Distributed velocity method of solving the convective-dispersion equation: 1. Introduction,mathematical theory,and numerical implementation

This is the first part of a two-part paper presenting a new method for treating convective-dispersive transport. The motivation for developing this technique arises from the demands of performing a risk assessment for a nuclear waste repository. These demands include computational efficiency over a relatively large range of Peclet numbers, the ability to handle chains of decaying radionuclides with rather extreme contrasts in both solution velocities and half lives, and the ability to treat leach- or solubility-limited sources. To the extent it has been tested to date, the distributed velocity method (DVM) appears to satisfy these demands. This part contains an overall introduction and presents the mathematical theory, numerical implementation, and example results.     

Measurements in the solar spectrum between 1400 and 1875 Å with a rocket-borne spectrometer

Intensity measurements in the solar continuum throughout the wavelength range 1400 Å–1875 Å are reported for a rocket flight from White Sands, New Mexico at 16:31 h UT on September 24, 1968. These intensities are approximately a factor of 3 lower than other published estimates and suggest a solar temperature minimum of 4400 K or lower which is in agreement with infrared observations.     

COSMOGENIC RADIONUCLIDES AND NOBLE GASES IN THE WETHERSFIELD (1982) CHONDRITE

The Wethersfield (1982) chondrite was assayed for a suite of cosmogenic radionuclides shortly after fall. Data are reported for ⁷Be, ²²Na, ²⁶Al, ⁴⁶Sc, ⁴⁸V, ⁵¹Cr, ⁵⁴Mn, ⁵⁶Co, ⁵⁷Co, and ⁶⁰Co. A comparison is made with predicted results based on a scaling to the Deep River Neutron Monitor. Noble gases were also assayed in a sub-sample. The cosmic ray exposure age is estimated to be 45 million years.     

Tight Reassembly of Gondwana Exposes Phanerozoic Shears in Africa as Global Tectonic Players

Aeromagnetic surveys help reveal the geometry of Precambrian terranes through extending the mapping of structures and lithologies from well-exposed areas into areas of younger cover. Continent-wide aeromagnetic compilations therefore help extend geological mapping beyond the scale of a single country and, in turn, help link regional geology with processes of global tectonics. In Africa, India and related smaller fragments of Gondwana, the margins of Precambrian crustal blocks that have escaped (or successfully resisted) fracture or extension in Phanerozoic time can often be identified from their aeromagnetic expression. We differentiate between these rigid pieces of Precambrian crust and the intervening lithosphere that has been subjected to deformation (usually a combination of extension and strike-slip) in one or more of three rifting episodes affecting Africa during the Phanerozoic: Karoo, Early Cretaceous and (post-) Miocene. Modest relative movements between adjacent fragments in the African mosaic, commensurate with the observed rifting and transcurrent faulting, lead to small adjustments in the position of sub-Saharan Africa with respect to North Africa and Arabia. The tight reassembly of Precambrian sub-Saharan Africa with Madagascar, India, Sri Lanka and Antarctica (see animation in http://kartoweb.itc.nl/gondwana) can then be extended north between NW India and Somalia once the Early Cretaceous movements in North Africa have been undone. The Seychelles and smaller continental fragments that stayed with India may be accommodated north of Madagascar. The reassembly includes an attempt to undo strike-slip on the Southern Trans-Africa Shear System. This cryptic tectonic transcontinental corridor, which first formed as a Pan-African shear belt 700–500 Ma, also displays demonstrable dextral and sinistral movement between 300 and 200 Ma, not only evident in the alignment of the unsuccessful Karoo rifts now mapped from Tanzania to Namibia but also having an effect on many of the eventually successful rifts between Africa-Arabia and East Gondwana. We postulate its continuation into the Tethys Ocean as a major transform or megashear, allowing minor independence of movements between West Gondwana (partnered across the Tethys Ocean with Europe) and East Gondwana (partnered with Asia), Europe and Asia being independent before the 250 Ma consolidation of the Urals suture. The relative importance of primary driving forces, such as subduction ‘pull’, and ‘jostling’ forces experienced between adjacent rigid fragments could be related to plate size, the larger plates being relatively closely-coupled to the convecting mantle in the global scheme while the smaller ones may experience a preponderance of ‘jostling’ forces from their rigid neighbours.     

The potential of mid- and near-infrared diffuse reflectance spectroscopy for determining major- and trace-element concentrations in soils from a geochemical survey of North America

In 2004, soils were collected at 220 sites along two transects across the USA and Canada as a pilot study for a planned soil geochemical survey of North America (North American Soil Geochemical Landscapes Project). The objective of the current study was to examine the potential of diffuse reflectance (DR) Fourier Transform (FT) mid-infrared (mid-IR) and near-infrared (NIRS) spectroscopy to reduce the need for conventional analysis for the determination of major and trace elements in such continental-scale surveys. Soil samples (n = 720) were collected from two transects (east–west across the USA, and north–south from Manitoba, Canada to El Paso, Texas (USA), n = 453 and 267, respectively). The samples came from 19 USA states and the province of Manitoba in Canada. They represented 31 types of land use (e.g., national forest, rangeland, etc.), and 123 different land covers (e.g., soybeans, oak forest, etc.). The samples represented a combination of depth-based sampling (0–5 cm) and horizon-based sampling (O, A and C horizons) with 123 different depths identified. The set was very diverse with few samples similar in land use, land cover, etc. All samples were analyzed by conventional means for the near-total concentration of 49 analytes (C_total, C_carbonate and C_organic, and 46 major and trace elements). Spectra were obtained using dried, ground samples using a Digilab FTS-7000 FT spectrometer in the mid- (4000–400 cm⁻¹) and near-infrared (10,000–4000 cm⁻¹) at 4 cm⁻¹ resolution (64 co-added scans per spectrum) using a Pike AutoDIFF DR autosampler. Partial least squares calibrations were develop using: (1) all samples as a calibration set; (2) samples evenly divided into calibration and validation sets based on spectral diversity; and (3) samples divided to have matching analyte concentrations in calibration and validation sets. In general, results supported the conclusion that neither mid-IR nor NIRS would be particularly useful in reducing the need for conventional analysis of soils from this continental-scale geochemical survey. The extreme sample diversity, likely caused by the widely varied parent material, land use at the site of collection (e.g., grazing, recreation, agriculture, etc.), and climate resulted in poor calibrations even for C_total, C_organic and C_carbonate. The results indicated potential for mid-IR and NIRS to differentiate soils containing high concentrations (>100 mg/kg) of some metals (e.g., Co, Cr, Ni) from low-level samples (<50 mg/kg). However, because of the small number of high-level samples, it is possible that differentiation was based on factors other than metal concentration. Results for Mg and Sr were good, but results for other metals examined were fair to poor, at best. In essence, it appears that the great variation in chemical and physical properties seen in soils from this continental-scale survey resulted in each sample being virtually unique. Thus, suitable spectroscopic calibrations were generally not possible.