An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting

The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free, olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements in residual minerals reequilibrate with their surrounding melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Measuring the benefits and costs of community education and outreach in marine protected areas

Conservation organizations often invest considerable resources in education and outreach activities in and around marine protected areas (MPAs). The expectation is that such efforts will change local knowledge, attitudes and ultimately behavior. This is one of the first studies to assess the efficacy of using education and outreach activities to improve community knowledge and attitudes about an MPA. Random sample surveys in 2005 and 2010 (n=1213) before and after education and outreach activities are compared. Program budgets for the same period give the investment levels. With an investment level averaging US$24 per capita/year, the result was an average increase of 33% in “yes” responses across 15 indicators of knowledge and attitudes towards marine conservation. The increase in knowledge and positive attitudes was associated with a large decrease in “not sure” responses, suggesting that community members with fewer initial preconceptions are the most effective target for education and outreach activities. This study demonstrates that investments in MPA education and outreach can generate increases in local knowledge and positive attitudes, and changing knowledge and attitudes is expected to contribute to the long-term compliance with MPA regulations.     

Areas of Polar Coronal Holes from 1996 Through 2010

Polar coronal holes (PCHs) trace the magnetic variability of the Sun throughout the solar cycle. Their size and evolution have been studied as proxies for the global magnetic field. We present measurements of the PCH areas from 1996 through 2010, derived from an updated perimeter-tracing method and two synoptic-map methods. The perimeter-tracing method detects PCH boundaries along the solar limb, using full-disk images from the SOlar and Heliospheric Observatory/Extreme ultraviolet Imaging Telescope (SOHO/EIT). One synoptic-map method uses the line-of-sight magnetic field from the SOHO/Michelson Doppler Imager (MDI) to determine the unipolarity boundaries near the poles. The other method applies thresholding techniques to synoptic maps created from EUV image data from EIT. The results from all three methods suggest that the solar maxima and minima of the two hemispheres are out of phase. The maximum PCH area, averaged over the methods in each hemisphere, is approximately 6 % during both solar minima spanned by the data (between Solar Cycles 22/23 and 23/24). The northern PCH area began a declining trend in 2010, suggesting a downturn toward the maximum of Solar Cycle 24 in that hemisphere, while the southern hole remained large throughout 2010.     

Distribution patterns of living benthic foraminifera from Cap Breton canyon,Bay of Biscay: Faunal response to sediment instability

Analysis of living (Rose Bengal-stained) benthic foraminifera in 13 multicorer samples taken along the Cap Breton canyon (Bay of Biscay) revealed that the combination of organic-rich material and sediment instability provides very specific benthic ecosystem conditions. The active canyon hosts different foraminiferal assemblages that appear to be determined by different types and frequencies of environmental disturbance at the sites. Most of them are strongly dominated by shallow-infaunal living taxa that combine a tolerance for low-quality organic matter with a high reproductive potential. Foraminiferal assemblages characterized by high densities, very superficially living taxa and strong dominance of bolivinids and buliminids, follow a poor pioneer fauna dominated by Technitella melo. These assemblages are observed in the narrow canyon axis, where frequent sediment resuspension occurs and affects habitat stability. Assemblages studied from sites outside the canyon axis are still dominated by shallow-infaunal species but show lower foraminiferal densities and higher diversities. Deep-infaunal taxa are only present in some inner meanders and more distal stations. These assemblages are typical for ecological niches that are relatively stable and unaffected by re-sedimentation processes. They have attained a more advanced stage of ecosystem stability. They are influenced by neither lateral sediment nor enriched organic matter input.     

Case study concerning the impact of solar activity upon potential gradient and air earth current in the lower troposphere

Summary From the years of 1968 and 1969, five periods were selected which are distinguished by the fact that at the recording site for potential gradientE and air earth currentI (at 3000 m a.s.l.), pure fine weather prevailed for 7 up to 20 days, and the site was persistently situated above the exchange layer. Thus, favorable conditions existed for the investigation of solar impact on the behavior ofE andI. The following parameters were compared withE andI during said periods: solar flares bursts of very high frequency waves,X and proton bursts, solar wind velocity, geomagnetic disturbances and storms, and solar 10 cm radiation flux. It became very apparent that a maximum of 10 cm flux was followed, after a few days, by a maximum ofE xI. This correlation is more pronounced than that existing betweenE xI and solar flares. The correlation ofE xI with other geophysical and astrophysical parameters is loose by comparison. The investigations have revealed that fine analyses such as have been attempted here, might be suited for clearing up, step by step, the actual causal relationship between a solar event and the behavior of the atmospheric electrical parameters.

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Zusammenfassung Aus den Jahren 1968 und 1969 wurden 5 Perioden ausgewählt, die sich dadurch auszeichnen, dass an der in 3000 m a.s.l. liegenden Registrierstation für PotentialgradientE und air earth currentI über 7–20 Tage hinweg reines Schönwetter herrschte und sich die Station anhaltend über der Austausch-Schicht befand. Günstige Voraussetzungen für das Studium solarer Einflüsse auf das Verhalten vonE undI waren damit gegeben. Mit dem Zeitverlauf dieser Grössen wurde während dieser Perioden verglichen: solar flares, Ultrakurzwellen bursts,X- und proton bursts, solar wind velocity, geomagnetische Störungen und Stürme, und solar 10 cm flux. Es zeichnete sich schr klar ab, dass wenige Tage nach einem Maximum des 10 cm flux ein Maximum vonE xI flogt. Diese Korrelation ist ausgeprägter als die zwischenE xI und solar flares. Die übrigen geo- und astrophysikalischen Parameter lassen eine vergleichsweise lose Korrelation mitE xI erkennen. Die Untersuchungen zeigen, dass sich Feinanalysen, wie sie hier versucht worden sind, dazu eignen könnten, die eigentlichen Kausalbeziehungen zwischen solarem Ereignis und Verhalten der atmosphärischelektrischen Parametern Schritt für Schritt aufzuklären.

     

Traces of NO 3 ′ ions contained in ice crystals influence charge separation upon crystal fragmentation

Summary If needle-shaped ice crystals are grown in an atmosphere containing traces of nitrous gases, the amount of electrical charge generated when sharp crystal points break away, is between 10 and 50 times as high as in the case of crystals grown in absence of nitrous gases A definite relation has been found to exist between the NO ₃ ion concentration of the ice crytals and the amount of charge (average value 2.7×10^–8, maximum value 13×10^–8 coulombs per gram of ice splinters) generated upon fragmentation. The relation found is possibly of importance with respect to thunderstorm electricity generation.Physikalisch-Bioklimatische Forschungsstelle der Fraunhofer-Gesellschaft, Garmisch-Partenkirchen.     

Volcanic conduit failure as a trigger to magma fragmentation

In the assessment of volcanic risk, it is often assumed that magma ascending at a slow rate will erupt effusively, whereas magma ascending at fast rate will lead to an explosive eruption. Mechanistically viewed, this assessment is supported by the notion that the viscoelastic nature of magma (i.e., the ability of magma to relax at an applied strain rate), linked via the gradient of flow pressure (related to discharge rate), controls the eruption style. In such an analysis, the physical interactions between the magma and the conduit wall are commonly, to a first order, neglected. Yet, during ascent, magma must force its way through the volcanic edifice/structure, whose presence and form may greatly affect the stress field through which the magma is trying to ascend. Here, we demonstrate that fracturing of the conduit wall via flow pressure releases an elastic shock resulting in fracturing of the viscous magma itself. We find that magma fragmentation occurred at strain rates seven orders of magnitude slower than theoretically anticipated from the applied axial strain rate. Our conclusion, that the discharge rate cannot provide a reliable indication of ascending magma rheology without knowledge of conduit wall stability, has important ramifications for volcanic hazard assessment. New numerical simulations are now needed in order to integrate magma/conduit interaction into eruption models.     

New studies on the radioactivity of the atmosphere

1. I.
   The effect of the gamma rays from the various radioactive substances floating in the atmosphere—previously only estimated theoretically—was determined directly by measuring the total ionization with and without a 1,2 cm. iron plate on top of the ionization chamber which was shielded on the bottom and on all sides by 10 cm. iron. The absorption of the soft component of cosmic radiation in 1,2 cm. iron was taken into account. It was found that the gamma radiation from the radioactive substances in the atmosphere (“air radiation”) amounts, on the average to 0,15I (ion pairs per cm.³·sec) near the ground. It varies considerably from day to day. These variations can exaggerate or mask actual fluctuations which may occur in the soft component of cosmic rays.     

Comparisons of Three Methods to Determine the Vertical Stratification of Pore Fluids

Three methods were used to investigate the possibility of vertical stratification of the pore fluid in an aquifer. The wells available for the study were fully screened and had a 5cm disturbed annulus around them. The first method used a pump with a straddle packer to isolate a short section of the secreened interval. A tracer test demonstrated that most of the pumped sample came from the well bore, presumably by piping through the disturbed. annulus. The second method used induction logs to measure the formation electrical conductivity as a function of depth. Due to the presence of clays and an inability to obtain porosity information, it was not possible to determine the pore fluid electrical conductivity using induction logs. A third method, dilution sampling, was developed that used a straddle packer to isolate a segment of the well screen. A tracer was injected into the packed-off segment, and the tracer concentration in the well was monitored. The tracer was removed from the packed-off segment by dilution and advection by ground water. When the tracer was completely removed from the packed-off segment, the fluid in the segment was considered to be representative of the adjacent pore fluid. Only the dilution sampling method determined unambiguously that the pore fluid was not stratified.