Variability of surface roughness and turbulence intensities at a coastal site in India

Surface-layer features with different prevailing wind directions for two distinct seasons (Southwest Monsoon and Northeast Monsoon) on the west coast of India are studied using data obtained from tower-based sensors at a site located about 500 m from the coast. Only daytime runs have been used for the present analysis. The surface boundary-layer fluxes have been estimated using the eddy correlation method. The surface roughnessz ₀ obtained using the stability-corrected wind profiles (Paulson, 1970) has been found to be low for the Southwest monsson season. For the other season,z ₀ is relatively high. The drag coefficientC _D varies with height in the NE monsoon season but not in the season with lowz ₀. This aspect is reflected in the wind profiles for the two seasons and is discussed in detail. The scaling behaviour of friction velocityu _* and the turbulence intensity of longitudinal, lateral and vertical winds _u, _v and _w, respectively) are further examined to study their dependence on fetch. Our study shows that for the non-dimensional case, _u/u_* and _v/u_* do not show any surface roughness dependence in either season. On the other hand, for _w/u_* for the season with lowz ₀, the values are seen to agree well with that of Panofskyet al. (1977) for homogeneous terrain whereas for the other season with highz ₀, the results seem to conform more to the values observed by Smedman and Högström (1983) for coastal terrain. The results are discussed in the light of observations by other investigators.     

Mixed-layer characteristics as related to the monsoon climate of New Delhi,India

Annual variations of mixed-layer characteristics at New Delhi, India have been studied for a weak monsoon (1987) and a strong monsoon (1988) year. In the weak monsoon year (1987), the maximum mixing depthh _max was found to have a value of around 3000 m during the pre-monsoon, less than 2000 m during the summer monsoon, around 2000 m during the post-monsoon, and less than 1000 m in the winter season. For the strong monsoon year (1988),h _max values were less than 1987 values for comparable periods throughout the year. The seasonal and yearly differences ofh _max were explained by the surface energy balance and potential temperature gradient at a time close to sunrise. According to the spatial patterns of obtained by an objective analysis of the 850 to 700 hPa layers. mixed-layer characteristics obtained at New Delhi are representative of the north and central regions of India.     

Sediment oxygen profiles in a super-oxygenated antarctic lake

Perennially ice-covered lakes are found in the McMurdo Dry Valleys of southern Victoria Land, Antarctica. In contrast to temperate lakes that have diurnal photic periods, antarctic (and arctic) lakes have a yearly photic period. An unusual feature of the antarctic lakes is the occurrence of O2 at supersaturated levels in certain portions of the water column. Here we report the first sediment O2 profiles obtained using a microelectrode from a perennially ice-covered antarctic lake. Sediment cores collected in January and October 1987 from Lake Hoare in Taylor Valley show oxygenation down to 15, and in some cases, 25 cm. The oxygenation of sediments several centimeters below the sediment-water interface is atypical for lake sediments and may be characteristic of perennially ice-covered lakes. There is a significant difference between the observed January and October sediment O2 profiles. Several explanations may account for the difference, including seasonality. A time-dependent model is presented which tests the feasibility of a seasonal cycle resulting from the long photoperiod and benthic primary production in sediments overlain by a highly oxygenated water column.     

Pore pressure profiles in fractured and compliant rocks1

Fluid permeability in fractured rocks is sensitive to pore-pressure changes. This dependence can have large effects on the flow of fluids through rocks. We define the permeability compliance γ= 1/k(k/δp_p)_pc, which is the sensitivity of the permeability k to the pore pressure p_p at a constant confining pressure p_c, and solve the specific problems of constant pressure at the boundary of a half-space, a cylindrical cavity and a spherical cavity. The results show that when the magnitude of permeability compliance is large relative to other compliances, diffusion is masked by a piston-like pressure profile. We expect this phenomenon to occur in highly fractured and compliant rock systems where γ may be large. The pressure profile moves rapidly when fluids are pumped into the rock and very slowly when fluids are pumped out. Consequently, fluid pressure, its history and distribution around injection and production wells may be significantly different from pressures predicted by the linear diffusion equation. The propagation speed of the pressure profile, marked by the point where δp_p/δx is a maximum, decreases with time approximately as and the amplitude of the profile also dissipates with time (or distance). The effect of permeability compliance can be important for fluid injection into and withdrawal from reservoirs. For example, excessive drawdown could cause near-wellbore flow suffocation. Also, estimates of the storage capacity of reservoirs may be greatly modified when γ is large. The large near-wellbore pressure gradients caused during withdrawal by large γ can cause sanding and wellbore collapse due to excessive production rates.     

Radiocarbon redating of contaminated samples from a tropical volcano: the Mansion ‘Series’ of St Kitts,West Indies

Heavy rainfall and dense vegetation on tropical volcanoes produce abundant carbonized wood in pyroclastic deposits, in addition to easy contamination of this wood by root systems and soluble humic material. Because the physical nature of the charcoal varies, some samples are more prone to contamination. Two independent studies of the same volcano, Mt Liamuiga on St Kitts in the Lesser Antilles, sometimes using samples from the same carbonized tree, yielded a systematic difference in radiocarbon ages. An exchange of samples and a re-investigation of three physically distinct types of charcoal yielded the following results. Rare, hard, dense charcoal, lacking contamination, which had yielded a spurious age of 2860 years bp, was redated at 1845±58 years bp. Common soft, friable charcoal with good cellular structure proved to be susceptible to contamination. A field decontamination technique utilized by one group seems significant as it yields older ages than when only routine laboratory pre-treatment was used, indicating that the latter technique only partly removes the dried and hard residue produced by the decomposition of modern plant rootlets. A previous date of 24870 years bp obtained from powdery charcoal in a horizon beneath the Mansion Series contradicted ages older than 41000 years bp from common friable charcoal in the lower Mansion Series. The soft powdery charcoal was re-investigated using a sample collected a few centimeters from the original, although field decontamination of this sample was not possible, more extensive laboratory treatment yielded an age of ca. 43000 years bp, again proving that routine laboratory pretreatments are inadequate. A revised geochronology for the Mansion Series is described and a cautionary discussion is presented for the benefit of investigators using radiocarbon ages to date volcanic deposits.     

An assessment of field evidence for ‘Byerlee’ friction

Structural analyses of the angles of frictional lock-up for fault sets that have become progressively misoriented, together with field observations from seismology, geomorphology, and borehole stress measurements, suggest that Byerlee friction coefficients (0.6<<0.85) are widely applicable to natural sliding surfaces with displacements of up to a few kilometres in the upper crust, from the surface of the earth to seismogenic depths. Extensional normal faults operating under presumed vertical trajectories of extreme compressive stress provide some of the best evidence for frictional lock-up followed by the initiation of new favorably oriented faults, but similar lock-up phenomena also occur in thrust and strike-slip fault systems.However, extensional detachments which appear to have formed and remained active at very low dips (<15°) lie well outside the dip range of currently active normal faults, requiring stress trajectories that deviate significantly from the vertical and horizontal during their initiation and perhaps also during their continued reactivation. Other conspicuous exceptions to the pattern of frictional lock-up expected from Byerlee friction are major transform structures, such as the San Andreas fault in California, which remain active though oriented at high angles to the maximum principal compression. On the basis of the evidence afforded by the lower displacement faults, the apparent weakness of such structures seems most likely to arise from locally elevated fluid pressure, rather than from the presence of anomalously low-friction material within the fault zones.     

Dynamics of the plasmasphere in the dusk sector as observed in the outer ionosphere

Summary Direct measurements of the thermal plasma parameters in the topside ionosphere reveal variations of the plasmasphere boundary in the dusk sector. The ACTIVE satellite's near-polar orbits at altitudes of 500 – 1800 km around winter solstice 1989 were used to study the bulge region of the plasmasphere during intervals with different levels of geomagnetic agitation. The narrow, sharply defined trough in electron concentration corresponding to the plasmapause under quiet conditions situated at L = 6 – 7 moved to lower L-values with increasing geomagnetic activity. This narrow trough can be found in all main ion constituents. During periods of moderate geomagnetic activity, following the onset of a weak magnetic storm, a portion of the plasmaspheric bulge region was separated from the main plasmaspheric body. This can be seen in the outer ionosphere as an inner narrow trough at lower L-value. Troughs in light ions need no longer coincide with this in electron concentration. He⁺ is the most sensitive constituent reflecting the dusk sector plasmaspheric situation at this altitude.Dedicated to the Memory of Professor Karel P     

Blind prediction of the site effects at Ashigara Valley,Japan, and its comparison with reality

Weak and strong ground motions were numerically predicted for three stations of the Ashigara Valley test site. The prediction was based on the records from a rock-outcrop station, one weak-motion record from a surface-sediments station, and the standard geotechnical model. The data were provided by the Japanese Working Group on the Effects of Surface Geology as a part of an international experiment. The finite-difference method for SH waves in a 2-D linear viscoelastic medium (a causalQ model) was employed.Comparison with the real records shows that at two stations the predictions fit better than at the third one. Strangely, the two better predictions were for stations situated at larger distances from the reference rock station (one station was on the surface, the other in a borehole). The strong ground motion (the peak acceleration of about 200 cm s^–2) was not predicted qualitatively worse than the weak motion (8 cm s^–2). A less sophisticated second prediction (not submitted during the experiment), in which we did not attempt to fit the available weak-motion record at the sedimentary station, agrees with the reality significantly better.     

Solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions

An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H₂S/HS^–/SO _inf4 ^sup2– . The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H₂S+HH^–=Au(HS) ₂ ^– +1/2H₂ (K₁₄); PtS+HS^–+H⁺=Pt (HS) ₂ ⁰ (K₁₅); PdS+HS^–+H⁺=Pd (HS) ₂ ⁰ (K₁₆); PtS₂+H₂=Pt (HS) ₂ ⁰ (K₂₁).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H₂ gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H₂ at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits.     

Aqueous alteration of the Bali CV3 chondrite: evidence from mineralogy, mineral chemistry, and oxygen isotopic compositions

A petrographic, geochemical, and oxygen isotopic study of the Bali CV3 carbonaceous chondrite revealed that the meteorite has undergone extensive deformation and aqueous alteration on its parent body. Deformation textures are common and include flattened chondrules, a well-developed foliation, and the presence of distinctive (100) planar defects in olivine. The occurrence of alteration products associated with the planar defects indicates that the deformation features formed prior to the episode of aqueous alteration. The secondary minerals produced during the alteration event include well-crystallized Mg-rich saponite, framboidal magnetite, and Ca-phosphates. The alteration products are not homogeneously distributed throughout the meteorite, but occur in regions adjacent to relatively unaltered material, such as veins of altered material following the foliation. The alteration assemblage formed under oxidizing conditions at relatively low temperatures (<100 degrees C). Altered regions in Bali have higher Na, Ca, and P contents than unaltered regions which suggests that the fluid phase carried significant dissolved solids. Oxygen isotopic compositions for unaltered regions in Bali fall within the field for other CV3 whole-rocks, however, the oxygen isotopic compositions of the heavily altered material lie in the region for the CM and CR chondrites. The heavy-isotope enrichment of the altered regions in Bali suggest alteration conditions similar to those for the petrographic type-2 carbonaceous chondrites.