Natural Gradient Tracer Test to Evaluate Natural Attenuation of MTBE Under Anaerobic Conditions

A natural gradient tracer test using perdeuterated MTBE was conducted in an anaerobic aquifer to determine the relative importance of dispersion and degradation in reducing MTBE concentrations in ground water. Preliminary ground water chemistry and hydraulic conductivity data were used to place the tracer within an existing dissolved MTBE plume at Port Hueneme, California. Following one year of transport, the tracer plume was characterized in detail.
Longitudinal dispersion was identified as the dominant mechanism for lowering the perdeuterated MTBE concentrations. The method of moments was used to determine the longitudinal and lateral dispersion coefficients (0.85 m²/day and 0.08 m²/day, respectively). A mass-balance analysis, carried out after one year of transport, accounted for 110% of the injected mass and indicated that no significant mass loss occurred. The plume structure created by zones of higher and lower hydraulic conductivity at the site was complex, consisting of several localized areas of high tracer concentration in a lower concentration plume. This is important because the aquifer has generally been characterized as exhibiting fairly minor heterogeneity. In addition, the tracer plume followed a curved flowpath that deviated from the more macroscopic direction of ground water flow inferred from local ground water elevation measurements and the behavior of the existing plume. Understanding the mass balance, plume structure, curvature of the tracer plume, and consequently natural attenuation behavior required the detailed sampling approach employed in this study. These data imply that a detailed understanding of site hydrogeology and an extensive sampling network may be critical for the correct interpretation of monitored natural attenuation of MTBE.     

Post-Miocene stratigraphy and depositional environments of valley-fill sequences at the mouth of Tampa Bay, Florida

Post-Miocene sea-level low stands allowed rivers and karst processes to incise the exposed carbonate platform along the Gulf Coast of Florida. Few Miocene to mid-Pleistocene deposits survived erosion along the present coast except within incised valleys. Since their formation, these valleys have been filled and incised multiple times in response to sea-level changes. The thick sedimentary sequences underlying the mouth of Tampa Bay have been recorded as a range of depositional environments and multiple sea-level incursions and excursions during pre-Holocene time and subsequent to the accumulation of the Miocene carbonate sequences. Sediment analysis of cores collected from a north–south transect across the mouth of Tampa Bay has enabled the identification of lithofacies, ranging from well-sorted, quartz sand to dense, fossiliferous, phosphatic grainstone. These facies were deposited in freshwater, estuarine, and shallow, open marine environments. As a result of channel development and migration within the paleovalley, and cut-and-fill associated with individual transgressions and regressions, correlation of the lithofacies does not extend across the entire transect. Fining-upward sequences truncated by tidal ravinement surfaces that extend throughout the paleovalley can, however, be identified. Age determinations based on 14-C analysis, amino-acid racemization, and strontium isotope analysis dating of numerous samples yield ages of Miocene, Pliocene, early Pleistocene, and late Pleistocene, as well as Holocene for sequences that accumulated and were preserved in this valley-fill complex. Numerous inconsistencies in the stratigraphic organization of the age determinations indicate that there are bad dates, considerable reworking of shells that were dated, or both. For this reason as well as the lack of detailed correlation among the three relatively complete cores, it is not possible to place these strata in a sequence stratigraphic framework.     

Modeling diffusion advection in the mass transfer of water vapor through martian regolith

Diffusion advection is an effect in diffusive multicomponent mass transfer that occurs when the flux vectors of the individual components do not add up to zero. This can be a significant effect for the mass transfer of water vapor from subsurface ice or liquid reservoirs through porous regolith at martian temperatures and pressures. Ignoring diffusion advection and using Fick's law alone to calculate the flux under these conditions will result in an erroneously small value while using a measured flux to calculate a diffusivity will result in an erroneously high value. The inaccuracy in both cases increases with temperature. The literature contains several examples of erroneous treatment of this effect. The correct approach is well-known from other applications of mass transfer and takes diffusion advection into account in the appropriate amount regardless of the temperature and pressure and reduces to the simple Fick's law when conditions warrant. In this way, there is no need to decide under what conditions diffusion advection is or is not important. It can be used in the transition region to pure Knudsen diffusion in a fashion similar to that used with the more limited Fickian approach.     

Mapping nonlinear shallow-water tides: a look at the past and future

Overtides and compound tides are generated by nonlinear mechanisms operative primarily in shallow waters. Their presence complicates tidal analysis owing to the multitude of new constituents and their possible frequency overlap with astronomical tides. The science of nonlinear tides was greatly advanced by the pioneering researches of Christian Le Provost who employed analytical theory, physical modeling, and numerical modeling in many extensive studies, especially of the tides of the English Channel. Le Provost’s complementary work with satellite altimetry motivates our attempts to merge these two interests. After a brief review, we describe initial steps toward the assimilation of altimetry into models of nonlinear tides via generalized inverse methods. A series of barotropic inverse solutions is computed for the M tide over the northwest European Shelf. Future applications of altimetry to regions with fewer in situ measurements will require improved understanding of error covariance models because these control the tradeoffs between fitting hydrodynamics and data, a delicate issue in coastal regions. While M can now be robustly determined along the Topex/Poseidon satellite ground tracks, many other compound tides face serious aliasing problems. In memory of Christian Le Provost     

Catastrophic middle Pleistocene jökulhlaups in the upper Susquehanna River: Distinctive landforms from breakout floods in the central Appalachians

Widespread till and moraines record excursions of middle-Pleistocene ice that flowed up-slope into several watersheds of the Valley and Ridge Province along the West Branch of the Susquehanna River. A unique landform assemblage was created by ice-damming and jökulhlaups emanating from high gradient mountain watersheds. This combination of topography formed by multiple eastward-plunging anticlinal ridges, and the upvalley advance of glaciers resulted in an ideal geomorphic condition for the formation of temporary ice-dammed lakes. Extensive low gradient (1°–2° slope) gravel surfaces dominate the mountain front geomorphology in this region and defy simple explanation. The geomorphic circumstances that occurred in tributaries to the West Branch Susquehanna River during middle Pleistocene glaciation are extremely rare and may be unique in the world. Failure of ice dams released sediment-rich water from lakes, entraining cobbles and boulders, and depositing them in elongated debris fans extending up to 9 km downstream from their mountain-front breakout points. Poorly developed imbrication is rare, but occasionally present in matrix-supported sediments resembling debris flow deposits. Clast weathering and soils are consistent with a middle Pleistocene age for the most recent flows, circa the 880-ka paleomagnetic date for glacial lake sediments north of the region on the West Branch Susquehanna River. Post-glacial stream incision has focused along the margins of fan surfaces, resulting in topographic inversion, leaving bouldery jökulhlaup surfaces up to 15 m above Holocene channels. Because of their coarse nature and high water tables, jökulhlaup surfaces are generally forested in contrast to agricultural land use in the valleys and, thus, are readily apparent from orbital imagery.     

Dissolved nitrous oxide (N2O) dynamics in agricultural field drains and headwater streams in an intensive arable catchment

Indirect nitrous oxide (N₂O) emissions produced by nitrogen (N) leaching into surface water and groundwater bodies are poorly understood in comparison to direct N₂O emissions from soils. In this study, dissolved N₂O concentrations were measured weekly in both lowland headwater streams and subsurface agricultural field drain discharges over a 2‐year period (2013–2015) in an intensive arable catchment, Norfolk, UK. All field drain and stream water samples were found to have dissolved N₂O concentrations higher than the water–air equilibrium concentration, illustrating that all sites were acting as a net source of N₂O emissions to the atmosphere. Soil texture was found to significantly influence field drain N₂O dynamics, with mean concentrations from drains in clay loam soils (5.3 μg N L^?1) being greater than drains in sandy loam soils (4.0 μg N L^?1). Soil texture also impacted upon the relationships between field drain N₂O concentrations and other water quality parameters (pH, flow rate, and nitrate (NO₃) and nitrite (NO₂) concentrations), highlighting possible differences in N₂O production mechanisms in different soil types. Catchment antecedent moisture conditions influenced the storm event mobilisation of N₂O in both field drains and streams, with the greatest concentration increases recorded during precipitation events preceded by prolonged wet conditions. N₂O concentrations also varied seasonally, with the lowest mean concentrations typically occurring during the summer months (JJA). Nitrogen fertiliser application rates and different soil inversion regimes were found to have no effect on dissolved N₂O concentrations, whereas higher N₂O concentrations recorded in field drains under a winter cover crop compared to fallow fields revealed cover crops are an ineffective greenhouse gas emission mitigation strategy. Overall, this study highlights the complex interactions governing the dynamics of dissolved N₂O concentrations in field drains and headwater streams in a lowland intensive agricultural catchment.     

The Neogene and Quaternary of England: landscape evolution,tectonics, climate change and their expression in the geological record

During the Neogene and Quaternary, tectonic and climatic processes have had a profound impact upon landscape evolution in England and, perhaps as far back as 0.9 Ma, patterns of early human occupation. Until the Late Miocene, large-scale plate tectonic processes were the principal drivers of landscape evolution causing localised basin inversion and widespread exhumation. This drove, in places, the erosion of several kilometres of Mesozoic cover rocks and the development of a regional unconformity across England and the North Sea Basin. By the Pliocene, the relative influence of tectonics on landscape evolution waned as the background tectonic stress regime evolved and climatic influences became more prominent. Global-scale climate-forcing increased step-wise during the Plio-Pleistocene amplifying erosional and depositional processes that operated within the landscape. These processes caused differential unloading (uplift) and loading (subsidence) of the crust (‘denudational isostasy’) in areas undergoing net erosion (upland areas and slopes) and deposition (basins). Denudational isostasy amplified during the Mid-Pleistocene Transition (c.0.9 Ma) as landscapes become progressively synchronised to large-scale 100 ka ‘eccentricity’ climate forcing. Over the past 0.5 Ma, this has led to the establishment of a robust climate record of individual glacial/interglacial cycles enabling comparison to other regional and global records. During the Last Glacial-Interglacial Transition and early Holocene (c.16–7 ka), evidence for more abrupt (millennial/centennial) scale climatic events has been discovered. This indicates that superimposed upon the longer-term pattern of landscape evolution is a more dynamic response of the landscape to local and regional drivers.     

Isotopic partitioning between scallop shell calcite and seawater: effect of shell growth rate

The relationship between molluscan shell growth rate and skeletal δ¹⁸O and δ¹³C was investigated in a detailed field study for the scallop, Pecten maximus. Seasonal variation in shell growth rate was found to be a governing factor influencing shell δ¹⁸O and δ¹³C. At low shell growth rates, shell δ¹⁸O were more positive (of the order +0.4‰) and δ¹³C more negative (up to −2‰) as compared with predicted values for precipitation of inorganic calcite in isotopic equilibrium with seawater. The deviations in δ¹⁸O were hypothesized as reflecting possible differences in solution carbonate chemistry at the site of mineralization in the extrapallial fluid as compared with that of the external seawater medium. The deviations in shell δ¹³C were consistent with incorporation of isotopically depleted respiratory ¹³C (i.e., a metabolic effect). A trend toward more depleted shell δ¹⁸O and δ¹³C values occurred at higher shell growth rates, with negative δ¹⁸O values as compared with predicted equilibrium at shell growth rates above 0.13 mm per day. These simultaneous negative deviations in skeletal δ¹⁸O and δ¹³C were interpreted as resulting from a kinetic effect. The implications for environmental reconstruction from molluscan isotopic records are discussed in light of a model of isotopic behavior based on the findings of the study.     

THE NEW INTERNATIONAL DIVISION OF LABOR AND DEBT CRISIS IN THE THIRD WORLD

The advanced capitalist ccuntries are undergoing an industrial devolution as remarkable as the industrial revolution of the nineteenth century. The removal of high-paying jobs through automation and geographical migration destroys the main market of the center and precipitates debt crises in newly industrialized countries of the periphery which have followed export-oriented growth policies. This results in a new, internationalized form of the crises of iate capitalism and provides a new institutional foucs for crisis in the international banks. The paper examines this global process from the perspective of the geography of class struggle.     

Regional variation in springtime ichthyoplankton assemblages in the northeast Pacific Ocean

The coastal regions of the northeast Pacific support large, economically valuable fishery resources and provide nursery areas for many fish species. Over the last few decades, there have been dramatic shifts in species abundance and composition in this area. In this paper, we examine the springtime spatial patterns in the ichthyoplankton of three oceanographically different regions, the Southeast Bering Sea, the Gulf of Alaska and the U.S. West Coast. The data examined are a subset of a larger database (comprising data from cruises conducted from 1972 to 1997) that is being used to investigate spatial, seasonal and interannual patterns in ichthyoplankton of the northeast Pacific in relation to environmental conditions. Ichthyoplankton were collected during seven cruises using 60-cm bongo nets. Spatial patterns of ichthyoplankton were examined using both classification and ordination techniques. Relative Bray-Curtis dissimilarity coefficients calculated from the log₁₀ (n+1) of abundance data were used as input to the numerical classification of species and stations. Nonmetric multidimensional scaling was also applied to the abundance data to examine geometric patterns in the data. The numerical analyses of the species abundance data sets for each cruise revealed spatial patterns in the ichthyoplankton that suggest the occurrence of geographically distinct assemblages of fish larvae in each region. For all three sampling regions, the assemblage structure is primarily related to bathymetry, and Shelf, Slope, and Deep-Water assemblages are described. This shallow to deep-water gradient in species occurrence and abundance reflects the habitat preference and spawning location of the adult fish. Another degree of complexity is superimposed on this primary assemblage structure in each region and seems to be related to local topography and the prevailing current patterns. The patterns in ichthyoplankton assemblages of the three regions in the northeast Pacific Ocean described here form the basis for future investigations of spatial and temporal patterns in the ichthyoplankton of the subarctic Pacific.Regional Index Terms: Northeast Pacific Ocean, Southeast Bering Sea, Gulf of Alaska, U.S. West Coast.