Petrology of lavas from the 2004–2005 flank eruption of Mt. Etna,Italy: inferences on the dynamics of magma in the shallow plumbing system

Following the 2001 and 2002–2003 flank eruptions, activity resumed at Mt. Etna on 7 September 2004 and lasted for about 6 months. This paper presents new petrographic, major and trace element, and Sr–Nd isotope data from sequential samples collected during the entire 2004–2005 eruption. The progressive change of lava composition allowed defining three phases that correspond to different processes controlling magma dynamics inside the central volcano conduits. The compositional variability of products erupted up to 24 September is well reproduced by a fractional crystallization model that involves magma already stored at shallow depth since the 2002–2003 eruption. The progressive mixing of this magma with a distinct new one rising within the central conduits is clearly revealed by the composition of the products erupted from 24 September to 15 October. After 15 October, the contribution from the new magma gradually becomes predominant, and the efficiency of the mixing process ensures the emission of homogeneous products up to the end of the eruption. Our results give insights into the complex conditions of magma storage and evolution in the shallow plumbing system of Mt. Etna during a flank eruption. Furthermore, they confirm that the 2004–2005 activity at Etna was triggered by regional movements of the eastern flank of the volcano. They caused the opening of a complex fracture zone extending ESE which drained a magma stored at shallow depth since the 2002–2003 eruption. This process favored the ascent of a different magma in the central conduits, which began to be erupted on 24 September without any significant change in eruptive style, deformation, and seismicity until the end of eruption.     

A new hydrostratigraphic model of Venice area (Italy)

Two environmental problems affect the Venice area: subsidence, which has been increasing due to the intensive water abstraction after the Second World War, and contamination of the soil and shallow aquifers. In order to address these problems, which are decisive factors in the entire Venetian ecosystem, the aquifer structure must be known in detail. The lithologic data are abundant and of good quality up to a depth of 50 m, whereas boreholes beyond this depth are much rarer and more dispersed, making their associated lithological data unreliable. This work, which uses the available data together with fast and low cost passive seismic measurements, provides an improved understanding of the deeper hydrogeologic domain. For this purpose, a MATLAB package (Modalstrata) has been developed to improve the correlation of the stratigraphic succession for each selected homogeneous sub-area and applied to obtain a new, upgraded hydrostratigraphic model. The horizontal to vertical spectral ratio passive seismic surveys have confirmed the lateral correlations among the sample areas at least for the two main aquifer horizons. Analysis and comparisons of several previous studies performed on the data related to the only drilling continuous coring 951 m deep in the Tronchetto Island (Venice), have allowed a satisfactory validation of the proposed hydrogeological model.     

A comparison of procrystal and ab initio model representations of the electron-density distributions of minerals

 The procrystal calculation of the electron density is a very rapid procedure that offers a quick way to analyze various bonding properties of a crystal. This study explores the extent to which the positions, number, and properties of bond-critical points determined from the procrystal representations of the electron density for minerals are similar to those of first-principles ab initio model distributions. The purpose of the study is to determine the limits imposed upon interpretation of the procrystal electron density. Procrystal calculations of the electron density for more than 300 MO bonds in crystals were compared with those previously calculated using CRYSTAL98 and TOPOND software. For every bond-critical point found in the ab initio calculations, an equivalent one was also found in the procrystal model, with similar magnitudes of electron density, and at similar positions along the bonds. The curvatures of the electron densities obtained from the ab initio and the procrystal distributions are highly correlated. It is concluded that the procrystal distributions are capable of providing good estimates of the bonded radii of the atoms and the properties of the electron-density distributions at the bond-critical points. Because the procrystal model is so fast to compute, it is especially useful in addressing the question as to whether a pair of atoms is bonded or not. If the Bader criteria for bonding are accepted, then the successful generation of the bond-critical points by the procrystal model demonstrates that bonding is an atomic feature. The main difference between the critical-point properties of the procrystal and the ab initio model is that the curvature in the electron density perpendicular to the bond path of the ab initio model is sharper than for the procrystal model. This is interpreted as indicating that the electrons that migrate into a bond originate from its sides, and not from the regions closer to the nuclei. This observation also suggests that ab initio optimization routines could see an improvement in speed if the parameters relating to the angular components of atomic wave functions were to vary before the radial components. Received: 6 August 2001 / Accepted: 21 November 2001     

Defect distribution and dissolution morphologies on low-index surfaces of α-quartz

The dissolution of prismatic and rhombohedral quartz surfaces by KOH/H₂O solutions was investigated by atomic force microscopy. Rates of dissolution of different classes of surface features (e.g., steps, voids, and dislocation etch pits) were measured. The prismatic surface etched almost two orders of magnitude faster than the rhombohedral surface, mostly due to the difference in the number and the rate of dissolution of extended defects, such as dislocations. Because of the presence of imperfect twin boundaries, defect densities on the prismatic surface were estimated at 50-100 μm⁻², whereas the rhombohedral surface possessed only ∼0.5-1.0 μm⁻², mostly in the form of crystal voids. Crystal voids etched almost one order of magnitude faster on the prismatic surface than on the rhombohedral surface due to differences in the number and the density of steps formed by voids on the different surfaces. In the absence of extended defects, both surfaces underwent step-wise dissolution at similar rates. Average rates of step retreat were comparable on both surfaces (∼3-5 nm/h on the prismatic surface and ∼5-10 nm/h on the rhombohedral surface). Prolonged dissolution left the prismatic surface reshaped to a hill-and-valley morphology, whereas the rhombohedral surface dissolved to form coalescing arrays of oval-shaped etch pits.     

Simulated ROSAT observations of clusters of galaxies

Detailed simulations have been made of the search for clusters of galaxies during the ROSAT all-sky x-ray survey (0.1–2 keV). The simulations use a conservative estimate of the cluster luminosity function to create an x-ray catalog specifying cluster position, redshift, flux, temperature and angular extent. This is used in combination with realistic models of the ROSAT scanning motion and of the background due to particles, cosmic x-rays and scattered solar x-rays, to build a simulated ROSAT data base. The data base has been subjected to the ROSAT source search algorithms and the results analyzed. Two cases were considered, a 2-degree wide great circle strip representing the general survey, and a region within 10 degrees of the ecliptic pole, where the exposure is unusually high. We present estimates of the minimum number of clusters to be detected, the fraction recognized as extended x-ray sources, and the minimum detectable energy flux from clusters during the survey.     

Hydrologic response of upland catchments to wildfires

To which extent do wildfires affect runoff production, soil erosion and sediment transport in upland catchments? This transient effect is investigated here by combining data of long term precipitation, sediment yield and wildfire records with a fine resolution spatially distributed modeling approach to flow generation and surface erosion. The model accounts for changes in the structure and properties of soil and vegetation cover by combining the tube-flux approach to topographic watershed partition with a parsimonious parametrization of hydrologic processes. This model is used to predict hydrologic and sediment fluxes for nine small catchments in Saint Gabriel mountains of southern California under control (pre-fire) and altered (post-fire) conditions. Simulation runs using a 45 years record of hourly precipitation show the passage of fire to significantly modify catchment response to storms with a major effect on erosion and flood flows. The probability of occurrence of major floods in the post-fire season is shown to increase up to an order of magnitude under same precipitation conditions. Also, the expected anomaly of sediment yield can increase dramatically the desertification hazard in upland wildfire prone areas. One should further consider the role of firefloods produced by the combined occurrence of wildfires and storms as a fundamental source of non-stationarity in the assessment of hydrologic hazard.     

Bounds on the eigenvalues of the planetary-scale baroclinic instability problem

In the framework of the linear baroclinic instability problem for planetary geostrophic flows, bounds on the related complex eigenvalues are deduced. The main feature of this result is the independence of these bounds from the latitude and the density stratification, so that it generalizes the results of previous work on the subject.     

Nonlocal bacterial electron transfer to hematite surfaces

Mechanisms by which dissimilatory iron-reducing bacteria utilize iron and manganese oxide minerals as terminal electron acceptors for respiration are poorly understood. In the absence of exogenous electron shuttle compounds, extracellular electron transfer is generally thought to occur through the interfacial contact area between mineral surfaces and attached cells. Possible alternative reduction pathways have been proposed based on the discovery of a link between an excreted quinone and dissimilatory reduction. In this study, we utilize a novel experimental approach to demonstrate that Shewanella putrefaciens reduces the surface of crystalline iron oxides at spatial locations that are distinct from points of attachment.     

Inner-Helmholtz potential development at the hematite (α-Fe2O3) (0 0 1) surface

Electric potentials of the (0 0 1) surface of hematite were measured as a function of pH and ionic strength in solutions of sodium nitrate and oxalic acid using the single-crystal electrode approach. The surface is predominantly charge-neutral in the pH 4-14 range, and develops a positive surface potential below pH 4 due to protonation of μ-OH⁰ sites (pK_1,1,0,int = −1.32). This site is resilient to deprotonation up to at least pH 14 (−pK_−1,1,0,int ? 19). The associated Stern layer capacitance of 0.31-0.73 F/m² is smaller than typical values of powders, and possibly arises from a lower degree of surface solvation. Acid-promoted dissolution under elevated concentrations of HNO₃ etches the (0 0 1) surface, yielding a convoluted surface populated by sites. The resulting surface potential was therefore larger under these conditions than in the absence of dissolution. Oxalate ions also promoted (0 0 1) dissolution. Associated electric potentials were strongly negative, with values as large as −0.5 V, possibly from metal-bonded interactions with oxalate. The hematite surface can also acquire negative potentials in the pH 7-11 range due to surface complexation and/or precipitation of iron species (0.0038 Fe/nm²) produced from acidic conditions. Oxalate-bearing systems also result in negative potentials in the same pH range, and may include ferric-oxalate surface complexes and/or surface precipitates. All measurements can be modeled by a thermodynamic model that can be used to predict inner-Helmholtz potentials of hematite surfaces.