Stratigraphy of total metals in PIRLA sediment cores

Sediment cores from 30 low-alkalinity lakes in northern New England (NE), New York (NY), the northern Great Lakes States (NGLS) of Minnesota, Michigan, and Wisconsin, and Florida (FL) have been dated by ²¹⁰Pb and analyzed for water and organic content, eight major elements (Al, Ti, Fe, Mn, Ca, Mg, Na, K) plus four trace metals (Pb, Zn, Cu, and V). Variations in the percentages of major elements through time are dominated by long-term independent variations in the abundance of SiO₂, FeO, and to a lesser extent Ca and Al. Additional variations are caused by varying proportions of inorganic matter. Major variations in chemistry are generally unrelated to documented distrubances in the watersheds; most disturbances are minor fires or selective logging.Accelerated accumulation of Pb from atmospheric sources into sediment first occurs in sediment dated between 1800 and 1850 in NY and NE, slightly later in the NGLS region, and about 1900 in FL. Modern accumulation rates in all areas are comparable (ca. 1 to 4 g cm^–2 yr^–1). Accumulation rates of Pb in some lakes have declined significantly from 1975 to 1985. Atmospheric deposition of anthropogenic Zn and Cu is also indicated by generally increasing accumulation rates in sediment cores, but the record is not as clear nor are chemical profiles in all lakes parallel to the trends in atmospheric emissions inferred on the basis of fossil fuel consumption, smelting, and other industrial activities. Inter-lake variations in profiles of Cu and Zn are large. Vanadium accumulation rates increase by the 1940s in NY and NE, but not until the 1950s in the NGLS region. This timing correlates with regional trends in the combustion of fuel oil, a major source of atmospheric V.Acidification of some of the lakes is suggested by decreases in the concentration and accumulation rates of Mn, Ca, and Zn in recent sediment, relative to other elements of catchment origin. The decreases generally occur slightly before the onset of acidification as indicated by diatoms. Increased sediment accumulation rates for Fe may indicate the acidification of watershed soils. The use of the accumulation rate of TiO₂ as an indicator of rates of erosion and for normalization of trace metal accumulation rates is in question for lakes where the flux of TiO₂ from the atmosphere varies and is a significant fraction of the total flux of TiO₂ to the sediment.This is the thirteenth of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.     

Strategies to mitigate aliasing of loading signals while estimating GPS frame parameters

Although GNSS techniques are theoretically sensitive to the Earth center of mass, it is often preferable to remove intrinsic origin and scale information from the estimated station positions since they are known to be affected by systematic errors. This is usually done by estimating the parameters of a linearized similarity transformation which relates the quasi-instantaneous frames to a long-term frame such as the International Terrestrial Reference Frame (ITRF). It is well known that non-linear station motions can partially alias into these parameters. We discuss in this paper some procedures that may allow reducing these aliasing effects in the case of the GPS techniques. The options include the use of well-distributed sub-networks for the frame transformation estimation, the use of site loading corrections, a modification of the stochastic model by downweighting heights, or the joint estimation of the low degrees of the deformation field. We confirm that the standard approach consisting of estimating the transformation over the whole network is particularly harmful for the loading signals if the network is not well distributed. Downweighting the height component, using a uniform sub-network, or estimating the deformation field perform similarly in drastically reducing the amplitude of the aliasing effect. The application of these methods to reprocessed GPS terrestrial frames permits an assessment of the level of agreement between GPS and our loading model, which is found to be about 1.5 mm WRMS in height and 0.8 mm WRMS in the horizontal at the annual frequency. Aliased loading signals are not the main source of discrepancies between loading displacement models and GPS position time series.     

Phosphorus retention in calcareous soils and the effect of organic matter on its mobility

A survey of the interactions between phosphorus (P) species and the components of calcareous soils shows that both surface reactions and precipitation take place, especially in the presence of calcite and limestone. The principal products of these reactions are dicalcium phosphate and octacalcium phosphate, which may interconvert after formation. The role of calcium carbonate in P retention by calcareous soils is, however, significant only at relatively high P concentrations – non-carbonate clays play a more important part at lower concentrations. In the presence of iron oxide particles, occlusion of P frequently occurs in these bodies, especially with forms of the element that are pedogenic in origin. Progressive mineralization and immobilization, often biological in nature, are generally observed when P is added as a fertilizer.     

Metamorphic history of the Jutogh Series in the Simla klippe,lower Himalayas

The metamorphic rocks of the Jutogh Series around Simla, structurally overlying the less metamorphosed rock groups along a thrust contact, have been involved in three phases of deformation and two episodes of metamorphism. The first metamorphism is in the albite-epidote-amphibolite facies in a major part of the area, reaching the amphibolite facies locally in the central part. This metamorphism is late-to post-kinematic with reference to the F ₁ movement, the thermal peak having been reached in a post-F ₁ pre-F ₂ static phase. The second metamorphism, syn-to post-tectonic with respect to F ₂ but preceding F ₃, is generally in the greenschist facies, and only locally in the albite-epidote-amphibolite facies in the higher structural levels. Metamorphic overprinting has caused widespread retrogression and disequilibrium assemblages. As the large scale recumbent folding and thrusting of F ₁ and F ₂ phases belong to the Tertiary Himalayan orogeny, the metamorphism in the Jutogh Series could not have been Precambrian in age.     

Tank damage during the may 1983 coalinga earthquake

The magnitude M = 6-5 Coalinga earthquake of 2 May 1983 caused intense ground shaking throughout the epicentral region. Unanchored cylindrical ground supported tanks located at six sites within this oil producing area were damaged; damages included elephant's foot buckling at the base of three moderate sized tanks, joint rupture and top shell buckling in one large old rivetted tank, bottom plate rupture of a relatively new welded tank and damage to the floating roofs of 11 tanks. Also oil spilled over the top of many tanks and secondary damages occurred in pipe connections, ladders, etc. In this paper an estimate is made of the intensity of ground motion at each of the tank sites, based on strong motion records made during the main shock and the strongest aftershock. Then response parameters specified by current codes are correlated with the damages observed at each tank site. Based on this comparison, it is concluded that current U.S. practice under-estimates the sloshing response of tanks with floating roofs and does not adequately address the uplifting mechanism of unanchored ground supported tanks.     

Complete preservation of ophiolite suite from south Andaman,India: A mineral-chemical perspective

Field studies supplemented by petrographic analyses clearly reveal complete preservation of ophiolite suite from Port Blair (11°39′N: 92°45′E) to Chiriyatapu (11°30′24″N: 92°42′30″E) stretch of South Andaman. The ophiolite suite reveals serpentinite at the base which is overlain unconformably by cumulate ultramafic-mafic members with discernible cumulus texture and igneous layering. Basaltic dykes are found to cut across the cumulate ultramafic-mafic members. The succession is capped by well exposed pillow basalts interlayered with arkosic sediments. Olivine from the basal serpentinite unit are highly magnesian (Fo_80.1–86.2). All clinopyroxene analyses from cumulate pyroxenite, cumulate gabbro and basaltic dyke are discriminated to be ‘Quad’ and are uniformly restricted to the diopside field. Composition of plagioclase in different lithomembers is systematically varying from calcic to sodic endmembers progressively from cumulate pyroxenite to pillow basalt through cumulate gabbro and basaltic dyke. Plagioclase phenocrysts from basaltic dyke are found to be distinctly zoned (An_60.7-An_35.3) whereas groundmass plagioclase are relatively sodic (An₃₃-An_23.5). Deduced thermobarometric data from different lithomembers clearly correspond to the observed preservation of complete ophiolite suite.     

Neutrino emission,population II stars and big-bang cosmology

The spectroscopic determination of the helium abundance in the oldest stars of the galaxy is supported by the theory of stellar evolution when neutrino emission is considered according to the photon-neutrino coupling theory, if it is assumed that the population II stars started their life with a low surface helium content.Receipt delayed by postal strike in Great Britain.     

The origin of selected lunar geochemical anomalies: Implications for early volcanism and the formation of light plains

The Apollo orbital geochemistry, photogeologic, and other remote sensing data sets were used to identify and characterize geochemical anomalies on the eastern limb and farside of the Moon and to investigate the processes responsible for their formation. The anomalies are located in the following regions: (1) Balmer basin, (2) terrain northeast of Mare Smythii, (3) near Langemak crater, (4) Pasteur crater, (5) terrain northwest of Milne basin, (6) northeast of Mendeleev basin, (7) north and northeast of Korolev basin, (8) terrain north of Taruntius crater, and (9) terrain north of Orientale basin. The anomalies are commonly associated with Imbrian- or Nectarian-aged light plains units which exhibit dark-haloed impact craters. The results of recent spectral reflectance studies of dark-haloed impact craters plus consideration of the surface chemistry of the anomalies strongly indicate that those geochemical anomalies associated with light plains deposits which display dark-haloed impact craters result from the presence of basaltic units that are either covered by varying thickness of highland debris or have a surface contaminated with significant amounts of highlands material. The burial or contamination of ancient volcanic surfaces by varying amounts of highland material appears to have been an important (though not the dominant) process in the formation of lunar light plains. Basaltic volcanism on the eastern limb and farside of the Moon was more extensive in both space and time than has been accepted.     

Application of soft computing techniques for shallow foundation reliability in geotechnical engineering

This research focuses on the application of three soft computing techniques including Minimax Probability Machine Regression(MPMR),Particle Swarm Optimization based Artificial Neural Network(ANN-PSO)and Particle Swarm Optimization based Adaptive Network Fuzzy Inference System(ANFIS-PSO)to study the shallow foundation reliability based on settlement criteria.Soil is a heterogeneous medium and the involvement of its attributes for geotechnical behaviour in soil-foundation system makes the prediction of settlement of shallow a complex engineering problem.This study explores the feasibility of soft computing techniques against the deterministic approach.The settlement of shallow foundation depends on the parametersγ(unit weight),e0(void ratio)and CC(compression index).These soil parameters are taken as input variables while the settlement of shallow foundation as output.To assess the performance of models,different performance indices i.e.RMSE,VAF,R^2,Bias Factor,MAPE,LMI,U(95),RSR,NS,RPD,etc.were used.From the analysis of results,it was found that MPMR model outperformed PSO-ANFIS and PSO-ANN.Therefore,MPMR can be used as a reliable soft computing technique for non-linear problems for settlement of shallow foundations on soils.     

The influence of dunes on mixing in a migrating salt‐wedge: Fraser River estuary,Canada

Dune bedforms and salt‐wedge intrusions are common features in many estuaries with sand beds, and yet little is known about the interactions between the two. Flow visualization with an echosounder and velocity measurements with an acoustic Doppler current profiler over areas of flat‐bed and sand dunes in the highly‐stratified Fraser River estuary, Canada, were used to examine the effect of dunes on interfacial mixing. As the salt‐wedge migrates upstream over the flat‐bed, mixing is restricted to the lower portion of the water column. However, as the salt‐wedge migrates into the dune field from the flat bed, there is a dramatic change in the flow, and large internal in‐phase waves develop over each of the larger dunes, with water from the salt‐wedge reaching the surface of the estuary. The friction Richardson number shows that bed friction is more important in interfacial mixing over the dunes than over the flat‐bed, and a plot of internal Froude Number versus obstacle (dune) height shows that the salt‐wedge flow over the dunes is mainly supercritical. Such bedforms can be expected to cause similar effects in interfacial mixing in other estuaries and sediment‐laden density currents, and may thus be influential in fluid mixing and sediment transport. Copyright © 2010 John Wiley & Sons, Ltd.