A soil chronosequence in Late Glacial and Neoglacial moraines, Humboldt Glacier, northwestern Venezuelan Andes

Late Glacial and Neoglacial (Little Ice Age) deposits on the Humboldt Massif were analyzed for relative-age dating parameters, including geomorphic and weathering characteristics, geochemical and soil properties. The soil chronosequence, formed in chemically uniform parent materials, provides an important database to study soil evolution in a tropical alpine environment. Extractable and total Fe and Al concentrations, examined to assess their use in relative-age determination, and as paleoenvironmental indicators, provide an important measure of the accumulation and downward profile movement over time of organically-bound Al, ferrihydrite and other crystalline forms (hematite and goethite) of extractable Fe. Ferrihydrite is particularly useful in determining former perched water levels in soils with relation to paleoclimate. The ratios of most Fe extracts are time dependent. The Fe_d/Fe_t ratio, within statistical limits, shows a slow increase from LIA (Little Ice Age) to Late Glacial soils, which closely correlates with other alpine soil studies in the middle latitudes and other tropical alpine locales. Values of Al_d (dithionite) and Al_o (oxalate extractable) generally do not correlate with time; however, Al_p (pyrophosphate extractable) measured against Al_t (total) provides insight on the downward translocation over time of organically-bound Al. Low leaching rates in this chronosequence are further supported by clay mineralogy trends and the geochemical data.     

The application of cathodoluminescence to interpreting the diagenesis of an ancient calcrete profile

A laterally extensive calcrete profile has been identified in the Late Asbian (Lower Carboniferous) shallow marine shelf limestones of the Llangollen area, North Wales. The upper surface of the profile is defined by a laterally discontinuous palaeokarstic surface and by laminated calcareous crusts which developed within the underlying limestone. The profile contains a unique series of early pore-filling vadose cements which only occur down to 1 m below the palaeokarstic surface. Cathodoluminescence reveals that these cements pre-date the late pore-filling meteoric phreatic cements which occur throughout local Asbian lithologies. A spar cement stratigraphy has been established for the calcrete profile. Subaerial vadose cements comprise two generations of non-luminescent cement, followed by a brightly luminescent generation which occasionally shows an acicular habit. This needle-fibre calcite represents the final stage of vadose cementation. Precipitation of vadose cements was contemporary with subaerial alteration and micritization of the limestone. Textures, visible only with cathodoluminescence, provide evidence of recurrent periods of fabric dissolution. The most extensive phase of dissolution occurred immediately after the precipitation of the non-luminescent subaerial vadose cements. Several different textures have been recorded, each reflecting the morphology of a partially dissolved substrate. Dissolution textures are generally confined to the walls of the larger pores and to early brecciation fractures. These probably acted as fluid pathways in the calcrete during early subaerial diagenesis. Much of the non-marine micrite in the calcrete profile appears as needle-fibre calcite under cathodoluminescence. This acicular calcite was probably formed in response to localized supersaturation of meteoric pore fluids caused by periods of near-surface evaporation. Since needle-fibre luminescence is strongly variable, these ambient conditions are not believed to have directly controlled the activator ion concentrations of cementing pore waters. Needle-fibre calcite is considered to be a cement precipitate which has almost completely recrystallized to micrite, probably during the late stages of subaerial diagenesis. Two generations of subaerial micrite which define a ‘micrite stratigraphy’, have been distinguished under cathodoluminescence. Reconstructing the diagenetic history of this ancient calcrete profile has revealed that subaerial alteration was multistaged, with many diagenetic processes acting simultaneously during a single phase of emergence.     

THE RADIATION OF ACOUSTIC WAVES FROM AN AIR-GUN*

A theoretical model is developed for predicting three important parameters of the pressure pulse radiated by an air-gun, namely the rise time, the amplitude of the initial pulse, and the period of the bubble pulse. A knowledge of these three parameters is essential for the efficient design of air-guns arrays. The prediction of the amplitude of the initial pulse is based on the assumption that the initial pulse is radiated by a spherical source with surface area equal to that of the air-gun ports and not by a spherical source with initial volume equal to that of the air-gun chamber, as has been assumed previously. A simple equation is obtained for predicting the period of the bubble pulsation, taking into account the effect of the air-gun body, boundaries such as the sea-surface and seabed and the presence of a number of identical air-guns placed at the same depth and fired simultaneously.     

Infrared vibrational spectra of Beta-Phase Mg2SiO4 and Co2SiO4 to Pressures of 27 GPa

Infrared absorption spectra of the high-pressure polymorphs β-Mg₂SiO₄ and β-Co₂SiO₄ have been measured between 0 and 27 GPa at room temperature. Grüneisen parameters determined for 11 modes of β-Mg₂SiO₄ (frequencies of 300 to 1,050 cm^?1) and 5 modes of β-Co₂SiO₄ (490 to 1,050 cm^?1) range between 0.8 and 1.9. Averaging the mid-infrared spectroscopic data for β-Mg₂SiO₄ yields an average Grüneisen parameter of 1.3 (±0.1), in good agreement with the high-temperature thermodynamic value of 1.35. Similarly, we find a value of 1.05 (±0.2) for the average spectroscopic Grüneisen parameter of β-Co₂SiO₄.     

An integrated approach to investigate saline water intrusion and to identify the salinity sources in the Central Godavari delta, Andhra Pradesh, India

The Central Godavari delta is located along the Bay of Bengal Coast, Andhra Pradesh, India, and is drained by Pikaleru, Kunavaram and Vasalatippa drains. There is no groundwater pumping for agriculture as wells as for domestic purpose due to the brackish nature of the groundwater at shallow depths. The groundwater table depths vary from 0.8 to 3.4 m and in the Ravva Onshore wells, 4.5 to 13.3 m. Electrical Resistivity Tomography (ERT) surveys were carried out at several locations in the delta to delineate the aquifer geometry and to identify saline water aquifer zones. Groundwater samples collected and analyzed for major ions for assessing the saline water intrusion and to identify the salinity origin in the delta region. The results derived from ERT indicated low resistivity values in the area, which can be attributed to the existence of thick marine clays from ground surface to 12–15 m below ground level near the coast and high resistivity values are due to the presence of coarse sand with freshwater away from the coast. The resistivity values similar to saline water <0.01 Ω m is attributed to the mixing of the saline water along surface water drains. In the Ravva Onshore Terminal low resistivity values indicated up coning of saline water and mixing of saline water from Pikaleru drain. The SO ₄ ^?2 /Cl^?and Na⁺²/Cl^?ratios did not indicate saline water intrusion and the salinity is due to marine palaeosalinity, dilution of marine clays and dissolution of evaporites.     

Geochronological constraints on the emplacement history of an anorthosite — rapakivi granite suite: U−Pb zircon and baddeleyite study of the Korosten complex,Ukraine

U–Pb zircon/baddeleyite ages obtained for the Korosten anorthosite-rapakivi granite complex, Ukrainian shield, suggest that different magmatic phases were emplaced during a period of ca. 30 million years as a series of distinct igneous episodes. The earliest 1789.1±2.0 Ma anorthosites were followed by 1781.3±3.2 Ma dykes of plagiogranite porphyries. The emplacement of a major rapakivi granite phase took place at 1767.4±2.2 Ma, and was followed by emplacement of layered intrusions of anorthosites, gabbronorites, diabases and ultrabasic rocks between 1761 and 1758 Ma. The minimum duration of magmatism of about 30 million years, the 6–15 million years interval between igneous pulses, and alternation of discrete episodes of basic and felsie magmatism are common features of major anorthositemangerite-charnockite-rapakivi granite complexes. Temporal distribution of igneous activity in the Korosten complex shows that the gabbro-anorthosites and the granites are not comagmatic, although they are possibly cogenetic, and that at least four portions of granitic and basic magmas were generated during a relatively long period of at least 30 million years. The time gap of about 20–25 million years between early basic and later and more voluminous granitic magmatism, characteristic of the Korosten pluton, Wiborg and Salmi batholiths, probably reflects the duration of extensional processes before the generation of large volumes of magma in the lower crust.     

Attitudes and behaviors of undergraduate students toward environmental issues

The studies carried out throughout the world have indicated that there are differences between environmental attitudes and environmentally responsible behaviors of undergraduate students. In what ways the environmental attitudes and behaviors of the students who will protect and manage the resources of the country in the future have changed is an important issue? This study was aimed at determining the environmental attitudes and environmentally responsible behaviors of the undergraduate students of Abant Ýzzet Baysal University toward environmental issues. In addition, the effects of the faculty in which the students are enrolled, locality and gender on the determined environmental attitudes and environmentally responsible behaviors of the students were investigated. The data were gathered from 507 students in 2005. To explain the environmental attitudes and environmentally responsible behaviors of undergraduate students toward environmental issues, factor analysis was used with Varimax Rotation method. To determine the changes of the environmental attitudes and environmentally responsible behaviors of the students with regard to the faculty, locality and gender, one-way analysis of variance was used. According to the results, students highly support the environmental attitudes and highly participate only in consumerism behaviors. Finally, it was determined if faculty and gender had an effect on the environmental attitudes and behaviors of the students.