Petrochemical variations among mildly peralkaline (comendite) obsidians from the oceans and continents

Eleven new analyses and modes of comendite obsidians are presented, and compared with all available data on similar rocks. Most specimens are aphyric or contain only sparse phenocrysts, most commonly alkali feldspar. The oxides SiO₂, Al₂O₃, Na₂O and K₂O total over ninety percent by weight in all analyses. Iron, as FeO, is the only other constituent rising above one percent by weight. When the analyses are projected into the system Na₂O-K₂O-Al₂O₃-SiO₂, oceanic and continental samples group differently. Oceanic specimens have a compositional spread ranging from trachytic to the quartz-feldspar cotectic zone, consistent with derivation through a trachyte magma stem. Continental comendites show a strong correlation with the experimentally determined quartz-feldspar minima along a path of increasing peralkalinity. These differences presumably reflect the contrasting environments of magma generation, and suggest an origin by partial melting within the continental crust for the continental comendite obsidians.     

Carbonatite in the tuffs of the West Eifel,Germany

Newly-discovered carbonatitic fragments from the West Eifel are described in terms of their petrography and trace-element content.     

Extensions to Spatial Factor Methods with an Illustration in Geochemistry

Many applications involving spatial data require several layers of information to be simultaneously analyzed in relation to underlying geography and topographic detail. This in turn generates a need for forms of multivariate analysis particularly oriented to spatial problems and designed to handle spatial structure and dependency both within and between spatially indexed multivariate responses. In this paper we focus on one group of such methods sometimes referred to as spatial factor analysis. Use of these techniques has so far been mostly restricted to applications in the geosciences and in some forms of image processing, but the methods have potential for wider use outside these fields. They are concerned with identifying components of a multivariate data set with a spatial covariance structure that predominantly acts over a particular spatial range or zone of influence. We review the various forms of spatial factor analysis that have been proposed and emphasize links between them and with the linear model of coregionalization employed in geostatistics. We then introduce extensions to such methods that may prove useful in exploratory spatial analysis, both generally and more specifically in the context of multivariate spatial prediction. Application of our proposed exploratory techniques is demonstrated on a small but illustrative geochemical data set involving multielement measurements from stream sediments.     

The destructive effects of binary encounters on red giants in the Galactic Centre

We consider the destructive effects of encounters between binaries and red giant stars in the Galactic Centre. Such encounters may explain the observed depletion of luminous red giants within the central 0.2 pc of the galaxy. We consider encounters involving 2- and 8-M⊙ red giants, and thus span the range of stellar masses contributing to the most luminous red giants observed in the Galactic Centre. To explore the phase space of encounters thoroughly, we simulate 18 × 10³ encounters using a modified four-body code in which the red giant core and components of the binary are treated as point masses, and where the envelope configuration is assumed to remain static throughout the encounter. We then rerun a small number of encounters with a smoothed particle hydrodynamics (SPH) code to confirm the reliability of conclusions drawn from the four-body runs. We see two possible pathways to red giant destruction. A large fraction of encounters lead to the formation of common-envelope systems, where two compact objects (drawn from the red giant core and the components of the original binary) form a binary within a common gaseous envelope, whilst the third body is ejected. The destruction of the red giant will then follow when the envelope is ejected as the binary hardens. In a smaller number of encounters, the intruding binary passes through the star and ejects the red giant core from the envelope. The red giant envelope will then disperse on short time-scales. We compute the time-scales for both of these processes to occur in the Galactic Centre for a variety of binary populations.     

Annual and seasonal variations in the low-latitude topside ionosphere

Annual and seasonal variations in the low-latitude topside ionosphere are investigated using observations made by the Hinotori satellite and the Sheffield University Plasmasphere Ionosphere Model (SUPIM). The observed electron densities at 600 km altitude show a strong annual anomaly at all longitudes. The average electron densities of conjugate latitudes within the latitude range ±25° are higher at the December solstice than at the June solstice by about 100% during daytime and 30% during night-time. Model calculations show that the annual variations in the neutral gas densities play important roles. The model values obtained from calculations with inputs for the neutral densities obtained from MSIS86 reproduce the general behaviour of the observed annual anomaly. However, the differences in the modelled electron densities at the two solstices are only about 30% of that seen in the observed values. The model calculations suggest that while the differences between the solstice values of neutral wind, resulting from the coupling of the neutral gas and plasma, may also make a significant contribution to the daytime annual anomaly, the E × B drift velocity may slightly weaken the annual anomaly during daytime and strengthen the anomaly during the post-sunset period. It is suggested that energy sources, other than those arising from the 6% difference in the solar EUV fluxes at the two solstices due to the change in the Sun-Earth distance, may contribute to the annual anomaly. Observations show strong seasonal variations at the solstices, with the electron density at 600 km altitude being higher in the summer hemisphere than in the winter hemisphere, contrary to the behaviour in NmF2. Model calculations confirm that the seasonal behaviour results from effects caused by transequatorial component of the neutral wind in the direction summer hemisphere to winter hemisphere.     

The effect of uncertainty in aerodynamic resistance on evaporation estimates from the combination model

Evaporation estimates from a soybean crop calculated from the combination model are insensitive to aerodynamic resistance. The insensitivity arises from a strong link between evaporation and the vapour pressure deficit of the air and bulk stomatal resistance. The sensitivity of aerodynamic resistance to errors in surface roughness and zero-plane displacement is considered. The resistance is found to be more sensitive to errors in surface roughness than to errors in zero-plane displacement. However, large errors in these have little effect on calculated evaporation. Both surface roughness and zero-plane displacement are empirically related to crop height and leaf area index. Errors incurred by ignoring bluff-body effects and atmospheric stability are small in estimating both resistance and evaporation. Evaporation can be calculated adequately from empirical estimates of surface roughness and zero-plane displacement and single-level measurements of windspeed.     

A method of analyzing polymodal distributions in orientation data

A method of cluster analysis for orientation data is described. The method enables vector statistics to be applied to polymodal distributions. Similar results to those found by modal analysis are obtained.     

An analogue model study of electromagnetic induction in the eastern coastal region of North America

The behavior of electric and magnetic field variations over the eastern coastal region of North America is studied using a scaled laboratory electromagnetic analogue model. The model source frequency used simulates a period of 1 h in the geophysical scale. The results indicate that deflection and conductive channelling of induced electric current is important for both the E-polarization (northeast-southwest direction of the electric field of the source) and the H-polarization (northwest-southeast) of the source field. In the model, conductive channelling occurs through the Strait of Belle Isle, Cabot Strait, and in the St. Lawrence River. Current deflection is particularly prevalent around the southeast coast of Newfoundland for both E- and H-polarization, and around the northeast coastline of Nova Scotia for E-polarization. The model results also show current deflection by cape and bay coastal features, as well as by ocean depth contours.A comparison of model measurements for the cases of a uniform source field and a line current source indicate that the nature of the source field has a measurable but surprisingly small effect on the vertical to horizontal magnetic field ratio for both E- and H-polarizations, and negligible effect on the magnetotelluric ratio for coastal regions.The model fields in coastal regions were found to be strongly influenced by induced currents, deflected and channelled by the coastline and ocean bathymetry, and were dependent on the nature and particularly the polarization of the source field. Thus, along the complex coastline of eastern North America, a wide range of electric and magnetic field values should be expected. In some regions the coast effect, measured by the vertical to horizontal magnetic field ratio at the coast, could be expected to be extremely small or absent, while in other regions the ratio could approach a value as large as unity for variations of 1 h period.