Microbiological and physicochemical analysis of the coastal waters of southern Brazil

The aim of this study was to assess the impact of sewage discharge on coastal waters by evaluating the influence of physicochemical parameters on the presence of enteric microorganisms in seawater samples collected from 11 beaches in Florianopolis, Santa Catarina, Brazil, over a one-year period (August 2009 to July 2010). Samples were assessed for the presence of human adenoviruses (HAdV), polyomavirus (JCPyV), hepatitis A virus (HAV), and noroviruses (HuNoV GI and GII). Escherichia coli and physicochemical parameters (salinity, temperature, pH and dissolved oxygen) were also evaluated. From the 132 samples analyzed, 55% were positive for HAdV, 51.5% for HAV, 7.5% for HuNoV GI, 4.5% for HuNoV GII, and 3% for JCPyV. E. coli levels ranged from 8 to 1325 CFU/100mL at all sites. The overall results highlight the problem of sewage discharge into coastal waters and confirm that there is no correlation between viral presence and bacterial contamination.     

Investigating the partonic entanglement entropy at low Bjorken-x within Gluon saturation approach

In this work, the entanglement entropy is examined within the context of deep inelastic scattering in $ep$ collisions. The calculation is based on a formalism where the partonic state at small- $x$ is maximally entangled, consisting of a large number of micro-states occurring with equal probabilities. Analytical expressions for the number of gluons, $N_{\text{gluon}}$, are considered, derived from gluon saturation models for dipole-target amplitudes within the framework of the Quantum Chromodynamics (QCD) color dipole picture. A comparison of the entanglement entropy with thermodynamic entropy measured in $pp$ and $ep$ collisions at high energies is done.     

High‐frequency cycles of brachiopod shell beds on subaqueous delta‐scale clinoforms (early Pliocene,south‐east Spain)

During the early Pliocene, subaqueous delta‐scale clinoforms developed in the Águilas Basin, in a mixed temperate carbonate–siliciclastic system. The facies distribution is consistent with the infralittoral prograding wedge model. Stacking patterns and bounding surfaces indicate that the clinoforms formed during the highstand and falling sea‐level stages of a high rank cycle. Twenty‐two prograding clinothems were recognized over a distance of ≥1 km. Biostratigraphic data indicate a time span shorter than 700 kyr for the whole unit (MPl3 biozone of the Mediterranean Pliocene). Cyclic skeletal concentrations and occasional biostromes of suspension feeders (terebratulid brachiopods, modiolid bivalves and adeoniform bryozoan colonies), slightly evolved glauconite and occasional Glossifungites ichnofacies formed on the clinoforms during high‐frequency pulses of relative sea‐level rise. During such stages, increased accommodation space in the topsets of the clinoforms caused a strong reduction of terrigenous input into the foresets and bottomsets. This provided favourable conditions for the development of these suspension feeder palaeocommunities. During stillstand stages, however, reduced accommodation space in the topsets eventually resumed progradation in the foresets. There, the abundance of Ditrupa tubes indicates frequent siltation events that extirpated the terebratulid populations and other epifaunal suspension feeders in the foreset and bottomset subenvironments. The occurrence of shell beds on the clinoforms suggests that this case study represents lower progradation rates than standard examples where shell beds bound the clinobedded units at their base and top only. Importantly, the distributions of biofacies and ichnoassemblage associations contribute significantly to the understanding of the effects of relative sea‐level fluctuations on the evolution of subaqueous delta‐scale clinoform systems.     

Rare Earth Element Geochemistry of the Zigzag - Klondyke Sedimentary Rock Formations: Clues to the Evolution of the Baguio Mineral District (Luzon), Philippines

Abstract. Petrographic analysis of the Oligocene-Miocene Zigzag Formation and Miocene Klondyke Formation of the Baguio Mineral District reveals a transitional arc source for the former and an undissected arc source for the latter. Whole rock geochemistry of these sedimentary rock formations show affiliation of the Zigzag Formation to active continental margin whereas the Klondyke Formation appears to have been derived from an oceanic island arc source. A different aspect of the geology of the district is further gleaned from the whole rock rare earth element geochemistry of these rocks. Samples from the Zigzag Formation are characterized by higher REE concentrations compared to the Klondyke Formation samples. The REE data indicate that the sedimentary rocks of the Klondyke Formation had geochemically-less fractionated igneous lithologies as their progenitor whereas the older Zigzag Formation was derived from a more differentiated source. This new set of information contributes to the understanding of the evolution of this district from a marginal basin to an island arc setting.     

Progression of deformation and sedimentation in the southernmost Andes

The chronology of thrust motion in the Fuegian thin-skinned fold-thrust belt was established using data from the Atlantic coast of Tierra del Fuego. A set of original structural–geological maps showing the distribution of structures, unconformities and synorogenic sequences in the last tip of the Andes reveals the cratonward propagation of thrusts and sedimentary depocenters. A succession of syntectonic angular and progressive unconformities occur in the studied zone: (1) an angular unconformity between Danian and Late Paleocene sequences, (2) a series of progressive and syntectonic angular unconformities developed from the Late Early Eocene to the Late Eocene, and (3) a Lower Miocene syntectonic unconformity. Additional evidence for the time–space location of the thrust-front is provided by the presence of seismically triggered sand intrusions in Late Cretaceous, Late Paleocene and Middle Miocene sequences.The integration of data shows that faulting occurred in three main episodes: San Vicente thrusting, ca. 61–55 Ma, Río Bueno thrusting, ca. 49–34, and Punta Gruesa strike-slip event, ca. 24–16 Ma. San Vicente thrusting represents the onset of thrust propagation onto the foreland craton. The thrust-front endured a major cratonward migration through the Río Bueno thrusting, and remained steady afterward. Punta Gruesa constitutes a strike-slip event, associated with the phase of wrench deformation that influences the southernmost Andes since the Oligocene. Although the overall pattern of faulting was progressively younger cratonward, several episodes of out-of-sequence thrusting and folding occurred.Other features in the southernmost Andes can be linked to these three deformation events to broadly characterize the behavior of the Fuegian orogenic wedge in terms of critical taper models. The Fuegian Andes underwent at least three cycles between subcritical, critical and supercritical stages of behavior in terms of deformation, erosion, and sedimentation.     

Assessment of sidewall erosion in large gullies using multi-temporal DEMs and logistic regression analysis

Although in the last decades gully erosion has been a thriving research field, few studies have specifically addressed the contribution and location of sidewall erosion processes in gullies. In this paper, sidewall erosion in some large gullies in a Mediterranean area (Anoia-Penedès, NE Spain) is mapped and assessed for two time intervals (1975–1995 and 1995–2002), using detailed digital elevation models derived from aerial photographs at a scale of 1:5000 to 1:7000. Logistic regression analysis is applied to compute the probability of occurrence of gully sidewall erosion from terrain variables. The results confirm the complex nature of sidewall processes, whose intensity is most probably related to rainfall characteristics. Prolonged wet soil conditions in the period 1995–2002, together with the large and high-intensity rainfall of an extreme event occurred on 10th June 2000, help to explain the different sediment production rates: 16±0.4 Mg ha⁻¹ year⁻¹ in 1975–1995 and 83±6.3 Mg ha⁻¹ year⁻¹ in 1995–2002. The logistic regression analysis revealed that gully-wall slope angle was the main factor controlling gully sidewall failure. In gully walls with high slope angles, tension crack development is the main process promoting wall collapse. The application of the logistic regression model showed a high overall accuracy (87%) but over 50% of commission and omission errors for the class of interest (sidewall erosion), in agreement with the variance explained by the model.     

Effect of plant growth on Pb and Zn geoaccumulation in 300-year-old mine tailings of Zacatecas,México

Concentrations of Pb and Zn, plant uptake of these metals, the influence of the plants’ growth on the physicochemical properties and metal concentrations in the tailings of an abandoned 300-year-old mine tailing dam in Zacatecas, Mexico were investigated. Tailings were found to be heavily contaminated, with average levels of 2621 ± 53 and 3827 ± 83 mg/kg for Pb and Zn, respectively (maximum concentrations of 8466 ± 116 and 12,475 ± 324 mg/kg, respectively), exceeding international standards. Though physico-chemical conditions (pH, conductivity, redox potential, moisture, organic matter, nitrate, nitrite, ammonium nitrogen, total nitrogen, phosphorus and sulfates) do not favor the development of vegetation, some plants have adapted to these adverse conditions. Moreover, there was a significant reduction of Pb and Zn concentration in the rhizosphere (between 10–78% for Pb and 18–62% for Zn, depending on plant species). Sporobolus airoides showed average biomass concentrations of 173 ± 2 and 313 ± 6 mg/kg, for Pb and Zn, respectively; which implies a risk for mobility and possible incorporation into the food chain. Barcleyanthus salicifolius, Asclepsias linaria and Cortaderia selloana on the other hand, showed average biomass concentrations of 28 ± 3 and 121 ± 5 mg/kg of Pb and Zn, respectively, thus representing a lower biomagnification risk. The effect of these plants to reduce metal concentrations in the rhizosphere, improve physico-chemical conditions in metal polluted substrates, but with limited metal accumulation in biomass, suggests that they can be evaluated for use in stabilizing metal polluted tailings.     

Integrated modelling for water quality management in a eutrophic reservoir in south-eastern Portugal

The Enxoé Reservoir was built in 1998. Since 2000, it has exhibited frequent high chlorophyll-a concentrations, reaching a geometric mean three times higher than the national limit for eutrophication, presenting the reservoir with the highest eutrophic state in Portugal. Toxic algal blooms have also often been observed, which pose serious challenges to water managers, as the reservoir is used for potable water production (25,000 inhabitants). The objective of this study was to implement a reservoir model (CE-QUAL-W2), with inputs from a watershed model (SWAT), in order to represent the actual reservoir state and to test management measures to reduce its trophic level and algal bloom concentration peaks. The integrated model was used to depict the origin of its trophic status. Simulations were also compared to measured data at the reservoir surface (water level, nitrate, orthophosphate, suspended solids, and oxygen) and in water profiles (temperature, oxygen). The model was able to represent stratification and thermocline depths, as well as the actual chlorophyll-a and dissolved oxygen concentrations. The model results showed that internal phosphorus load from deposited sediments was an important factor in fuelling the algal blooms. This process occurs predominantly in summer, when stratification takes place and aeration is reduced, promoting anoxic conditions in the bottom waters. Since the reservoir is relatively shallow (average 5 m), released phosphorus is then easily able to reach the photic zone in most parts of the reservoir, where it is consumed. Different management scenarios were tested, suggesting that a mesotrophic level could barely be reached and maintained simply by reducing the nutrient loads (both external and internal). It is suggested that only an increase in the reservoir dam height could produce a mesotrophic level, averting anoxia by blocking the release of phosphorus from sediments to the photic zone. Future work should focus on a cost–benefit analysis to test the feasibility of each of the proposed scenarios, taking advantage of the integration strategy to assess where in the watershed load reductions would be most effective.     

The Hyperstatic Reaction Method for the Analysis of the Sprayed Concrete Linings Behavior in Tunneling

Hyperstatic Reaction Method considers the interaction between the shotcrete lining and the rock mass modelling half tunnel section by beam elements connected by nodes, which can develop bending moments, axial forces and shear forces. The interaction between ground and support is represented by Winkler type springs in the nodes of the numerical model, in the normal and tangential direction. 1944 analyses were developed considering three different tunnel radius values (2.0, 4.5 and 7.0 m), three different rock types (RMR = 40, RMR = 60 and RMR = 80), three different stress ratios acting on the linings (\(K = 1, \,K = 0.5\) and \(K = 0\)), three different lining thickness values (0.1, 0.2 and 0.3 m) and three values of the average elastic modulus of the shotcrete (6000, 9000 and 12,000 MPa). Besides, also two different stiffness values of the tangential springs at nodes were considered. Results show that the lining thickness and the elastic modulus of the shotcrete have a strong influence on the bending moment values which develop inside. The maximum axial force is not practically influenced by the lining elastic modulus and thickness. Both maximum bending moments and maximum axial forces increase in a linear way with the vertical load value; tunnel radius, \(K\) and RMR values of the rock mass have also a great influence on the maximum bending moment and axial force. Besides, it is possible to note how the absence of shear interaction between the lining and the rock mass causes bending moment values in the lining higher with respect to the case where the stiffness of the tangential springs at nodes equals to half the stiffness of the normal springs. For this reason, the neglectance of the shear interaction between the lining and the tunnel wall leads to an overdesign of the SC lining.