Humic acids: Their detergent qualities and potential uses in pollution remediation

Humic acids are amphiphilic species whose behavior in aqueous solution suggests that they form pseudomicelles–aggregates akin to the micelles familiar from synthetic surfactant chemistry. It is thought that humic pseudomicelles can be formed by both intramolecular coiling and intermolecular association, depending on the molecular weight, structural characteristics, and polydispersity of the humic acid in question. The process does not feature a critical micelle concentration. Experimental evidence indicates that metal ions enhance the detergent character of dissolved humic acid by facilitating the coiling and folding of the polymer chains. A recently conceived alternative model suggests that humic acids consist of relatively small subunits that associate through weak molecular interactions. This view appears to run counter to certain experimental observations, but deserves careful attention. The strong association between metal ions and solid humic acid makes it possible to use an inexpensive commercial grade for the decontamination of polluted water. A continuous elution process through a column packed with humic acid allows for the removal of both heavy metals and organic xenobiotics from aqueous solution.     

First-order regional seismotectonic model for South Africa

A first-order seismotectonic model was created for South Africa. This was done using four logical steps: geoscientific data collection, characterisation, assimilation and zonation. Through the definition of subunits of concentrations of earthquake foci and large neotectonic and structural domains, seismotectonic structures, systems and domains were created. Relatively larger controls of seismicity exist between the Great Escarpment and the coast. In the south, this region is characterised by large aeromagnetic anomalies and large EW trending faults. In the west, it is characterised by the NW–SE trending Wegener stress anomaly, radial-trending dykes and earthquake clusters. In the east, it is characterised by a large neotectonic domain where several large historical earthquakes occurred. In the centre of South Africa, several clusters of earthquake activity are found, often related to mining activity. Further north, seismicity is related to both mining activity and neotectonic deformation. This work contributes to the development of a seismotectonic model for South Africa by (1) bringing together, digitally, several data sets in a common GIS platform (geology, geophysics, stress, seismicity, neotectonics, topography, crustal and mantle structure and anisotropy), (2) understanding the significance of data sets for seismotectonic zonation and limitations thereof and (3) obtaining a reasonable regional model for use in seismic hazard assessments.     

A Local Example of Land‐Use Change: Southern Illinois—1807, 1938, and 1993*

This article provides an analysis of a wetland site in southern Illinois from presettlement to the present. The study area is part of the Cache River‐Cypress Creek Wetland, which has international importance, as recognized by the Ramsar Convention on Wetlands. Land‐cover data for 1807, 1938, and 1993 were created and analyzed with a geographic information system (GIS). Land‐use change by topographic setting (uplands, transitional, and bottomlands) and soil productivity was quantified and studied. Interviews with local experts informed this analysis. Results illustrate the complexity of environmental change and its driving forces. First, notable forest and swamp acreage was converted to cropland between 1807 and 1938 and, to a lesser degree, from 1938 to 1993. Second, there were land‐use variations by topographic region. Between 1807 and 1938, the largest transformation occurred in the uplands, with substantial acreage converted from forest to cropland. Between 1938 and 1993, however, agriculture decreased in the upland areas as hilly areas reverted to forest cover. At the same time, agriculture expanded in the bottomlands as this land was drained for farming. Third, there are interesting patterns within these categories of land‐use change, as soil productivity is an indicator of what lands were taken out of cropland and converted back to grassland and forest.     

The origin of selected lunar geochemical anomalies: Implications for early volcanism and the formation of light plains

The Apollo orbital geochemistry, photogeologic, and other remote sensing data sets were used to identify and characterize geochemical anomalies on the eastern limb and farside of the Moon and to investigate the processes responsible for their formation. The anomalies are located in the following regions: (1) Balmer basin, (2) terrain northeast of Mare Smythii, (3) near Langemak crater, (4) Pasteur crater, (5) terrain northwest of Milne basin, (6) northeast of Mendeleev basin, (7) north and northeast of Korolev basin, (8) terrain north of Taruntius crater, and (9) terrain north of Orientale basin. The anomalies are commonly associated with Imbrian- or Nectarian-aged light plains units which exhibit dark-haloed impact craters. The results of recent spectral reflectance studies of dark-haloed impact craters plus consideration of the surface chemistry of the anomalies strongly indicate that those geochemical anomalies associated with light plains deposits which display dark-haloed impact craters result from the presence of basaltic units that are either covered by varying thickness of highland debris or have a surface contaminated with significant amounts of highlands material. The burial or contamination of ancient volcanic surfaces by varying amounts of highland material appears to have been an important (though not the dominant) process in the formation of lunar light plains. Basaltic volcanism on the eastern limb and farside of the Moon was more extensive in both space and time than has been accepted.     

Discrimination of Spectrally-Close Crops Using Ground-Based Hyperspectral Data

Hyperspectral remote sensing, because of its large number of narrow bands, has shown possibility of discriminating the crops. Current study was carried out to select the optimum bands for discrimination among pulses, cole crops and ornamental plants using the ground-based Hyperspectral data in Patha village, Lalitpur district, Uttar Pradesh state and Kolkata, West Bengal state. The field observations of reflectance were taken using a 512-channel spectroradiometer with a range of 325–1075 nm. The stepwise discriminant analysis was carried out and separability measures, such as Wilks’ lambda and F-Value were used as criteria for identifying the narrow bands. The analysis showed that, the best four bands for pulse crop discrimination lie mostly in NIR and early MIR regions i.e. 750, 800, 940 and 960 nm. Within cole crops discrimination is primarily determined by the green, red and NIR bands of 550, 690, 740, 770 and 980 nm. The separability study showed the bands 420,470,480,570,730,740, 940, 950, 970, 1030 nm are useful for discriminating flowers.     

GMOS spectroscopy of the S0 galaxy NGC 3115

We present Gemini Multi-Object Spectrograph longslit spectroscopy of the isolated S0 galaxy NGC 3115. We have determined kinematical data and Lick/IDS absorption line-strength indices for the major axis out to around 9 kpc and for the minor axis out to around 5 kpc (around 2R _e ). Using stellar population models which include the effects of variable [α/Fe] ratios, we derive metallicities, abundance ratios and ages for the stellar population of NGC 3115. We find that [α/Fe] remains fairly constant with increasing radius at around  [α/Fe]= 0.17  for the major axis but increases rapidly for the minor axis to around  [α/Fe]= 0.3  . We also find that to first order, this behaviour can be explained by a simple spheroid + disc model, where the spheroid has  [α/Fe]= 0.3  and the disc shows close to solar abundance ratios. The disc also appears considerably younger than the spheroid, having an age of around 6 Gyr compared to 12 Gyr for the spheroid. We compare these results to those previously presented for the globular cluster system of NGC 3115.     

High iridium concentration of alkaline rocks of Deccan and implications to K/T boundary

We report here an unusually high concentration of iridium in some alkali basalts and alkaline rocks of Deccan region having an age of about 65Ma, similar to the age of the Cretaceous-Tertiary boundary. The alkali basalts of Anjar, in the western periphery of Deccan province, have iridium concentration as high as 178pg/g whereas the alkaline rocks and basalts associated with the Amba Dongar carbonatite complex have concentrations ranging between 8 and 80 pg/g. Some of these values are more than an order of magnitude higher than the concentration in the tholeiitic basalts of Deccan, indicating the significance of alkaline magmatism in the iridium inventory at the Cretaceous-Tertiary boundary. Despite higher concentration, their contribution to the global inventory of iridium in the Cretaceous-Tertiary boundary clays remains small. The concentration of iridium in fluorites from Amba Dongar was found to be <30 pg/g indicating that iridium is not incorporated during their formation in hydrothermal activity.     

Evidence of melt/rock interaction in the Cr-spinel bearing wehrlite rocks of Bangriposi,India: Implications for nature of the metasomatic agent

Cr-spinel bearing wehrlite rocks of Bangriposi are found within the multiply deformed metasedimentary rocks of Singhbhum Group belonging to North Singhbhum Mobile Belt of eastern India. Detailed mineralogical and geochemical studies reveal that these rocks have suffered a two-stage alteration involving a deeper level modal and cryptic metasomatism and a subsequent shallower depth pervasive hydrothermal alteration. Cryptic metasomatism is defined by elevated LREE contents of the wehrlite and its clinopyroxne grains. Metasomatism induced changes in the modal mineralogy of the rocks include the absence of primary orthopyroxene grains, presence of secondary diopside-phlogopite(now present as vermiculite) defining disequilibrium reaction textures and secondary orthopyroxene rims around serpentinized olivine. The mineralogical and geochemical changes due to the metasomatic event present a contrasting picture in regard to the metasomatic history of the rocks. Possible scenarios involving a single stage or multiple stage metasomatism events have been discussed while explaining the metasomatic reactions that took place. An attempt has been made to estimate the REE concentrations of the final equilibrating melt from REE contents of clinopyroxene grains of the wehrlite. The possibility of the LREE-enriched equilibrating melt of the wehrlite rocks(the deeper level metasomatic agent) being similar to residual melts from the E-MORB type parental melts of nearby gabbro suite has been ruled out by geochemical modeling. REE abundance patterns of several natural enriched melts have been compared with REE pattern of calculated LREE-enriched equilibrating melt of the wehrlite and most resemblance has been observed with calcic and potassic melts. It is therefore suggested that the Cr-spinel bearing wehrlite rocks of Bangriposi has been affected by a calcio-potassic melt in deeper level, prior to the shallow level serpentinization event.