Deposition and fate of reactive Fe,Mn, P,and C in suspended particulate matter in the Bay of Biscay

Hydrographic structure of the water column, dissolved nutrient concentrations and the distribution of suspended particulate matter were recorded from CDT measurements and Niskin bottles sampling on the continental slope of the Bay of Biscay and on the axis of Capbreton canyon. Ascorbate extraction was applied here for the first time on marine suspended particles to determine the content of reactive Fe- and Mn-oxides, and P associated with Fe-oxides. Hydrographic structure of the south-eastern part of the Bay of Biscay did not change during the last three decades. Particulate organic carbon (POC) contents dropped strongly with depth, showing that organic matter mineralization was efficient in the water column. Organic matter mineralized in the water column had a Redfield N:P ratio. POC percent of particles collected at depth were higher during a bloom period, suggesting that some new organic matter reached the bottom. Contents of Fe and Mn extracted with the ascorbate leaching solution showed that suspended particles originated from the Gironde estuary, one of the major sources of particles in the Bay of Biscay. Intermediate and deeper nepheloid layers occurred in the Capbreton canyon. Particles of nepheloid layers were enriched in Mn- and Fe-oxides because they originated from resuspension of surface sediment.     

Chondrules in CK carbonaceous chondrites and thermal history of the CV–CK parent body

CK chondrites are the only group of carbonaceous chondrites with petrologic types ranging from 3 to 6. It is commonly reported than ~15 vol% of CK4–6 samples are composed of chondrules. The modal abundance of chondrules estimated here for 18 CK3–6 (including five CK3s) ranges from zero (totally recrystallized) to 50.5%. Although almost all chemically re‐equilibrated with the host matrix, we recognized in CK3s and Tanezrouft (Tnz) 057 (CK4) up to 85% of chondrules as former type I chondrules. Mean diameters of chondrules range from 0.22 to 1.05 mm for Karoonda (CK4) and Tnz 057 (CK4), respectively. Up to ~60% of chondrules in CK3–4 are surrounded by igneous rims (from ~20 μm to 2 mm width). Zoned olivines were found in unequilibrated chondrules from DaG 431 (CK3‐an), NWA 4724 (CK3.8), NWA 4423 (CK3.9), and Tnz 057 (CK4). We modeled Fe/Mg interdiffusion profiles measured in zoned olivines to evaluate the peak metamorphic temperatures and time scales of the CK parent body metamorphism, and proposed a two‐stage diffusion process in order to account for the position of inflection points situated within chondrules. Time scales inferred from Fe/Mg interdiffusion in olivine from unequilibrated chondrules are on the order of tens to a hundred thousand years (from 50 to 70,000 years for peak metamorphic temperatures of 1140 and 920 K, respectively). These durations are longer than what is commonly accepted for shock metamorphism and shorter than what is required for nuclide decay. Using the concept of a continuous CV–CK metamorphic series, which is reinforced by this study, we estimated peak metamorphic temperatures <850 K for CV, 850–920 K for CK3, and 920–1140 K for CK4–6 chondrites considering a duration of 70,000 years.     

Slow and Fast Rotating Coronal Holes from Geomagnetic Indices

The evolution of the 27-day recurrence in the series of two solar indices (Wolf number WN and 10.7 cm radio flux F) and two geomagnetic indices (Dst and ζ, variance of the geomagnetic field recorded at a magnetic observatory) have been studied over the 1957 – 2007 time span. Spectral energies contained in two period domains (25 – 27.3 and 27.3 – 31 days), designated as E ₁ and E ₂, have been computed. Whereas the evolution of E ₁ is the same for the four indices, that of E ₂ is essentially different for WN and F on the one hand, Dst and ζ on the other hand. Some general conclusions on the dynamics of the solar outer layers are inferred from these results. First the solar activity, as measured by WN, and when averaged over a few years, evolves in the same way whatever the latitude. Second, two families of coronal holes (CHs) are identified; the rapidly and the slowly rotating CHs evolve quite differently.     

Anthropogenic influence on the planktonic community in the basin of Mamala Bay (Oahu Island,Hawaii) based on field and satellite data

The anthropogenic impact on the biomass of coastal plankton communities caused by submerged disposal of urban sewage waters (dumping) was studied. The observations were carried out in August–September of 2002–2004 in Mamala Bay (Oahu Island, Hawaii) using satellite and sea truth methods. An analysis of the variability of the integral indicators of the water column determined on the basis of shipborne measurements allowed us to divide them into two groups: the elements most sensitive to the pollution (heterotrophic bacteria (H-Bact), the phototrophic cyanobacteria Synechococcus spp. (SYN), and chlorophyll a (CHLa)) and the elements that manifested episodic positive dependence on the inflow of the polluted waters (heterotrophic unicellular eukaryotes, small unicellular algae, the phototrophic green bacteria Prochlorococcus spp., as well as the total biomass of microplankton). It was shown that the submerged wastewater disposal in the region of the diffuser of the dumping device led to an insignificant (1.2–1.4 times, on the average) local increase in the integral biomass of H-Bact, SYN, and in the content of CHLa. A similar but sharper (1.5–2.1, on the average) increase in these parameters was found in the water layers with maximal biomasses. The possible pathways of disposed waters (under the pycnocline, at its upper boundary, and in the entire mixed layer) were analyzed on the basis of studying the vertical displacement of the biomasses of H-Bact, SYN, and prochlorophytes. The possibility of using the optical anomalies distinguished from satellite data as markers of anthropogenic eutrophication caused by dumping was confirmed. Application of such markers depends on the water transparency and on the shapes of the curves of the vertical distribution of autotrophic organisms.     

Distribution and temporal variation of mega‐fauna at the Regab pockmark (Northern Congo Fan), based on a comparison of videomosaics and geographic information systems analyses

The Regab pockmark is a large cold seep area located 10 km north of the Congo deep sea channel at about 3160 m water depth. The associated ecosystem hosts abundant fauna, dominated by chemosynthetic species such as the mussel Bathymodiolus aff. boomerang, vestimentiferan tubeworm Escarpia southwardae, and vesicomyid clams Laubiericoncha chuni and Christineconcha regab. The pockmark was visited during the West African Cold Seeps (WACS) cruise with RV Pourquoi Pas? in February 2011, and a 14,000‐m² high‐resolution videomosaic was constructed to map the most populated area and to describe the distribution of the dominant megafauna (mussels, tubeworms and clams). The results are compared with previous published works, which also included a videomosaic in the same area of the pockmark, based on images of the BIOZAIRE cruise in 2001. The 10‐year variation of the faunal distribution is described and reveals that the visible abundance and distribution of the dominant megafaunal populations at Regab have not changed significantly, suggesting that the overall methane and sulfide fluxes that reach the faunal communities have been stable. Nevertheless, small and localized distribution changes in the clam community indicate that it is exposed to more transient fluxes than the other communities. Observations suggest that the main megafaunal aggregations at Regab are distributed around focused zones of high flux of methane‐enriched fluids likely related to distinct smaller pockmark structures that compose the larger Regab pockmark. Although most results are consistent with the existing successional models for seep communities, some observations in the distribution of the Regab mussel population do not entirely fit into these models. This is likely due to the high heterogeneity of this site formed by the coalescence of several pockmarks. We hypothesize that the mussel distribution at Regab could also be controlled by the occurrence of zones of both intense methane fluxes and reduced efficiency of the anaerobic oxidation of methane possibly limiting tubeworm colonization.     

Trophic ecology of Pomatoschistus microps within an intertidal bay (Roscoff,France), investigated through gut content and stable isotope analyses

The diet of Pomatoschistus microps has been studied using both gut content and stable isotope analyses. In the Roscoff Aber Bay (Brittany, France), this fish is commonly found on sandy muddy intertidal flats. Gut content analyses were also interpreted using trophic indices. Owing to the large diversity of prey consumed, these indices emphasised the opportunistic feeding behaviour of P. microps. Here, this species fed mainly on endofauna with meiofauna being of high relative importance. The main biotic components of its trophic habitat, characterized by δ¹³C and δ¹⁵N, provided evidence of a major trophic pathway based on drift Enteromorpha sp. Trophic positions estimated by both diet analyses and isotopic analyses led to similar results. In this bay, P. microps is a first‐order predator with a low degree of omnivory. Despite a preferential consumption of the amphipod Corophium arenarium, we assumed that this goby behaves as a generalist feeding on a uniform variety of endofauna taxa.     

Soil treatment with organic non-traditional additives for the improvement of earthworks

The aim of this study was to characterise the technical and environmental implications of non-traditional treatments of a low-plasticity compacted silt (PI = 14) and to investigate their actions both at the micro- and macro-structural scales. Three non-traditional additives derived from industrial vegetal by-products were studied. These additives are classified as an acid solution, an enzymatic solution (ES) and calcium lignosulfonate (LS). The first step was to characterise the effects of these treatments on Proctor compaction, bearing capacity, unconfined compressive strength and stiffness. The index properties of the treated samples were also measured to assess changes in the interaction between soil minerals and the additives. These experimental results showed that the 0.002 % ES and 2.0 % LS treatments were the most effective at improving the soil dry density and allowing the soil to reach optimum density using 3 % less water or 25 % less compaction energy. In a second step, the mechanisms involved in the treatment were investigated. A microscopic study was conducted including scanning electron microscopy and mercury injection porosity tests; measurements of the surface tension of non-traditional additives mixed with water completed the study and demonstrated that the ES treatment has the same surfactant properties as sodium dodecyl sulphate, a common surfactant. Compaction tests confirmed that the behaviours of the soil after ES and sodium dodecyl sulphate treatments were similar.     

Debating clean energy: Frames,counter frames,and audiences

In the United States, both scholars and practitioners have repeatedly emphasized the importance of “issue framing” for garnering public support for climate change policy. However, the debate frequently overlooks the importance of counter frames. For every framing attempt by advocates of climate policy, there will be a counter frame by the opponents of climate policy. How do counter frames influence the effectiveness of issue framing as a communication strategy? To answer this question, we report results from a survey experiment on a nationally representative sample of 1000 Americans on clean energy policy, a key policy issue in the public debate on climate change in the United States. Overall, we find that different combinations of positive and negative frames have remarkably little effect on support for clean energy policy. A follow-up on-line survey experiment with a convenience sample of 2000 Americans suggests that the counter frames are responsible for undermining the effects of the original frames.     

Laser Ablation (U-Th-Sm)/He Dating of Zircons: Analytical Age Bias and its Consequence for Studying Detrital Zircon Populations

The in situ (U-Th-Sm)/He and U/Pb laser-ablation double-dating procedure is a valuable method that can provide a large dataset relatively efficiently in contrast with conventional bulk helium thermochronometry. In this study, we evaluate the potential age error associated with the double ablation procedure and report the in situ (U-Th-Sm)/He double-ablation dating of 249 zircons from the Fish Canyon Tuff locality. With LA-ICP-MS pseudo-depth profiling and 3D numerical modelling, we show that the concentric double-ablation procedure in minerals with U-Th-Sm zoning can generate a significant (U-Th-Sm)/He age error (positive or negative), resulting in over-scattering and/or an offset of the mean age. Pseudo-depth profiling is insufficient to predict the individual age error, partly because of the superimposed ablations. To evaluate the consequence of this inherent bias, we confront a synthetic age distribution to the error expected for U-Th-Sm zoned zircons analysed with double-ablation (U-Th-Sm)/He thermochronometry. As expected, a strong age bias causes the spreading of peak ages, downgrading the original signal. Yet, the throughput of the ablation-based method can allow intra- and inter-sample peak age identification and comparison, and the coupling of (U-Th-Sm)/He and U/Pb ages extends our ability to deconvolute a multimodal age spectrum.