Quantifying the fast outflow in the luminous Seyfert galaxy PG1211+143

We report two new XMM–Newton observations of PG1211+143 in 2007 December, again finding evidence for the fast outflow of highly ionized gas first detected in 2001. Stacking the new spectra with those from two earlier XMM–Newton observations reveals strong and broad emission lines of Fe  xxv and O  viii , indicating the fast outflow to be persistent and to have a large covering factor. This finding confirms a high mass rate for the ionized outflow in PG1211+143 and provides the first direct measurement of a wide angle, subrelativistic outflow from an active galactic nuclei (AGN) transporting mechanical energy with the potential to disrupt the growth of the host galaxy. We suggest PG1211+143 may be typical of an AGN in a rapid super-Eddington growth phase.     

The potential of mid- and near-infrared diffuse reflectance spectroscopy for determining major- and trace-element concentrations in soils from a geochemical survey of North America

In 2004, soils were collected at 220 sites along two transects across the USA and Canada as a pilot study for a planned soil geochemical survey of North America (North American Soil Geochemical Landscapes Project). The objective of the current study was to examine the potential of diffuse reflectance (DR) Fourier Transform (FT) mid-infrared (mid-IR) and near-infrared (NIRS) spectroscopy to reduce the need for conventional analysis for the determination of major and trace elements in such continental-scale surveys. Soil samples (n = 720) were collected from two transects (east–west across the USA, and north–south from Manitoba, Canada to El Paso, Texas (USA), n = 453 and 267, respectively). The samples came from 19 USA states and the province of Manitoba in Canada. They represented 31 types of land use (e.g., national forest, rangeland, etc.), and 123 different land covers (e.g., soybeans, oak forest, etc.). The samples represented a combination of depth-based sampling (0–5 cm) and horizon-based sampling (O, A and C horizons) with 123 different depths identified. The set was very diverse with few samples similar in land use, land cover, etc. All samples were analyzed by conventional means for the near-total concentration of 49 analytes (C_total, C_carbonate and C_organic, and 46 major and trace elements). Spectra were obtained using dried, ground samples using a Digilab FTS-7000 FT spectrometer in the mid- (4000–400 cm⁻¹) and near-infrared (10,000–4000 cm⁻¹) at 4 cm⁻¹ resolution (64 co-added scans per spectrum) using a Pike AutoDIFF DR autosampler. Partial least squares calibrations were develop using: (1) all samples as a calibration set; (2) samples evenly divided into calibration and validation sets based on spectral diversity; and (3) samples divided to have matching analyte concentrations in calibration and validation sets. In general, results supported the conclusion that neither mid-IR nor NIRS would be particularly useful in reducing the need for conventional analysis of soils from this continental-scale geochemical survey. The extreme sample diversity, likely caused by the widely varied parent material, land use at the site of collection (e.g., grazing, recreation, agriculture, etc.), and climate resulted in poor calibrations even for C_total, C_organic and C_carbonate. The results indicated potential for mid-IR and NIRS to differentiate soils containing high concentrations (>100 mg/kg) of some metals (e.g., Co, Cr, Ni) from low-level samples (<50 mg/kg). However, because of the small number of high-level samples, it is possible that differentiation was based on factors other than metal concentration. Results for Mg and Sr were good, but results for other metals examined were fair to poor, at best. In essence, it appears that the great variation in chemical and physical properties seen in soils from this continental-scale survey resulted in each sample being virtually unique. Thus, suitable spectroscopic calibrations were generally not possible.     

Chemistry of hot springs along the Eastern Lau Spreading Center

The Eastern Lau Spreading Center (ELSC) is the southernmost part of the back-arc spreading axis in the Lau Basin, west of the Tonga trench and the active Tofua volcanic arc. Over its 397-km length it exhibits large and systematic changes in spreading rate, magmatic/tectonic processes, and proximity to the volcanic arc. In 2005, we collected 81 samples of vent water from six hydrothermal fields along the ELSC. The chemistry of these waters varies both within and between vent fields, in response to changes in substrate composition, temperature and pressure, pH, water/rock ratio, and input from magmatic gases and subducted sediment. Hot-spring temperatures range from 229° to 363 °C at the five northernmost fields, with a general decrease to the south that is reversed at the Mariner field. The southernmost field, Vai Lili, emitted water at up to 334 °C in 1989 but had a maximum venting temperature of only 121 °C in 2005, due to waning activity and admixture of bottom seawater into the subseafloor plumbing system. Chloride varies both within fields and from one field to another, from a low of 528 mmol/kg to a high of 656 mmol/kg, and may be enriched by phase separation and/or leaching of Cl from the rock. Concentrations of the soluble elements K, Rb, Cs, and B likewise increase southward as the volcanic substrate becomes more silica-rich, especially on the Valu Fa Ridge. Iodine and δ⁷Li increase southward, and δ¹¹B decreases as B increases, apparently in response to increased input from subducted sediment as the arc is approached. Species that decrease southward as temperature falls are Si, H₂S, Li, Na/Cl, Fe, Mn, and ⁸⁷Sr/⁸⁶Sr, whereas pH, alkalinity, Ca, and Sr increase. Oxygen isotopes indicate a higher water/rock ratio in the three systems on Valu Fa Ridge, consistent with higher porosity in more felsic volcanic rocks. Vent waters at the Mariner vent field on the Valu Fa Ridge are significantly hotter, more acid and metal-rich, less saline, and richer in dissolved gases and other volatiles, including H₂S, CO₂, and F, than the other vent fields, consistent with input of magmatic gases. The large variations in geologic and geophysical parameters produced by back-arc spreading along the ELSC, which exceed those along mid-ocean ridge spreading axes, produce similar large variations in the composition of vent waters, and thus provide new insights into the processes that control the chemistry of submarine hot springs.     

SFRmaker and Linesink-Maker: Rapid Construction of Streamflow Routing Networks from Hydrography Data

Groundwater models have evolved to encompass more aspects of the water cycle, but the incorporation of realistic boundary conditions representing surface water remains time-consuming and error-prone. We present two Python packages that robustly automate this process using readily available hydrography data as the primary input. SFRmaker creates input for the MODFLOW SFR package, while Linesink-maker creates linesink string input for the GFLOW analytic element program. These programs can reduce weeks or even months of manual effort to a few minutes of execution time, and carry the added advantages of reduced potential for error, improved reproducibility and facilitation of step-wise modeling through reduced dependency on a particular conceptual model or discretization. Two real-world examples at the county to multi-state scales are presented.     

Micromorphological evidence for subglacial multiphase sedimentation and deformation during overpressurized fluid flow associated with hydrofracturing

Hydrofracture systems are being increasingly recognized within subglacial to ice‐marginal settings and represent a visible expression of the passage of pressurized meltwater through these glacial environments. Such structures provide a clear record of the fluctuating hydrostatic pressure and of the resulting brittle fracturing of the host sediment/bedrock and the pene‐contemporaneous liquefaction and introduction of sediment‐fill. A detailed macro‐ and microstructural study of a hydrofracture system cutting Devonian sandstone bedrock exposed at the Meads of St John, near Inverness (NE Scotland), has revealed that this complex multiphase system was active over a prolonged period and accommodated several phases of fluid flow. The main conduits that fed the hydrofracture system are located along bedding within the sandstone, with the site of the wider, steeply inclined to subvertical, transgressive linking sections being controlled by the contemporaneous development of high‐angle fractures and normal faults, the latter occurring in response to localized extension within the bedrock. A comparison with published engineering hydraulic fracturing data indicates that the various stages of sediment‐fill deposited during a flow event can be directly related to the fluctuation in overpressure during hydrofracturing. A model is proposed linking the evolution of this hydrofracture system to the retreat of the overlying Findhorn glacier. The results of this study also indicate that the development and repeated reactivation of subglacial hydrofracture systems can have a dramatic effect on the permeability of the bed, influencing the potential for overpressure build‐up within the subglacial hydrogeological system, and facilitating the migration of meltwater beneath glaciers and ice sheets.