Constraints on metasomatized mantle under Central South America: evidence from Jurassic alkaline lamprophyre dykes from the Eastern Cordillera, NM Argentina

In the Río Grande Valley, NW Argentina, several porphyritic panidiomorphic, ocelli-bearing dykes and sills intrude the Neoproterozoic to lower Paleozoic basement of the Eastern Cordillera. New petrographical and geochemical data permit us to classify these rocks as ocellar-analcime monchiquites, a feldspar-free variety of alkaline lamprophyre composed of Ti-rich-diopside/augite, Ti-rich biotite/phlogopite, forsteritic olivine, titanian-pargasite and analcime, with abundant ocelli filled with analcime/carbonate. In terms of geochemical compositions they are characterized by LILE and LREE enrichment and lack of Nb-Ta and Eu anomalies. The ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd initial ratios range between 0.70377 to 0.70781 and 0.512506 and 0.512716 respectively, and T_DM model ages vary between 0.25–0.64 Ga. A K-Ar age of 163?±?9 Ma suggests that these rocks are related to the pre-rifting stage of the Mesozoic-Cenozoic continental Salta Rift in NW Argentina. Partial melting of a heterogeneous enriched metasomatized lithospheric mantle, magma mixing and fractionation are envisaged to explain the petrographic, geochemical and isotope characteristics of these magmas.     

GGR Biennial Review: Advances in Laser Ablation and Solution ICP-MS from 2008 to 2009 with Particular Emphasis on Sensitivity Enhancements,Mitigation of Fractionation Effects and Exploration of New Applications

Recent developments from 2008 to 2009 in ICP-MS engineering, methods and applications are reviewed here. Of particular emphasis are advances in: (a) maximising sensitivity and reducing elemental/isotopic fractionation during laser ablation processing; (b) developing new analytical techniques to measure major, minor and trace element abundances without depending on matrix-matched calibrating materials, pre-determined internal standard concentrations and/or multiple analytical methods; (c) applying in situ and solution-based ICP-MS techniques to the analysis of forensic materials for criminal and/or nuclear investigations; and (d) improving precision and limits of detection of laser ablation multi-collector ICP-MS measurements of (ultra) trace elemental and isotopic abundances.     

Thermochemistry of strontium incorporation in aragonite from atomistic simulations

We have investigated the thermodynamics of mixing between aragonite (orthorhombic CaCO₃) and strontianite (SrCO₃). In agreement with experiment, our simulations predict that there is a miscibility gap between the two solids at ambient conditions. All Sr_xCa_1−xCO₃ solids with compositions 0.12 < x < 0.87 are metastable with respect to separation into a Ca-rich and a Sr-rich phase. The concentration of Sr in coral aragonites (x ∼ 0.01) lies in the miscibility region of the phase diagram, and therefore formation of separated Sr-rich phases in coral aragonites is not thermodynamically favorable. The miscibility gap disappears at around 380 K. The enthalpy of mixing, which is positive and nearly symmetric with respect to x = 0.5, is the dominant contribution to the excess free energy, while the vibrational and configurational entropic contributions are small and of opposite sign. We provide a detailed comparison of our simulation results with available experimental data.     

Integration of 3D large‐scale earthquake simulations into the assessment of the seismic risk of Bogota,Colombia

Bogotá, the capital city of Colombia, is mostly located on a lacustrine soil deposit surrounded by hills in a central plateau of the eastern cordillera of the Colombian Andes. This highly populated urban area is exposed to a significant seismic hazard from local and regional fault systems. In addition, the potential ground motion amplification during earthquakes due to the presence of soft soil deposits, along with the effects of the surface and subsurface topography, can strongly influence the seismic hazard and consequently the seismic risk to the city. This study aims to develop a physics‐based framework to generate synthetic ground records that can help better understand the seismic response of the basin and other amplification effects during strong earthquake shaking in the region, and to incorporate these effects into the estimation of seismic risk. To this end, a set of simulations were first conducted on Hercules, the wave propagation octree‐based finite element simulator developed by the Quake Group at Carnegie Mellon University, to identify the impacts of hypothetical strong earthquakes scenarios. Then, the results from these simulations were integrated with the exposure and vulnerability information previously developed for the main building constructions in the city to assess the seismic risk in the region under different conditions of analysis. Results from this more detailed model are compared with previously published results from simplified models. Sensitivity analyses help identify critical aspects that should be considered in the future to improve the seismic risk assessment of infrastructure.     

A 400-year tree-ring record of the Puelo River summer–fall streamflow in the Valdivian Rainforest eco-region, Chile

The Puelo River is a watershed shared between Chile and Argentina with a mean annual streamflow of 644 m³ s^?1. It has a high ecologic and economic importance, including introduced farmed salmon, tourism, sports fishing and projected hydroelectricity. Using Austrocedrus chilensis and Pilgerodendron uviferum tree-ring records we reconstructed summer–fall (December–May) Puelo River streamflow, which is the first of such reconstructions developed in the Pacific domain of South America. The reconstruction goes back to 1599 and has an adjusted r ² of 0.42. Spectral analysis of the reconstructed streamflow shows a dominant 84-year cycle which explains 25.1% of the total temporal variability. The Puelo River summer–fall streamflow shows a significant correlation (P?>?0.95, 1943–2002) with hydrological records throughout a vast geographic range within the Valdivian eco-region (35 to 46°S). Seasonal Puelo River interannual streamflow variability is related to large-scale oceanic and atmospheric circulation features. Summer–fall streamflows showed a significant negative correlation with the Antarctic Oscillation (AAO), whereas winter–spring anomalies appear to be positively connected with sea surface temperature variations in the tropical Pacific. In general, above- and below-average discharges in winter–spring are related to El Niño and La Niña events, respectively. The temporal patterns of the observed and reconstructed records of the Puelo River streamflow show a general decreasing trend in the 1943–1999 period. Projected circulation changes for the next decades in the Southern Hemisphere would decrease summer–fall Puelo River streamflows with significant impacts on salmon production, tourism and hydropower generation.     

The activity of NaCl in seawater of 10–40‰ salinity and 5–25°C at 1 atmosphere

The activity of NaCl in artificial seawater was measured potentiometrically with Na⁺- and Cl^? -sensitive electrodes. The salinity of the solutions, examined at 25°C, ranged from 10–40‰ salinity. The change in the activity from 5–25°C was measured at 35‰ salinity.The molal mean activity coefficient of NaCl in 35‰ seawater at 25°C is 0.667. The relative partial molal enthalpy of NaCl in 35‰ seawater is ?130 ±50 cal mol^?1. This value is in good agreement with the value measured in pure 0.72 M NaCl.The results were compared with activity coefficients predicted by a specific interaction model and by an ion association model. Good agreement was found in both cases.     

Expert systems for automated correlation and interpretation of wireline logs

CORRELATOR is an interactive computer program for lithostratigraphic correlation of wireline logs able to store correlations in a data base with a consistency, accuracy, speed, and resolution that are difficult to obtain manually. The automatic determination of correlations is based on the maximization of a weighted correlation coefficient using two wireline logs per well. CORRELATOR has an expert system to scan and flag incongruous correlations in the data base. The user has the option to accept or disregard the advice offered by the system. The expert system represents knowledge through production rules. The inference system is goal-driven and uses backward chaining to scan through the rules. Work in progress is used to illustrate the potential that a second expert system with a similar architecture for interpreting dip diagrams could have to identify episodes—as those of interest in sequence stratigraphy and fault detection- and annotate them in the stratigraphic column. Several examples illustrate the presentation.     

Chemical characteristics of groundwater around two massive sulphide deposits in an area of previous mining contamination, Iberian Pyrite Belt, Spain

A detailed chemical study of groundwater was carried out to elucidate the processes controlling the oxidation and dissolution of sulphide minerals at two massive sulphide deposits in the Iberian Pyrite Belt (IPB), i.e. the mined La Zarza deposit and the unmined Masa Valverde deposit. It was found that major-element compositions varied according to the hydrological regime, La Zarza being in a relatively high area with groundwater recharge (and disturbance due to the human factor) and Masa Valverde being in a relatively low area with groundwater discharge. The variations mainly concern pH, Eh, SO₄ and Na concentrations. Metal concentrations were determined (a) by ICP-MS after filtration, and (b) in some cases by voltammetric measurement of Cu, Pb, Zn, Cd and Mn using the Voltammetric In situ Profiling (VIP) System, which allows detection of only the mobile fractions of trace elements (i.e., free metal ions and small labile complexes a few nanometers in size). If one compares the results obtained by each of the two methods, it would appear that the groundwater shows significant enhancement of metal solubility through complexing with organic matter and/or adsorption onto colloids and/or small particles. In areas of sulphide oxidation, however, this solubility enhancement decreases according to Cu>Zn>Cd>Pb. Under very low redox conditions, the attained metal concentrations can be several orders of magnitude (up to 10⁸–10⁹ for Cu and 10²–10³ for Pb) larger than those expected from equilibrium with respect to sulphide minerals as calculated with the EQ3NR geochemical code; Zn concentrations, however, are close to equilibrium with respect to sphalerite. The implication of these results is discussed with respect both to mineral exploration and to environmental issues.