Ground Motion Zoning of Santiago de Cuba: An Approach by SH Waves Modelling

— The expected ground motion in Santiago de Cuba basin from earthquakes which occurred in the Oriente fault zone is studied. Synthetic SH-waves seismograms have been calculated along four profiles in the basin by the hybrid approach (modal summation for the path source-profile and finite differences for the profile) for a maximum frequency of 1 Hz. The response spectra ratio (RSR) has been determined in 49 sites, distributed along all considered profiles with a spacing of 900 m. The corresponding RSR versus frequency curves have been classified using a logical-combinatorial algorithm. The results of the classification, in combination with the uppermost geological setting (geotechnical information and geological geometry of the subsoil) are used for the seismic zoning of the city. Three different main zones are identified, and a small sector characterized by major resonance effects, due to the particular structural conditions. Each zone is characterized in terms of its expected ground motion parameters for the most probable strong earthquake (M_S=7), and for the maximum possible (M_S=8).     

Oxygen and Hydrogen Isotopic Signatures of Large Atmospheric Ice Conglomerations

Specific studies about the stable isotope composition (¹⁸O/¹⁶O and D/H) of atmospheric icy conglomerations are still scarce. The present work offers, for the first time, a very detailed analysis of oxygen and hydrogen isotopic signatures of unusually large ice conglomerations, or “megacryometeors”, that fell to the ground in Spain during January 2000. The hydrochemical analysis is based on the bulk isotopic composition and systematic selective sampling (deuterium isotopic mapping) of eleven selected specimens. δ¹⁸O and δD (V-SMOW) of all samples fall into the Meteoric Water Line matching well with typical tropospheric values. The distribution of the samples on Craig's line suggests either a variation in condensation temperature and/or different residual fractions of water vapour (Rayleigh processes). Three of the largest megacryometeors exhibited unequivocally distinctive negative values (δ¹⁸O = −17.2%₀ and δD = −127 %₀ V-SMOW), (δ¹⁸O = −15.6%₀ and δD = −112%₀ V-SMOW) and (δ¹⁸O = −14.4%₀ and δD = −100%₀ V-SMOW), suggesting an atmospheric origin typical of the upper troposphere. Theoretical calculations indicate that the vertical trajectory of growth was lower than 3.2 km. During the period in which the fall of megacryometeors occurred, anomalous atmospheric conditions were observed to exist: a substantial lowering of the tropopause with a deep layer of saturated air below, ozone depression and strong wind shear. Moreover, these large ice conglomerations occurred during non-thunderstorm conditions, suggesting an alternative process of ice growth was responsible for their formation.     

Dendrogeomorphological assessment of movement at Hilda rock glacier, Banff National Park, Canadian Rocky Mountains

Abstract The results of this dendrogeomorphological study provide evidence of the active movement of Hilda rock glacier, a tongue‐shaped rock glacier in the Columbia Icefield region of Banff National Park. Cross‐sectional samples were cut from 44 detrital subalpine fir (Abies Iasiocarpa (Hook.) Nutt.) and Engelmann spruce (Picea engelmannii Parry) boles killed and buried by debris spilling off the steep distal slope of the rock glacier. The samples were crossdated using locally and regionally developed tree‐ring chronologies, and were shown to have been killed between 1576 and 1999. Our results show that Hilda rock glacier has advanced at an average rate of 1.6 cm/year since the late 1790s, with limited evidence of similar rates of activity extending back to the mid‐1570s. This rock glacier activity is believed to be linked to persistent periglacial processes that appear to be independent of the climatic forcing mechanisms known to influence glacier mass balances over the same interval.     

Coal fly ash and steel slag valorisation throughout a vitrification process

The aim of this research was to evaluate the feasibility of using the vitrification process as an alternative solution to the disposal of a coal fly ash and metallurgical slags in landfills. The starting wastes were characterised in terms of chemical, granulometric, mineralogical, and microstructural analysis. A selected batch composition composed by 58.5% fly ash, 31.5% metallurgical slag and 10.0 Na₂O% (wt%) was melted at 1450 °C and poured to obtain monolithic glass samples. The environmental behaviour of the starting wastes and the resulting glass was evaluated by standard leaching tests, which shows that vitrification leads to a stabilisation process in which the inorganic components of the wastes are immobilised throughout their incorporation into the glass structure. Moreover, vitrification transforms those hazardous wastes into a new non-hazardous glass. A preliminary study shows that the new glass is suitable for developing glass–ceramic tiles appropriate for floor pavement and wall covering.     

The natural attenuation of two acidic effluents in Tharsis and La Zarza-Perrunal mines (Iberian Pyrite Belt, Huelva, Spain)

The geochemical evolution of two acid mine effluents in Tharsis and La Zarza-Perrunal mines (Iberian Pyrite Belt, Huelva, Spain) has been investigated. In origin, these waters present a low pH (2.2 and 3.1) and high concentrations of dissolved sulphate and metals (Fe, Al, Mn, Cu, Zn, As, Cd, Co, Cr, Ni). However, the natural evolution of these acidic waters (which includes the bacterial oxidation of Fe(II) and the subsequent precipitation of Fe(III) minerals) represents an efficient mechanism of attenuation. This self-mitigating process is evidenced by the formation of schwertmannite, which retains most of the iron load and, by sorption, toxic trace elements like As. The later mixing with pristine waters rises the pH and favours the total precipitation of Fe(III) at pH 3.5 and, subsequently, Al compounds at pH 4.5, along with the sorption of trace metals (Mn, Zn, Cu, Cd, Co, Ni) until chemical equilibrium at circumneutral conditions is achieved.     

Chronic oil pollution harms Magellanic penguins in the Southwest Atlantic

Petroleum pollution is a problem for seabirds along the Southwest Atlantic coast. Twenty-five groups from Salvador, Brazil (12 degrees 58'S) to San Antonio Oeste, Argentina (40 degrees 43'S) survey or rehabilitate sick or oiled seabirds. Four groups, one each in Brazil and Uruguay, and two in Argentina, kept counts of birds found alive and in need of rehabilitation. An average of 63.7% of the seabirds found were Magellanic penguins (Spheniscus magellanicus), with 3869 reported since 1987. Mainly adult penguins were found in Argentina (1605 of 2102 penguins of known age class) and Uruguay (158 of 197). Juveniles were most common in Brazil (234 of 325). Oil fouling was the most frequent cause of injury or sickness. The number of oiled penguins reported in their wintering range has greatly increased since the early 1990s and is strongly correlated with petroleum exports from Argentina. Our results show that chronic petroleum pollution is a problem for wildlife from Southern Brazil through Northern Argentina, and regulations and enforcement are failing to protect living resources.     

Impact of lateral flow and spatial scaling on the simulation of semi‐arid urban land surfaces in an integrated hydrologic and land surface model

Understanding and representing hydrologic fluxes in the urban environment is challenging because of fine scale land cover heterogeneity and lack of coherent scaling relationships. Here, the impact of urban land cover heterogeneity, scale, and configuration on the hydrologic and surface energy budget (SEB) is assessed using an integrated, coupled land surface/hydrologic model at high spatial resolutions. Archetypes of urban land cover are simulated at varying resolutions using both the National Land Cover Database (NLCD; 30 m) and an ultra high‐resolution land cover dataset (0.6 m). The analysis shows that the impact of highly organized, yet heterogeneous, land cover typical of the urban domain can cause large variations in hydrologic and energy fluxes within areas of similar land cover. The lateral flow processes that occur within each simulation create variations in overland flow of up to ±200% and ±4% in evapotranspiration. The impact on the SEB is smaller and largely restricted to the wet season for our semi‐arid forcing scenarios. Finally, we find that this seasonal bias, predominantly caused by lateral flow, is displaced by a systematic diurnal bias at coarser resolutions caused by deficiencies in the method used for scaling of land surface and hydrologic parameters. As a result of this research, we have produced land surface parameters for the widely used NLCD urban land cover types. This work illustrates the impact of processes that remain unrepresented in traditional high‐resolutions land surface models and how they may affect results and uncertainty in modeling of local water resources and climate. Copyright © 2015 John Wiley & Sons, Ltd.     

Magnetic monitoring of top soils of Merida (Southern Mexico)

This paper focuses on the study of the correlation between magnetic parameters with the level of contamination by heavy metals in urban soils. We report a magnetic investigation of urban soil samples from Merida, state of Yucatan, Southern Mexico. It appears that most of our samples contain ferrimagnetic minerals as the magnetic carriers, probably coming from the titanomagnetites/titanomaghemites series. This is inferred by the acquisition of isothermal remanent magnetization, which shows that most of samples are almost completely saturated at about 200 mT. The S₋₂₀₀ value (factor characterizing stability of remanent magnetization) is between 0.8 and 1.0, characteristic of ferrimagnetic minerals. The susceptibility vs. temperature measurements also point to some titanomaghemites and titanomagnetites as probable responsible for magnetization. On the other hand, measurements of magnetic susceptibility at high and low frequencies helped us to determine the high content of superparamagnetic grains in the majority of the samples, although not all of these showed high values of magnetic susceptibility. We found that the most contaminated samples by Pb and Zn showed the higher saturation isothermal remanent magnetization values, whereas the higher values in magnetic susceptibility correspond to samples contaminated by Cr. Finally, we noted that a high level in Sr decreases the magnetic susceptibility.     

Genetic seascape of the threatened Caribbean elkhorn coral,Acropora palmata,on the Puerto Rico Shelf

It has been proposed that the elkhorn coral Acropora palmata is genetically separated into two distinct provinces in the Caribbean, an eastern and a western population admixing in Western Puerto Rico and around the Mona Passage. In this study, the genetic structure of A. palmata sampled at 11 Puerto Rican localities and localities from Curaçao, the Bahamas and Guadeloupe were examined. Analyses using five microsatellite markers showed that 75% of sampled colonies had unique genotypes, the rest being clone mates. Genetic diversity among genets was high (H_E = 0.761) and consistent across localities (0.685–0.844). F_ST ranged from ?0.011 to 0.047, supporting low but significant genetic differentiation between localities within the previously reported eastern and western genetic provinces. Plots of genetic per geographic distances and significant Mantel tests supported isolation‐by‐distance (IBD) within Puerto Rico. Analysis with the software STRUCTURE favored a scenario with weak differentiation between two populations, assigning Eastern Puerto Rican locations (Fajardo and Culebra), Guadeloupe and Curaçao to the Caribbean eastern population and Western Puerto Rican locations (west of Vega Baja and Ponce), Mona and the Bahamas to the Caribbean western population. Vieques and San Juan area harbored admixed profiles. Standardized F_ST per 1000 km unit further supported higher differentiation between localities belonging to different STRUCTURE populations, with IBD being stronger within Puerto Rico than on larger regional scales. This stronger genetic transition seems to separate localities between putative eastern and western provinces in the Eastern Puerto Rican region, but not around the Mona Passage.     

A review of the Tagus river tufa deposits (central Spain): age and palaeoenvironmental record

Here we determined the aminostratigraphy and aminochronology of tufa deposits located in central Spain associated with the Tagus river and some of its tributaries (the Henares, Dulce, Cifuentes, Ruguilla, Trabaque, Escabas and Guadiela rivers). We used aspartic acid and glutamic acid racemization ratios obtained from the ostracod Herpetocypris reptans. Tufa accumulations were found to be of different origins; those in the Henares, Cifuentes and Ruguilla rivers are of paludal origin, while those in the Dulce and Tagus rivers are of fluvial origin. A generally good correspondence was found between the age of the deposits and the position of the terraces above the current thalweg. However, the geomorphological evolution of the Henares, Cifuentes and Ruguilla rivers (infilling of pre-existing valleys) has produced deposits of distinct ages at the same elevation above the current river thalweg, and sometimes, older tufas are located below younger ones.We distinguished eight main tufa-deposition episodes. These occurred predominantly during even Marine Isotopic Stages (MIS), at 406 ± 90 (MIS 11), 264 ± 68 (MIS 7e), 189 ± 40 (MIS 7a), 130 ± 27 (MIS 6-5e), 101 ± 25 (MIS 5c), 32 ± 10 (MIS 3), 14 ± 4 (MIS 1), and 6 ± 2 (MIS 1) ka. These results are in agreement with the dating of similar deposits from nearby areas and other zones of Spain and Europe. The tufa stable-isotope compositions were similar to other examples in central and southern Spain and their plot falls in the same field as other lowland European stream tufas. Oxygen stable isotopes were influenced mainly by temperature and rainfall. The δ¹³C values indicated a major effect of soil-derived carbon rather than carbon from the catchment area, but moderated in each tributary by evaporation, flow regime and biological effects (photosynthesis).