Removal of Pyridine from Aqueous Solution by Adsorption on an Activated Carbon Cloth

Pyridine is a very toxic pollutant that has to be removed from wastewater. In this work, adsorption of pyridine on activated carbon cloth (ACC) is studied as a possible alternative for eliminating pyridine from aqueous solution. The ACC was produced from polyacrylonitrile. The adsorption equilibrium data of pyridine on ACC was obtained in a batch adsorber. The experimental data was interpreted with the isotherms of Langmuir, Freundlich, and Prausnitz‐Radke (PR), and the PR isotherm better represented the experimental data. The capacity of ACC for adsorbing pyridine was favored increasing the solution pH from 3 to 6, and this effect was due to the π–π dispersive and electrostatic interactions between the pyridine species in solution and the surface complexes of ACC. The modified Langmuir model fitted reasonably well the influence of pH on the adsorption capacity. In this model was assumed that both neutral pyridine and pyridinium were simultaneously adsorbed on ACC accordingly to the experimental results. The adsorption capacity was almost independent of temperature. The reversibility study revealed that 75% of the pyridine can be desorbed from ACC indicating that part of the pyridine was irreversibly adsorbed, and possibly chemisorbed.     

Earthquake dynamics on circular faults: a review 1970–2015

We review the development of earthquake dynamics taken from the point of view of the origin of seismic radiation instead of the detailed study of rupture propagation on complex surfaces. Many features of seismic radiation can be explained by simple models that serve as elementary canonical problems. Some of these properties are very well known like the fact that at low frequencies, the seismic spectrum is proportional to the seismic moment. At high frequencies, on the other hand, radiation is generated by the motion of the rupture front, in particular stopping phases and geometrical obstacles (barriers). A rupture front moving at constant speed does not produce far-field radiation. For many practical applications, for determining source size and stress drop, for example, it is not necessary to determine geometrical details of the rupture. For such cases, a simple circular crack model is quite sufficient. An improvement on this method is to do dynamic inversion on simple, elliptical-shaped sources and letting the rupture start arbitrarily from a point on the fault. This problem can be solved nowadays with finite differences and a variety of inversion techniques.     

Identification of High Frequency Pulses from Earthquake Asperities Along Chilean Subduction Zone Using Strong Motion

The Chilean subduction zone is one of the most active of the world with M?=?8 or larger interplate thrust earthquakes occurring every 10?years or so on the average. The identification and characterization of pulses propagated from dominant asperities that control the rupture of these earthquakes is an important problem for seismology and especially for seismic hazard assessment since it can reduce the earthquake destructiveness potential. A number of studies of large Chilean earthquakes have revealed that the source time functions of these events are composed of a number of distinct energy arrivals. In this paper, we identify and characterize the high frequency pulses of dominant asperities using near source strong motion records. Two very well recorded interplate earthquakes, the 1985 Central Chile (Ms?=?7.8) and the 2007 Tocopilla (Mw?=?7.7), are considered. In particular, the 2007 Tocopilla earthquake was recorded by a network with absolute time and continuos recording. From the study of these strong motion data it is possible to identify the arrival of large pulses coming from different dominant asperities. The recognition of the key role of dominant asperities in seismic hazard assessment can reduce overestimations due to scattering of attenuation formulas that consider epicentral distance or shortest distance to the fault rather than the asperity distance. The location and number of dominant asperities, their shape, the amplitude and arrival time of pulses can be one of the principal factors influencing Chilean seismic hazard assessment and seismic design. The high frequency pulses identified in this paper have permitted us to extend the range of frequency in which the 1985 Central Chile and 2007 Tocopilla earthquakes were studied. This should allow in the future the introduction of this seismological result in the seismic design of earthquake engineering.     

Potential risk of harmful algae transport by ballast waters: the case of Bilbao Harbour

Ballast water exchange was measured for the first time in Bilbao Harbour, one of the most active of northern Spain. Between 1997 and 2006, 41,900,980.34 ballast water tn were loaded and 13,272,709 tn were discharged. Bilbao Harbour appears to be mainly a source of ballast water, 90% of which would be discharged in European harbours. We estimated that vessels carrying liquid and solid bulk have higher probabilities of exporting ballast water, whereas those with liquid bulk and containers are more likely to introduce it. From 30 potentially harmful phytoplankton species identified to date near harbour facilities, there would be a high risk of exporting at least Alexandrium minutum, Dinophysis sp., Heterosigma akashiwo, Karlodinium sp., Ostreopsis cf. siamensis, Pfiesteria-like and Prorocentrum minimum. Invasion risk by ballast water was tested by analyzing the response of six strains of H. akashiwo from different geographic areas to varying salinity. Results show that successful growth of foreign strains would be possible.     

Location of Moderate-Sized Earthquakes Recorded by the NARS�CBaja Array in the Gulf of California Region Between 2002 and 2006

We relocated the hypocentral coordinates of small to moderate-sized earthquakes reported by the National Earthquake Information Center (NEIC) between April 2002 and August 2006 in the Gulf of California region and recorded by the broadband stations of the network of autonomously recording seismographs (NARS?CBaja array). The NARS?CBaja array consists of 19 stations installed in the Baja California peninsula, Sonora and Sinaloa, Mexico. The events reported by the preliminary determinations of epicenters (PDE) catalog within the period of interest have moment magnitudes (M _w) ranging between 1.1 and 6.7. We estimated the hypocentral location of these events using P and S wave arrivals recorded by the regional broadband stations of the NARS?CBaja and the RESBAN (Red Sismológica de Banda Ancha) arrays and using a standard location procedure with the HYPOCENTER code (Lienert and Havskov in Seism Res Lett 66:26?C36, 1995) as a preliminary step. To refine the location of the initial hypocenters, we used the shrinking box source-specific station term method of Lin and Shearer (J Geophys Res 110, B04304, 2005). We found that most of the seismicity is distributed in the NW?CSE direction along the axis of the Gulf of California, following a linear trend that, from north to south, steps southward near the main basins (Wagner, Delfin, Guaymas, Carmen, Farallon, Pescadero and Alarcon) and spreading centers. We compared the epicentral locations reported in the PDE with the locations obtained using regional arrival times, and we found that earthquakes with magnitudes in the range 3.2?C5.0?mb differ on the average by as much as 43?km. For the M _w magnitude range between 5 and 6.7 the discrepancy is less, differing on the average by about 25?km. We found that the relocated epicenters correlate well with the main bathymetric features of the Gulf.     

Application of HF radar currents to oil spill modelling

In this work, the benefits of high-frequency (HF) radar currents for oil spill modeling and trajectory analysis of floating objects are analyzed. The HF radar performance is evaluated by means of comparison between a drifter buoy trajectory and the one simulated using a Lagrangian trajectory model. A methodology to optimize the transport model performance and to calculate the search area of the predicted positions is proposed. This method is applied to data collected during the Galicia HF Radar Experience. This experiment was carried out to explore the capabilities of this technology for operational monitoring along the Spanish coast. Two long-range HF radar stations were installed and operated between November 2005 and February 2006 on the Galician coast. In addition, a drifter buoy was released inside the coverage area of the radar. The HF radar currents, as well as numerical wind data were used to simulate the buoy trajectory using the TESEO oil spill transport model. In order to evaluate the contribution of HF radar currents to trajectory analysis, two simulation alternatives were carried out. In the first one, wind data were used to simulate the motion of the buoy. In the second alternative, surface currents from the HF radar were also taken into account. For each alternative, the model was calibrated by means of the global optimization algorithm SCEM-UA (Shuffled Complex Evolution Metropolis) in order to obtain the probability density function of the model parameters. The buoy trajectory was computed for 24 h intervals using a Monte Carlo approach based on the results provided in the calibration process. A bivariate kernel estimator was applied to determine the 95% confidence areas. The analysis performed showed that simulated trajectories integrating HF radar currents are more accurate than those obtained considering only wind numerical data. After a 24 h period, the error in the final simulated position improves using HF radar currents. Averaging the information from all the simulated daily periods, the mean search and rescue area calculated using HF radar currents, is reduced by approximately a 62% in comparison with the search area calculated without these data. These results show the positive contribution of HF radar currents for trajectory analysis, and demonstrate that these data combined with atmospheric forecast models, are of value for trajectory analysis of oil spills or floating objects.     

Origin of biotite-apatite-rich enclaves, Achala batholith, Argentina

The Achala batholith of Argentina contains very unusual layered enclaves containing up to 30% apatite and 50% biotite in some layers. This modal mineralogy produces bulk-rock compositions that cannot represent liquids, having as little as 29% SiO₂ and up to 8% P₂O₅. Nor can the enclaves represent metasedimentary xenoliths because: (1) none of the Precambrian wall rocks has these compositions; (2) none of the metasedimentary xenoliths present within the batholith shows any degree of transition to the mica-apatite-rich enclaves; (3) the compositions and textures in the enclaves are inconsistent with metasediments; (4) a geochronological study of zircon from an enclave gives an age of 368 ± 2 Ma, the exact age of zircons in the granitic host rocks. For these reasons, we conclude that the enclaves are neither xenoliths of Precambrian wall rocks nor restite of a Precambrian source. The identical age of the enclave and the host granites, coupled with textural, mineralogical, and bulk-rock characteristics of the enclaves, indicates that the enclaves are magmatic segregations, i.e., cumulates. The F-rich nature of the stubby-shaped apatites and biotites indicates a high F content of the magma parental to the enclaves. We infer that the viscosity of the melt was lowered sufficiently to allow cumulates to form in spite of the granitic composition of the melt. Received: 12 December 1996 / Accepted: 11 August 1997     

Rupture process of the 19 August 1992 Susamyr, Kyrgyzstan, earthquake

The Susamyr earthquake of August 19, 1992 in Kyrgyzstan is one of the largest events (M_s = 7.4, M_b = 6.8) of this century in this region of Central Asia. We used broadband and long period digital data from IRIS and GEOSCOPE networks to investigate the source parameters, and their space-time distribution by modeling both body and surface waves. The seismic moment (M₀ = 6.8 × 10¹⁹ N m) and the focal mechanism were determined from frequency-time analysis (FTAN) of the fundamental mode of long period surface waves (100–250 s). Then, the second order integral moments of the moment-rate release were estimated from the amplitude spectra of intermediate period surface waves(40–70 s). From these moments we determined a source duration of 11–13 s, major and minor axes of the source of 30 km and 10–22 km, respectively; and an instant centroid velocity of 1.2 km/s. Finally, we performed a waveform inversion of P and SH waves at periods from 5–60 s. We found a source duration of 18–20 s, longer than the integral estimate from surface wave amplitudes. All the other focal parameters inverted from body waves are similar to those obtained by surface waves ( = 87° ± 6°, = 49° ± 6°, = 105° ± 3°, h = 14 ± 2 km, and M₀ = 5.8 ± 0.7 × 10¹⁹ N m). The initial rupture of this shallow earthquake was located at the south-west border of Susamyr depression in the western part of northern Tien Shan. A finite source analysis along the strike suggests a westward propagation of the rupture. The main shock of this event was preceded 2 s earlier by small foreshock. The main event was almost immediately followed by a very strong series of aftershocks. Our surface and body wave inversion results agree with the general seismotectonic features of the region.