurus and Protoceratops,the elongated tendons in Psittacosaurus may be related to the bipedal locomotion characteristic of this taxon.