Seasonal DOC accumulation in the Black Sea: a regional explanation for a general mechanism

During three cruises in the Black Sea, organised in July 1995 and April–May 1997, biological and chemical parameters that can influence the carbon budget were measured in the water column on the NW shelf, particularly in the mixing zone with Danube River waters. We observed in early spring (end of April–May) conditions an important input of freshwater organisms that enhanced the microbial activity in the low salinity range. High bacterial activity regenerates nitrogen in the form of nitrates, but is also responsible for an important consumption of ammonium and phosphate, leading to a high N/P ratio and a strong deficit in phosphorus. The consequence is a limitation of phytoplankton development but also a production of carbohydrates that accumulate all along the salinity gradient. These mechanisms are responsible for a seasonal accumulation of dissolved organic carbon (DOC) that increases from 210 μM in winter to about 280 μM in summer. All this excess DOC disappears during winter, probably degraded by bacterial activity. The degradation of carbon-rich organic matter increases the phosphorus demand by bacteria bringing limitation to phytoplankton primary production.     

Debating clean energy: Frames,counter frames,and audiences

In the United States, both scholars and practitioners have repeatedly emphasized the importance of “issue framing” for garnering public support for climate change policy. However, the debate frequently overlooks the importance of counter frames. For every framing attempt by advocates of climate policy, there will be a counter frame by the opponents of climate policy. How do counter frames influence the effectiveness of issue framing as a communication strategy? To answer this question, we report results from a survey experiment on a nationally representative sample of 1000 Americans on clean energy policy, a key policy issue in the public debate on climate change in the United States. Overall, we find that different combinations of positive and negative frames have remarkably little effect on support for clean energy policy. A follow-up on-line survey experiment with a convenience sample of 2000 Americans suggests that the counter frames are responsible for undermining the effects of the original frames.     

Derivation of Structure Parameters of Temperature and Humidity in the Convective Boundary Layer from Large-Eddy Simulations and Implications for the Interpretation of Scintillometer Observations

We derive the turbulent structure parameters of temperature $C_{T}^2$ and humidity $C_q^2$ from high-resolution large-eddy simulations (LES) of a homogeneously-heated convective boundary layer. Boundary conditions and model forcing were derived from measurements at Cabauw in The Netherlands. Three different methods to obtain the structure-parameters from LES are investigated. The shape of the vertical structure-parameter profiles from all three methods compare well with former experimental and LES results. Depending on the method, deviations in the magnitude up to a factor of two are found and traced back to the effects of discretization and numerical dissipation of the advection scheme. Furthermore, we validate the LES data with airborne and large-aperture scintillometer (LAS) measurements at Cabauw. Virtual path measurements are used to study the variability of $C_{T}^2$ in the mixed layer and surface layer and its implications for airborne and LAS measurements. A high variability of $C_{T}^2$ along a given horizontal path in the LES data is associated with plumes (high values) and downdrafts (low values). The path average of $C_{T}^2$ varies rapidly in time due to the limited path length. The LES results suggest that measured path averages require sufficient temporal averaging and an adequate ratio of path length to height above the ground for the LAS in order to approach the domain average of $C_{T}^2$ .     

Evolution of the Parisian urban climate under a global changing climate

The evolution of the Parisian urban climate under a changing climate is analyzed from long-term offline numerical integrations including a specific urban parameterization. This system is forced by meteorological conditions based on present-climate reanalyses (1970–2007), and climate projections (2071–2099) provided by global climate model simulations following two emission scenarios (A1B and A2). This study aims at quantifying the impact of climate change on air temperature within the city and in the surroundings. A systematic increase of 2-meter air temperature is found. In average according to the two scenarios, it reaches +?2.0/2.4°C in winter and +?3.5/5.0°C in summer for the minimum and maximum daily temperatures, respectively. During summer, the warming trend is more pronounced in the surrounding countryside than in Paris and suburbs due to the soil dryness. As a result, a substantial decrease of the strong urban heat islands is noted at nighttime, and numerous events with negative urban heat islands appear at daytime. Finally, a 30% decrease of the heating degree days is quantified in winter between present and future climates. Inversely, the summertime cooling degree days significantly increase in future climate whereas they are negligible in present climate. However, in terms of accumulated degree days, the increase of the demand in cooling remains smaller than the decrease of the demand in heating.     

Kuramoto Model of Nonlinear Coupled Oscillators as a Way for Understanding Phase Synchronization: Application to Solar and Geomagnetic Indices

We apply a Kuramoto model of nonlinear coupled oscillators to the simulation of slow variations of the phase difference between sunspot number [R _I ] and geomagnetic indices [aa and ζ]. The Kuramoto model is described for the particular case of two oscillators connected by symmetric coupling with quasi-stationary behavior, and its properties are investigated. By solving an inverse problem, we reconstruct the evolution of the couplings between pairs of indices [R _I and aa, R _I and ζ, aa and ζ], and interpret these in terms of the physics of the solar dynamo. The de-correlation between R _I and geomagnetic indices found in Solar Cycle 20 by Le Mouël et al. (J. Geophys. Res. 117, A09103, 2012) is successfully reproduced by the Kuramoto model and corresponds to the alternation of the leading oscillator. Application of the Kuramoto model to the cross-correlations [C(R _I ,ζ) and C(aa,ζ)] for ζ-indices computed in eight geomagnetic stations shows the latitudinal dependence of the mean phase difference. We discuss these results in terms of the solar-wind contribution to local geomagnetic indices [ζ].     

Geochemical constraints on the origin and tectonic setting of the serpentinized peridotites from the Paleoproterozoic Nyong series,Eseka area,SW Cameroon

Serpentinized rocks closely associated with Paleoproterozoic eclogitic metabasites were recently discovered at Eseka area in the northwestern edge of the Congo craton in southern Cameroon. Here, we present new field data, petrography, and first comprehensible whole-rock geochemistry data and discuss the protolith and tectonic significance of these serpentinites in the region. The studied rock samples are characterized by pseudomorphic textures, including mesh microstructure formed by serpentine intergrowths with cores of olivine, bastites after pyroxene. Antigorite constitutes almost the whole bulk of the rocks and is associated (to the less amount) with tremolite, talc, spinel, and magnetite. Whole-rock chemistry of the Eseka serpentinites led to the distinction of two types. Type 1 has high MgO (> 40 wt%) content and high Mg# values (88.80) whereas Type 2 serpentinite samples display relatively low MgO concentration and Mg# values (< 40 and 82.88 wt%, respectively). Both types have low Al/Si and high Mg/Si ratios than the primitive mantle, reflecting a refractory abyssal mantle peridotite protolith. Partial melting modeling indicates that these rocks were derived from melting of spinel peridotite before serpentinization. Bulk rock high-Ti content is similar to the values of subducted serpentinites (> 50 ppm). This similarity, associated with the high Cr contents, spinel-peridotite protolith compositions and Mg/Si and Al/Si ratios imply that the studied serpentinites were formed in a subduction-related environment. The U-shaped chondrite normalized-REE patterns of serpentinized peridotites, coupled with similar enrichments in LREE and HFSE, suggest the refertilized nature due to melt/rock interaction prior to serpentinization. Based on the results, we suggest that the Eseka serpentinized peridotites are mantle residues that suffered a high degree of partial melting in a subduction-related environment, especially in Supra Subduction Zone setting. These new findings suggest that the Nyong series in Cameroon represents an uncontested Paleoproterozoic suture zone between the Congo craton and the São Francisco craton in Brazil.

     

External controls on the distribution,fabrics and mineralization of modern microbial mats in a coastal hypersaline lagoon,Cayo Coco (Cuba)

Active, carbonate‐mineralizing microbial mats flourish in a tropical, highly evaporative, marine‐fed lagoonal network to the south of Cayo Coco Island (Cuba). Hypersaline conditions support the development of a complex sedimentary microbial ecosystem with diverse morphologies, a variable intensity of mineralization and a potential for preservation. In this study, the role of intrinsic (i.e. microbial) and extrinsic (i.e. physicochemical) controls on microbial mat development, mineralization and preservation was investigated. The network consists of lagoons, forming in the interdune depressions of a Pleistocene aeolian substratum; they developed due to a progressive increase in sea‐level since the Holocene. The hydrological budget in the Cayo Coco lagoonal network changes from west to east, increasing the salinity. This change progressively excludes grazers and increases the saturation index of carbonate minerals, favouring the development and mineralization of microbial mats in the easternmost lagoons. Detailed mapping of the easternmost lagoon shows four zones with different flooding regimes. The microbial activity in the mats was recorded using light–dark shifts in conjunction with microelectrode O₂ and HS^? profiles. High rates of O₂ production and consumption, in addition to substantial amounts of exopolymeric substances, are indicative of a potentially strong intrinsic control on mineralization. Seasonal, climate‐driven water fluctuations are key for mat development, mineralization, morphology and distribution. Microbial mats show no mineralization in the permanently submersed zone, and moderate mineralization in zones with alternating immersion and exposure. It is suggested that mineralization is also driven by water‐level fluctuations and evaporation. Mineralized mats are laminated and consist of alternating trapping and binding of grains and microbially induced magnesium calcite and dolomite precipitation. The macrofabrics of the mats evolve from early colonizing Flat mats to complex Cerebroid or Terrace structures. The macrofabrics are influenced by the hydrodynamic regime: wind‐driven waves inducing relief terraces in windward areas and flat morphologies on the leeward side of the lagoon. Other external drivers include: (i) storm events that either promote (for example, by bioclasts covering) or prevent (for example, by causing erosion) microbial mat preservation; and (ii) subsurface degassing, through mangrove roots and desiccation cracks covered by Flat mats (i.e. forming Hemispheroids and Cerebroidal structures). These findings provide in‐depth insights into understanding fossil microbialite morphologies that formed in lagoonal settings.     

Radiative heating of carbonaceous near-Earth objects as a cause of thermal metamorphism for CK chondrites

Metamorphic CK carbonaceous chondrites display matrix textures that are best explained by a transient thermal event with temperatures in the 550–950 K range and durations in the order of days to years, longer than what is commonly admitted for shock events but shorter than what is required for nuclide decay. We propose that radiative heating of small carbonaceous meteoroids with perihelia close to the Sun could account for the petrological features observed in CK chondrites. Numerical thermal modeling, using favorable known NEOs orbital parameters (perihelion distances between 0.07 and 0.15 AU) and physical properties of CV and CK chondrites (albedo in the range 0.01–0.1, 25% porosity, thermal diffusivity of 0.5–1.5 W m^?1 K^?1), shows that radiative heating can heat carbonaceous meteoroids in the meter size range to core temperatures up to 1050 K, consistent with the metamorphic temperatures estimated for CK chondrites. Sizes of known CV and CK chondrites indicate that all these objects were small meteoroids (radii from a few cm to 2.5 m) prior to their atmospheric entry. Simulations of dynamic orbits for NEO objects suggest that there are numerous such bodies with suitable orbits and properties, even if they are only a small percentage of all NEOs. Radiative heating would be a secondary process (superimposed on parent-body processes) affecting meteoroids formed by the disruption of an initially homogeneous CV3-type parent body. Different petrologic types can be accounted for depending on the sizes and heliocentric distances of the objects in such a swarm.