The environment of early Mars and the missing carbonates

Abstract– A model is presented in which the aqueous conditions needed to generate phyllosilicate minerals in the absence of carbonates found in the ancient Noachian crust are maintained by an early CO₂‐rich atmosphere, that, together with iron (II) oxidation, would prevent carbonate formation at the surface. After cessation of the internal magnetic dynamo, a CO₂‐rich primordial atmosphere was stripped by interactions with the solar wind and surface conditions evolved from humid to arid, with ground waters partially dissolving subsurface carbonate and sulfide minerals to produce acid‐sulfate evaporitic deposits in areas with upwelling ground water. In a subsequent geochemical state (Late Noachian to Hesperian), surface and subsurface acidic solutions were neutralized in the subsurface through interaction with basaltic crust, allowing the precipitation of secondary carbonates. This model suggests that, in the early Noachian, the surface waters of Mars maintained acidity because of a drop in temperature. This would have favored increased dissolution of CO₂ and a reduction in atmospheric pressure. In this scenario, physicochemical conditions precluded the formation of surface carbonates, but induced the precipitation of carbonates in the subsurface.     

Reproductive cycle,size at first maturation and fecundity in the golden ling,Genypterus blacodes,in Chile

Reproductive aspects of the golden ling, Genypterus blacodes, from the southern Chilean fishery are presented. Gonad samples were obtained from commercially caught fish between September 1999 and October 2000. Stage of sexual maturity, gonadosomatic index (GSI), and size of females at 50% maturation determined by logistic methods and by plotting the mean GSI by total length, are presented for both years. Batch fecundity was calculated from subsampling mature ovaries containing oocytes in advanced stages of maturity. Changes in GSI and monthly diameters of oocytes showed that ling had a spawning season which extended between August and November. The sizes at first maturity in 1999 and 2000 were 86.6 and 84.8 cm total length (TL), respectively, using the logistic model, and 84 cm for both years using the mean GSI‐size plotting method. The mean batch fecundity was 333 330 oocytes per individual for fish sized 85–120 cm TL. Fecundity increased with increasing weight and total length.     

Waterwells: how can we make legality more attractive?

Hydrogeology Journal - There is a pressing need to improve public administration of groundwater abstraction and use, given the global need to achieve sustainable resource exploitation and to reduce...     

Anomalous content of chromium in a Cretaceous sandstone aquifer of the Bauru Basin,state of São Paulo,Brazil

Anomalous and natural concentrations of Cr⁶⁺, occasionally exceeding the permitted limit for human consumption (0.05 mg/L), have been detected in groundwater in the northwestern region of the state of São Paulo. As part of a water-rock interaction investigation, this article describes the chemical and mineralogical characterization of rock samples taken from boreholes in the municipality of Urânia, with the objective of identifying Cr-bearing minerals and determining how chromium is associated with these minerals. Rock sample analysis were performed using X-ray Fluorescence, X-ray Diffraction, Scanning Electron Microscopy, electron microprobe and sequential extraction techniques. Chemical analyses indicated that the quartzose sandstones show a geochemical anomaly of chromium, with an average content of 221 ppm, which is higher than the reported chromium content of generic sandstones (35 ppm). Diopside was identified as the primary Cr-bearing mineral potentially subject to weathering processes, with a chromium content of up to 1.2% as Cr₂O₃. Many of the diopside grains showed dissolution features, confirming the occurrence of weathering. Sequential extraction experiments indicated that 99.3% of the chromium in samples is tightly bonded to minerals, whereas 0.24% is weakly bonded via adsorption. Assuming hypothetically that all adsorbed chromium is released via desorption, the theoretical Cr concentration in water would be one order of magnitude higher than the concentrations of Cr⁶⁺ detected in groundwater.     

A new species of the Gondwanan genus Cardiolaria Munier-Chalmas in the Sandbian of northwestern Argentina: Paleobiogeographic considerations

A new species of afghanodesmatid, Cardiolaria benicioi, is recorded from Sandbian strata of northwestern Argentina. This species confirms the strong paleobiogeographic relationships between the western Argentina basin and other peri-Gondwanan areas. The Mid-Late Ordovician distribution of bivalves fit well into the Mediterranean Province defined upon brachiopod and trilobite faunas. Similitudes between Tremadocian and Floian bivalves from the western Gondwana and the peri-Gondwanan areas indicate that such ‘Mediterranean’ paleobiogeographic patterns can be traced back well into the Early Ordovician.     

Multi-method assessment of connectivity between surface water and shallow groundwater: the case of Limarí River basin,north-central Chile

A study that tests the applicability and consistency of independent but complementary approaches in the assessment of interactions between surface water and shallow groundwater within a water-stressed basin is described. The mostly agricultural Limarí basin in arid north-central Chile was chosen as a suitable case study. The analyses involved: (1) a connectivity index method, (2) hydrochemistry, and (3) water isotopic geochemistry. Chemical and isotopic data were obtained from two sampling campaigns conducted in April (fall) and December (summer) of 2011 in 22 sampling locations, which included surface water and groundwater. The results obtained by each of the methodologies were mutually consistent and indicate high connectivity conditions. Additionally, the relative contribution by different sources was assessed through end-member mixing analysis, and for reaches of the river that showed gaining conditions, the contribution of groundwater inflow to stream discharge was estimated. It is suggested that this multi-method approach is useful for the characterization of surface-water–groundwater interactions, since it at least represents a suitable starting point for obtaining basic information on these relationships. Thus, it may become the base for further studies in arid and semi-arid basins facing water management challenges.     

Comparative agroenvironmental risks of pesticides in different cropping systems: application of the I-Phy indicator

The green revolution laid the foundations of modern agriculture, by using science and technology to produce more from same resources. The pesticides contributed to agricultural output in the last decades; however, their use has resulted in environmental pollution, health problems, soil and water contamination and negative impact on biota. The impacts of agricultural activities to the environment depended on the practices adopted during the production process. Measurement tools to assess the impacts of those practices are necessary to improve agricultural systems and must be evaluated in different ecosystems. Different soils, climates and crops impose many phytosanitary arrangements. This complex network and the fact that most of the indicators and measurement tools are developed for temperate climates makes it difficult to quantify the environmental impacts under subtropical regions. The I-Phy index is a predictive indicator that assesses the risks of pesticide usage in agriculture and identifies as to which practices generate the main environmental impacts of pesticides. The objective of this study was to test the suitability of the I-Phy index for subtropical conditions and, if suitable, compare the pesticide risk between two regions. Five crops were assessed under three different cropping systems: no-tillage, minimal tillage and conventional tillage. The I-Phy index was sensitive in both regions and capable of identifying that no-tillage generally presented risks of environmental pollution slightly lower than the other tillage systems. The results of I-Phy index showed that high environmental vulnerability of the fields and the numerous applications of active ingredients with high risks resulted in high risks of general contamination. The application of I-Phy on these two case studies showed the indicator can be useful as a support tool to farmers, research and extension institutions pursuing management practices with lower impact on the environment.     

Using a shifted Grünwald-Letnikov scheme for the Caputo derivative to study anomalous solute transport in porous medium

We propose an extension of the shifted Grünwald-Letnikov method to solve fractional partial differential equations in the Caputo sense with arbitrary fractional order derivative α and with an advective term. The method uses the relation between Caputo and Riemann-Liouville definitions, the shifted Grünwald-Letnikov, and the traditional backward and forward finite difference method. The stability of the method is investigated for the implicit and explicit scheme with homogeneous boundary conditions, and a stability criterion is found for the advective-dispersive equation. An application of the method is used to solve contaminant diffusion and advective-dispersive problems. The numerical solution for the fractional diffusion and fractional advection-dispersion is compared with their respective analytical solutions for different time and space grid refinements. The diffusion simulation exhibited a good fit between the analytical and numerical solutions, with the explicit scheme going from stable to unstable as the time and space refinement changes. The fractional advection-dispersion application produced small deviations from the analytical solution. These deviations, however, are analogous to the numerical dispersions encountered in conventional finite difference solutions of the advection-dispersion equation. The new method is also compared with the traditional L2 method. Notably, an example that involves asymmetrical fractional conditions, a fractional diffusivity that depends on time, and a source term show how the methods compare. Overall, this study assesses the quality and easiness of use of the numerical method.     

On the landslide event in 2010 in the Monarch Butterfly Biosphere Reserve, Angangueo, Michoacán, Mexico

In February 2010, 19 fatalities and economic damage were caused by a regional landslide episode in the state of Michoacán, México. The municipalities of Angangueo, Ocampo, Tiquicheo de Nicolás Romero, Tuxpan, and Tuzantla were severely damaged, with Angangueo being the most affected. The event involved a series of debris flows, of which four were the most significant; these four caused 16 deaths in addition to considerable damage to roads, electricity, and the water supply system, with indirect consequences in crop production, cattle farming, and tourism. The area affected by these four flows was calculated as 282?km², with an estimated 697,346?m³ of mobilized material. General observations indicated that the initiation sources of the debris flows were on deforested zones. The present research is concentrated on the Angangueo basin, an area situated within the Monarch Butterfly Biosphere Reserve. Given the lack of rain gauges in the area of interest, records from neighboring points were used to build a comprehensive overview of the extreme precipitation event that triggered the devastating debris flows. The nearest rain gauge, Laguna del Fresno, situated 21?km to the south, recorded 204?mm of rainfall from 1 to 5 February, equivalent to 30% of the mean annual rainfall. Moreover, during a 24-h period the El Bosque rain gauge recorded 144.5?mm of precipitation, the equivalent of 2,270% of the mean rainfall for the same month (6.36?mm). The occurrence of a hailstorm preceding the rainfall event is notable; conditions in the superficial soil layer would have included an increased pore water pressure. Presumably, before the 2,000-year return period extreme rainfall event, thawing of hail and consequent moisture and/or pore-pressure increase result in decreased frictional strength. This paper presents a spatial analysis of the distribution of these landslides, mainly debris flows, as well as general observations on the triggering mechanism, the strength properties of the materials involved, and the societal impact.     

A local spatial decision support system for developing countries based on MCA,fuzzy sets and OWA – case study of a municipality in Cuba

This paper presents a Spatial Decision Support System for local governments of developing countries. It allows municipality government, enterprises, scientific community and civil society to address decision problems using GIS. The framework is supported by four modules of information technologies: Environmental Decision Support Database, Data Manipulation, Decision Support, and Mapping. A case study is presented covering the implementation of this framework in one municipality of Cuba. An example of land suitability planning for coconut crops is used to evaluate the system performance and usability. Results show local municipalities are able to use this framework to solve local decision problems using state of the art decision making even with low infrastructure development.