Local magnitude,surface wave magnitude and seismic energy

Summary The local magnitude M_L at the seismological station Pruhonice (PRU) was converted into surface wave magnitude M_S using the formula M_S=–3.2+1.45 M_L and the seismic wave energy was estimated using the relation log E (Joule)=1.2+2.0 M_L. It was proposed to apply the same conversion formulae at seismological stations Kaperské Hory (KHC) and Berggiesshübel (BRG) where the calibrating functions for local magnitudes were determined for the same set of earthquakes with common reference magnitudes as in the case of the PRU station.     

Variability of Sea Surface Heights in the Baltic Sea: An Intercomparison of Observations and Model Simulations

Sea level changes in the Baltic Sea are dominated by internal, short-term variations that are mostly caused by the ephemeral nature of atmospheric conditions over the Baltic area. Tides are small and their influence decreases from western parts of the Baltic Sea to the Baltic Proper. Superimposed to the large short-term sea level changes (up to few decimeters from day to day) are seasonal and interannual variations (centimeters to decimeters). This study focuses on the comparison of sea surface heights obtained from observations and from a high resolution oceanographic model of the Baltic Sea. From this comparison, the accuracy of the modeled sea surface variations is evaluated, which is a necessary precondition for the further use of the oceanographic model in geodetic applications. The model reproduces all observed Baltic sea level variations very reliably with an accuracy of 5 to 9 cm (rms) for short-term variations (up to 2 months) and 8 cm (rms) for long-term variations (>2 months). An additional improvement of the model can be attained by including long-period sea level variations of the North Sea. The model performs well also in the case of extreme sea level events, as is shown for a major storm surge that occurred at the southern coast of the Baltic Sea in November 1995.     

Transient simulation of the last glacial inception. Part I: glacial inception as a bifurcation in the climate system

We study the mechanisms of glacial inception by using the Earth system model of intermediate complexity, CLIMBER-2, which encompasses dynamic modules of the atmosphere, ocean, biosphere and ice sheets. Ice-sheet dynamics are described by the three-dimensional polythermal ice-sheet model SICOPOLIS. We have performed transient experiments starting at the Eemiam interglacial, at 126 ky BP (126,000 years before present). The model runs for 26 kyr with time-dependent orbital and CO₂ forcings. The model simulates a rapid expansion of the area covered by inland ice in the Northern Hemisphere, predominantly over Northern America, starting at about 117 kyr BP. During the next 7 kyr, the ice volume grows gradually in the model at a rate which corresponds to a change in sea level of 10 m per millennium. We have shown that the simulated glacial inception represents a bifurcation transition in the climate system from an interglacial to a glacial state caused by the strong snow-albedo feedback. This transition occurs when summer insolation at high latitudes of the Northern Hemisphere drops below a threshold value, which is only slightly lower than modern summer insolation. By performing long-term equilibrium runs, we find that for the present-day orbital parameters at least two different equilibrium states of the climate system exist—the glacial and the interglacial; however, for the low summer insolation corresponding to 115 kyr BP, we find only one, glacial, equilibrium state, while for the high summer insolation corresponding to 126 kyr BP only an interglacial state exists in the model.

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Ultra‐reduced phases in Apollo 16 regolith: Combined field emission electron probe microanalysis and atom probe tomography of submicron Fe‐Si grains in Apollo 16 sample 61500

The lunar regolith contains a variety of chemically reduced phases of interest to planetary scientists and the most common, metallic iron, is generally ascribed to space weathering processes (Lucey et al. 2006 ). Reports of silicon metal and iron silicides, phases indicative of extremely reducing conditions, in lunar samples are rare (Anand et al. 2004 ; Spicuzza et al. 2011 ). Additional examples of Fe‐silicides have been identified in a survey of particles from Apollo 16 sample 61501,22. Herein is demonstrated the utility of low keV electron probe microanalysis (EPMA), using the Fe Ll X‐ray line, to analyze these submicron phases, and the necessity of accounting for carbon contamination. We document four Fe‐Si and Si⁰ minerals in lunar regolith return material. The new Fe‐Si samples have a composition close to (Fe,Ni)₃Si, whereas those associated with Si⁰ are close to FeSi₂ and Fe₃Si₇. Atom probe tomography of (Fe,Ni)₃Si shows trace levels of C (60 ppma and nanodomains enriched in C, Ni, P, Cr, and Sr). These reduced minerals require orders of magnitude lower oxygen fugacity and more reducing conditions than required to form Fe⁰. Documenting the similarities and differences in these samples is important to constrain their formation processes. These phases potentially formed at high temperatures resulting from a meteorite impact. Whether carbon played a role in achieving the lower oxygen fugacities—and there is evidence of nearby carbonaceous chondritic material—it remains to be proven that carbon was the necessary component for the unique existence of these Si⁰ and iron silicide minerals.     

Post‐Eocene intensification of deep‐water circulation in the central South Pacific: Micropalaeontological clues from dredged sites along the eastern Manihiki Plateau margin

Reconstruction of early Cenozoic deep‐water circulation is one of the keys to modelling Earth's greenhouse‐to‐icehouse surface evolution, but it has long been hampered by the paucity of information from the central South Pacific. To help overcome this knowledge gap, we present new micropalaeontological data from dredged carbonates (R/V Sonne Expedition SO193) at several eastern volcanic salients of the Manihiki Plateau. Interestingly, despite appreciable longitudinal separations among the dredged sites, ages indicated by the foraminiferal assemblages are consistently around the Middle Eocene (including mixed Turonian [Late Cretaceous]/Eocene at a single site), suggesting widespread post‐Eocene cessation of the pelagic sedimentation. By integrating with independent seismic and chronostratigraphic data (Deep Sea Drilling Project Leg 33) for large‐scale erosion of top‐Eocene–Oligocene sedimentary units on the eastern Manihiki Plateau, our results can be viewed as novel physical evidence for the intensification of central South Pacific deep‐water circulation since the Eocene/Oligocene climatic transition.     

Geochemical variations in the Cocos Plate subducting beneath Central America: implications for the composition of arc volcanism and the extent of the Galápagos Hotspot influence on the Cocos oceanic crust

New geochemical data from the Cocos Plate constrain the composition of the input into the Central American subduction zone and demonstrate the extent of influence of the Galápagos Hotspot on the Cocos Plate. Samples include sediments and basalts from Ocean Drilling Program (ODP) Site 1256 outboard of Nicaragua, gabbroic sills from ODP Sites 1039 and 1040, tholeiitic glasses from the Fisher Ridge off northwest Costa Rica, and basalts from the Galápagos Hotspot Track outboard of Central Costa Rica. Site 1256 basalts range from normal to enriched MORB in incompatible elements and have Pb and Nd isotopic compositions within the East Pacific Rise MORB field. The sediments have similar ²⁰⁶Pb/²⁰⁴Pb and only slightly more radiogenic ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb isotope ratios than the basalts. Altered samples from the subducting Galápagos Hotspot Track have similar Nd and Pb isotopic compositions to fresh Galápagos samples but have significantly higher Sr isotopic composition, indicating that the subduction input will have a distinct geochemical signature from Galápagos-type mantle material that may be present in the wedge beneath Costa Rica. Gabbroic sills from Sites 1039 and 1040 in East Pacific Rise (EPR) crust show evidence for influence of the Galápagos Hotspot ∼100 km beyond the morphological hotspot track.     

Monthly air temperature trends in Switzerland 1901–2000 and 1975–2004

Summary We analysed long-term temperature trends based on 12 homogenised series of monthly temperature data in Switzerland at elevations between 316 m.a.s.l. and 2490 m.a.s.l for the 20^th century (1901–2000) and for the last thirty years (1975–2004). Comparisons were made between these two periods, with changes standardised to decadal trends. Our results show mean decadal trends of +0.135 °C during the 20^th century and +0.57 °C based on the last three decades only. These trends are more than twice as high as the averaged temperature trends in the Northern Hemisphere. Most stations behave quite similarly, indicating that the increasing trends are linked to large-scale rather than local processes. Seasonal analyses show that the greatest temperature increase in the 1975–2004 period occurred during spring and summer whereas they were particularly weak in spring during the 20^th century. Recent temperature increases are as much related to increases in maximum temperatures as to increases in minimum temperature, a trend that was not apparent in the 1901–2000 period. The different seasonal warming rates may have important consequences for vegetation, natural disasters, human health, and energy consumption, amongst others. The strong increase in summer temperatures helps to explain the accelerated glacier retreat in the Alps since 1980. Authors’ addresses: Martine Rebetez, WSL Swiss Federal Research Institute, 1015 Lausanne, Switzerland; Michael Reinhard, Laboratory of Ecological Systems (ECOS), EPFL Swiss Federal Institute of Technology, 1015 Lausanne, Switzerland.     

Mineralogical and chemical characteristics of some natural jarosites

This paper presents a detailed study of the mineralogical, microscopic, thermal, and spectral characteristics of jarosite and natrojarosite minerals. Systematic mineralogic and chemical examination of a suite of 32 natural stoichiometric jarosite and natrojarosite samples from diverse supergene and hydrothermal environments indicates that there is only limited solid solution between Na and K at low temperatures, which suggests the presence of a solvus in the jarosite-natrojarosite system at temperatures below about 140 °C. The samples examined in this study consist of either end members or coexisting end-member pairs of jarosite and natrojarosite. Quantitative electron-probe microanalysis data for several natural hydrothermal samples show only end-member compositions for individual grains or zones, and no detectable alkali-site deficiencies, which indicates that there is no hydronium substitution within the analytical uncertainty of the method. In addition, there is no evidence of Fe deficiencies in the natural hydrothermal samples. Hydronium-bearing jarosite was detected in only one relatively young supergene sample suggesting that terrestrial hydronium-bearing jarosites generally are unstable over geologic timescales.Unit-cell parameters of the 20 natural stoichiometric jarosites and 12 natural stoichiometric natrojarosites examined in this study have distinct and narrow ranges in the a- and c-cell dimensions. There is no overlap of these parameters at the 1σ level for the two end-member compositions. Several hydrothermal samples consist of fine-scale (2-10 μm) intimate intergrowths of jarosite and natrojarosite, which could have resulted from solid-state diffusion segregation or growth zoning due to variations in the Na/K activity ratio of hydrothermal solutions.     

Heavy-ion irradiation on crystallographically oriented cordierite and the conversion of molecular CO2 to CO: a Raman spectroscopic study

Crystallographically oriented sections of natural gemstone quality cordierite single-crystals have been irradiated with swift heavy ions of GeV energy and various fluences. Irradiation effects on the crystal lattice were investigated by means of Raman spectroscopy. Raman line scans along the trajectory of the ions reveal a close correlation of beam parameters (such as fluence and energy loss dE/dx along the ion path) to strain due to associated changes in lattice dimensions and defect concentration. The luminescence background also scales with the ion fluence and suggests the formation of point defects, which could also account for the macroscopically observable colouration of the irradiated samples. In addition, changes in the amount and nature of volatile species inside the structural channels are observed. They also scale with dE/dx and confirm the previously postulated irradiation-induced conversion of CO₂ to CO. Irradiations along the crystallographic a-, b- and c-axis reveal no significant anisotropy effect with respect to lattice alterations. The polarisation characteristics of the Raman-active modes confirm the preferred molecular alignment of CO and CO₂ along the a-axis direction.