Heterogeneous pumice populations in the 2.08-Ma Cerro Gal��n Ignimbrite: implications for magma recharge and ascent preceding a large-volume silicic eruption

Triggering mechanisms of large silicic eruptions remain a critical unsolved problem. We address this question for the ~2.08-Ma caldera-forming eruption of Cerro Galán volcano, Argentina, which produced distinct pumice populations of two colors: grey (5%) and white (95%) that we believe may hold clues to the onset of eruptive activity. We demonstrate that the color variations correspond to both textural and compositional variations between the clast types. Both pumice types have bulk compositions of high-K, high-silica dacite to low-silica rhyolite, but there are sufficient compositional differences (e.g., ~150?ppm lower Ba at equivalent SiO₂ content and 0.03?wt.% higher TiO₂ in white pumice than grey) to suggest that the two pumice populations are not related by simple fractionation. Trace element concentrations in crystals mimic bulk variations between clast types, with grey pumice containing elevated Ba, Cu, Pb, and Zn concentrations in both bulk samples (average Cu, Pb, and Zn concentrations are 27, 35, and 82 in grey pumice vs. 11, 19, and 60 in white pumice) and biotite phenocrysts and white pumice showing elevated Li concentrations in biotite and plagioclase phenocrysts. White and grey clasts are also texturally distinct: White pumice clasts contain abundant phenocrysts (44?C57%), lack microlites, and have highly evolved groundmass glass compositions (76.4?C79.6?wt.% SiO₂), whereas grey pumice clasts contain a lower percentage of phenocrysts/microphenocrysts (35?C49%), have abundant microlites, and have less evolved groundmass glass compositions (69.4?C73.8?wt.% SiO₂). There is also evidence for crystal transfer between magma producing white and grey pumice. Thin highly evolved melt rims surround some fragmental crystals in grey pumice clasts and appear to have come from magma that produced white pumice. Furthermore, based on crystal compositions, white bands within banded pumice contain crystals originating in grey magma. Finally, only grey pumice clasts form breadcrusted surface textures. We interpret these compositional and textural variations to indicate distinct magma batches, where grey pumice originated from an originally deeper, more volatile-rich dacite recharge magma that ascended through and mingled with the volumetrically dominant, more highly crystalline chamber that produced white pumice. Shortly before eruption, the grey pumice magma stalled within shallow fractures, forming a vanguard magma phase whose ascent may have provided a trigger for eruption of the highly crystalline rhyodacite magma. We suggest that in the case of the Cerro Galán eruption, grey pumice provides evidence not only for cryptic silicic recharge in a large caldera system but also a probable trigger for the eruption.     

A multi-proxy approach to assessing isolation basin stratigraphy from the Lofoten Islands, Norway

This study takes a comprehensive approach to characterizing the isolation sequence of Heimerdalsvatnet, a coastal lake in the Lofoten Islands, northern Norway. We use established methods and explore new techniques to assess changes in marine influence. Bathymetric and sub-bottom profiles were acquired to examine basin-wide sedimentation and a 5.8 m sediment core spanning the last 7800 cal yr BP was analyzed. We measured magnetic susceptibility, bulk organic matter properties, molecular biomarkers, diatom assemblages, and elemental profiles acquired by scanning X-ray fluorescence. These characteristics of the sediment reflect detailed changes in salinity and water column conditions as the lake was progressively isolated. Three distinct litho/chemo-stratigraphic units represent a restricted marine phase (7800-6500 cal yr BP), a transitional phase characterized by intermittent marine influence (6500-4900 cal yr BP), and complete isolation and freshwater sedimentation (4900 cal yr BP to present). Although there are uncertainties in the estimate of the threshold elevation of the lake, the timing of these phases generally corresponds with previous interpretations of the local relative sea-level history. This record captures sea-level regression following the Tapes transgression and supports the interpretation of a subsequent sea-level stillstand, dated in Heimerdalsvatnet from 6500 to 4900 cal yr BP.     

Comparison of Earth and Mars as differentiated planets

Histories of the terrestrial planets are traceable to combinations of to five large-scale postaccretion processes: planetary differentiation, crustal differentiation, outgassing, plate tectonics, and recycling. All have operated on Earth to make a planet that was early differentiated into core, mantle, and crust and at very nearly the same time outgassed to form a differentiated crust, atmosphere and oceans. This gave rise to plate tectonics, recycling and thus two-way communication of the surface crust-atmosphere-ocean system with lower crust and upper mantle. Recycling of the Martian surface is probably restricted to limited chemical weathering of thin alteration surfaces of primary minerals because of the extreme slowness of diffusion controlled alteration where surfaces are not stripped by solution. There is evidence for neither subsidence of sedimentary basins nor subduction zones; thus internal recycling and two-way surface-interior communication is improbable. All sedimentary particles produced by mechanical erosion on Mars through its history are still at the surface or shallowly buried by later sediment. Any atmospheric components reacted with weathering crust are removed from the atmosphere. These and exospheric escape processes must have early reduced an original denser atmosphere to its present pressure after an early episode of planetary differentiation coupled to crustal differentiation and out-gassing. The early history of Mars may have been something like that of Earth until weathering and gas escape drew down its atmosphere.     

Early Mesoproterozoic bimodal plutonism in the southeastern Gawler Craton,South Australia

The Curramulka Gabbronorite on Yorke Peninsula, southeastern Gawler Craton has an emplacement age of 1589 ± 5 Ma. This is similar to previously determined ages for Arthurton Granite (1582 ± 7 Ma), Tickera Granite (ca 1600 – 1575 Ma), regional alteration, the Moonta – Wallaroo mineralisation (ca 1585 Ma) and localised deformation (Tiparra Deformation). Mesoproterozoic bimodal plutonism is interpreted to have resulted from mafic underplating, emplacement of mafic magmas during lithospheric attenuation and enhanced high heat flow assisting in melting of the lower crust to form the broadly A-type Arthurton and Tickera Granites. Plutonism either directly or indirectly created advective fluid-flow to form Cu – Au mineralisation in the Moonta – Wallaroo area. The nature and characteristics of Mesoproterozoic mafic bodies on the Gawler Craton are poorly known. The Curramulka Gabbronorite has a continental tholeiitic composition and igneous layering that is partly of cumulus origin but also contains magmatic segregations formed by fractionation. Some of these segregations have provided zircons for dating. This igneous layering is overprinted by two foliations of tectonic origin: the first is interpreted to be coeval with magma emplacement and the second with conjugate shearing accompanied by retrogression.     

Lithospheric tectonic structures developed under high-grade metamorphism in the Southern part of Madagascar

Abstract

This paper describes the tectono-metamorphic evolution of a segment of the Precambrian deep crust, in the southern Madagascar island. This crust corresponds to an Archaean basement reworked by a widespread, late panAfrican event (550–580 Ma) during the formation of the Mozambican belt. The finite geometry and associated metamorphism are depicted by satellite imaging, field mapping and P-T estimations using both conventional thermobarometric methods and TWEEQ software program with internally consistent thermodynamic data and uniform set of solution models. The structural pattern developed during high-grade metamorphism shows the juxtaposition of domains with complex fold geometries separated by a 15 km wide ductile shear zone. Within the folded domains, kilometre scale interference patterns associated with strongly dipping metamorphic stretching lineations can be described as superposed folding (F1 and F2 folds). The tight and upright F2 folds result from East-West horizontal shortening. The shear zone is defined by homogeneous orientations of steep foliations, sub-horizontal stretching lineations, and kilometre scale strain gradient. Within the shear zone, we observe dominant non-coaxial criteria at various scales that are consistent with a sinistral strike-slip system during D2 deformation stage. Nevertheless, we have also found in the shear zone, geometries typical of a horizontal shortening. Such a strain pattern is characteristic of transpression tectonics.

The synkinematic metamorphic conditions are estimated on mafic garnetiferous metabasites. Results show that regional transpression tectonics has developed under very high and constant thermal regime (about 800°C). A pressure gap, of about 3 kbar between the domains separated by the shear zone is identified. This implies tectonic coupling of two different structural levels during tranpressive tectonic.     

Quantifying the Loss of a Marine Ecosystem Service: Filtration by the Eastern Oyster in US Estuaries

The oyster habitat in the USA is a valuable resource that has suffered significant declines over the past century. While this loss of habitat is well documented, the loss of associated ecosystem services remains poorly quantified. Meanwhile, ecosystem service recovery has become a major impetus for restoration. Here we propose a model for estimating the volume of water filtered by oyster populations under field conditions and make estimates of the contribution of past (c. 1880–1910) and present (c. 2000–2010) oyster populations to improving water quality in 13 US estuaries. We find that filtration capacity of oysters has declined almost universally (12 of the 13 estuaries examined) by a median of 85 %. Whereas historically, oyster populations achieved full estuary filtration (filtering a volume equivalent or larger than the entire estuary volume within the residence time of the water) in six of the eight estuaries in the Gulf of Mexico during summer months, this is now the case for only one estuary: Apalachicola Bay, Florida. By contrast, while all five estuaries on the North Atlantic coast showed large decreases in filtration capacity, none were achieving full estuary filtration at the time of our c. 1900 historic baseline. This apparent difference from the Gulf of Mexico is explained at least in part by our North Atlantic baseline representing a shifted baseline, as surveyed populations were already much reduced by exploitation in this region.     

Neutron absorption constraints on the composition of 4 Vesta

Global maps of the macroscopic thermal neutron absorption cross section of Vesta's regolith by the Gamma Ray and Neutron Detector (GRaND) on board the NASA Dawn spacecraft provide constraints on the abundance and distribution of Fe, Ca, Al, Mg, and other rock‐forming elements. From a circular, polar low‐altitude mapping orbit, GRaND sampled the regolith to decimeter depths with a spatial resolution of about 300 km. At this spatial scale, the variation in neutron absorption is about seven times lower than that of the Moon. The observed variation is consistent with the range of absorption for howardite whole‐rock compositions, which further supports the connection between Vesta and the howardite, eucrite, and diogenite meteorites. We find a strong correlation between neutron absorption and the percentage of eucritic materials in howardites and polymict breccias, which enables petrologic mapping of Vesta's surface. The distribution of basaltic eucrite and diogenite determined from neutron absorption measurements is qualitatively similar to that indicated by visible and near infrared spectroscopy. The Rheasilvia basin and ejecta blanket has relatively low absorption, consistent with Mg‐rich orthopyroxene. Based on a combination of Fe and neutron absorption measurements, olivine‐rich lithologies are not detected on the spatial scales sampled by GRaND. The sensitivity of GRaND to the presence of mantle material is described and implications for the absence of an olivine signature are discussed. High absorption values found in Vesta's “dark” hemisphere, where exogenic hydrogen has accumulated, indicate that this region is richer in basaltic eucrite, representative of Vesta's ancient upper crust.     

Evaluation of Two Energy Balance Closure Parametrizations

A general lack of energy balance closure indicates that tower-based eddy-covariance (EC) measurements underestimate turbulent heat fluxes, which calls for robust correction schemes. Two parametrization approaches that can be found in the literature were tested using data from the Canadian Twin Otter research aircraft and from tower-based measurements of the German Terrestrial Environmental Observatories (TERENO) programme. Our analysis shows that the approach of Huang et al. (Boundary-Layer Meteorol 127:273–292, 2008), based on large-eddy simulation, is not applicable to typical near-surface flux measurements because it was developed for heights above the surface layer and over homogeneous terrain. The biggest shortcoming of this parametrization is that the grid resolution of the model was too coarse so that the surface layer, where EC measurements are usually made, is not properly resolved. The empirical approach of Panin and Bernhofer (Izvestiya Atmos Oceanic Phys 44:701–716, 2008) considers landscape-level roughness heterogeneities that induce secondary circulations and at least gives a qualitative estimate of the energy balance closure. However, it does not consider any feature of landscape-scale heterogeneity other than surface roughness, such as surface temperature, surface moisture or topography. The failures of both approaches might indicate that the influence of mesoscale structures is not a sufficient explanation for the energy balance closure problem. However, our analysis of different wind-direction sectors shows that the upwind landscape-scale heterogeneity indeed influences the energy balance closure determined from tower flux data. We also analyzed the aircraft measurements with respect to the partitioning of the “missing energy” between sensible and latent heat fluxes and we could confirm the assumption of scalar similarity only for Bowen ratios $\approx $ 1.     

Coliform Bacteria in New Jersey Domestic Wells: Influence of Geology,Laboratory, and Method

Following passage of the New Jersey Private Well Testing Act, 50,800 domestic wells were tested between 2002 and 2007 for the presence of total coliform (TC) bacteria. Wells containing TC bacteria were further tested for either fecal coliform or Escherichia coli (FC/E. coli) bacteria. Analysis of the data, generated by 39 laboratories, revealed that the rate of coliform detections in groundwater (GW) was influenced by the laboratory and the method used, and also by geology. Based on one sample per well, TC and FC/E. coli were detected in wells located in bedrock 3 and 3.7 times more frequently, respectively, than in wells located in the unconsolidated strata of the Coastal Plain. In bedrock, detection rates were higher in sedimentary rock than in igneous or metamorphic rock. Ice‐age glaciers also influenced detection rates, most likely by removing material in some areas and depositing thick layers of unconsolidated material in other areas. In bedrock, coliform bacteria were detected more often in wells with a pH of 3 to 6 than in wells with a pH of 7 to 10 whereas the reverse was true in the Coastal Plain. TC and FC/E. coli bacteria were detected in 33 and 9.5%, respectively, of sedimentary rock wells with pH 3 to 6. Conversely, for Coastal Plain wells with pH 3 to 6, detection rates were 4.4% for TC and 0.6% for FC/E. coli.