Earthquake deformation in the northwestern Sierras Pampeanas of Argentina based on seismic waveform modelling

We investigate the seismic properties of modern crustal seismicity in the northwestern Sierras Pampeanas of the Andean retroarc region of Argentina. We modelled the complete regional seismic broadband waveforms of two crustal earthquakes that occurred in the Sierra de Velasco on 28 May 2002 and in the Sierra de Ambato on 7 September 2004. For each earthquake we obtained the seismic moment tensor inversion (SMTI) and tested for its focal depth. Our results indicate mainly thrust focal mechanism solutions of magnitudes M_w 5.8 and 6.2 and focal depths of 10 and 8 km, respectively. These results represent the larger seismicity and shallower focal depths in the last 100 years in this region. The SMTI 2002 and 2004 solutions are consistent with previous determinations for crustal seismicity in this region that also used seismic waveform modelling. Taken together, the results for crustal seismicity of magnitudes ≥5.0 in the last 30 years are consistent with an average P-axis horizontally oriented by an azimuth of 125° and T-axis orientation of azimuth 241° and plunge 58°. This modern crustal seismicity and the historical earthquakes are associated with two active reverse faulting systems of opposite vergences bounding the eastern margin of the Sierra de Velasco in the south and the southwestern margin of the Sierra de Ambato in the north. Strain recorded by focal mechanisms of the larger seismicity is very consistent over this region and is in good agreement with neotectonic activity during the last 11,000 years by Costa (2008) and Casa et al. (in press); this shows that the dominant deformation in this part of the Sierras Pampeanas is mainly controlled by contraction. Seismic deformation related to propagation of thrusts and long-lived shear zones of this area permit to disregard previous proposals, which suggested an extensional or sinistral regime for the geomorphic evolution since Pleistocene.     

Gravitational Mesoscopic Constraints in Cosmological Dark Matter Halos

We present an analysis of the behaviour of the ‘coarse-grained’ (‘mesoscopic’) rank partitioning of the mean energy of collections of particles composing virialized dark matter halos in a Λ-CDM cosmological simulation. We find evidence that rank preservation depends on halo mass, in the sense that more massive halos show more rank preservation than less massive ones. We find that the most massive halos obey Arnold’s theorem (on the ordering of the characteristic frequencies of the system) more frequently than less massive halos. This method may be useful to evaluate the coarse-graining level (minimum number of particles per energy cell) necessary to reasonably measure signatures of ‘mesoscopic’ rank orderings in a gravitational system.     

The Hesperides basin: a continental‐scale upper Palaeozoic to Triassic basin in southern Gondwana

The late Palaeozoic to Triassic sedimentary record of the central Argentinean offshore was analysed through the integration of data from exploratory wells and 2D seismic lines. Our interpretations were combined with existing ones in Argentina, Uruguay, Brazil and South Africa for their analysis in the late Palaeozoic south‐western Gondwana context. The mapped upper Palaeozoic‐Lower Triassic stratigraphic record offshore Argentina bears a thickness of +7000 m south of the Colorado basin and encompasses the time span between Pennsylvanian and Lower Triassic; this means that it triples that of the Sierras de la Ventana of Argentina and involves a far larger time span. On the basis of seismic stratigraphic interpretations in localities near the coast, we interpret that a strong denudation process removed a great portion of the stratigraphic record in the Sierras de la Ventana, the surrounding plains and the Tandilia system of Buenos Aires. The seismic stratigraphic configuration of the late Palaeozoic succession shows continuous and parallel reflections in a wide sediment wedge extending for more than 1000 km between the Gondwanides orogen core to the south and offshore Uruguay to the north. Two salient aspects of this sedimentary wedge are that no flexural depocentre was observed at the Ventania fold belt front, and that deformation in the orogenic front is post‐Lower Triassic. The original westwards extent of the basin is interpreted to have encompassed the whole of Buenos Aires province in continuity with the Chacoparaná basin; to the east continuity and a straightforward correlation with the Karoo basin was interpreted. The name of Hespérides Basin is proposed herein to refer to a Pennsylvanian to Lower Triassic basin mainly controlled by dynamic subsidence that encompasses and exceeds the area of the Sauce Grande and Colorado basins and the Claromecó fore‐deep in Argentina. The Hespérides basin is interpreted to have been in lateral continuity with the Kalahari, Karoo and Chacoparaná basins of Africa and South America forming a +3 000 000 sq. km depocentre.     

The Grenville-age basement of the Andes

The analysis of the basement of the Andes shows the strong Grenville affinities of most of the inliers exposed in the different terranes from Colombia to Patagonia. The terranes have different histories, but most of them participated in the Rodinia supercontinent amalgamation during the Mesoproterozoic between 1200 and 1000 Ma. After Rodinia break-up some terranes were left in the Laurentian side such as Cuyania and Chilenia, while others stayed in the Gondwanan side. Some of the terranes once collided with the Amazon craton remained attached, experiencing diverse rifting episodes all along the Phanerozoic, as the Arequipa and Pampia terranes. Some other basement inliers were detached in the Neoproterozoic and amalgamated again to Gondwana in the Early Cambrian, Middle Ordovician or Permian times. A few basement inliers with Permian metamorphic ages were transferred to Gondwana after Pangea break-up from the Laurentian side. Some of them were part of the present Middle America terrane. An exceptional case is the Oaxaquia terrane that was detached from the Gondwana margin after the Early Ordovician and is now one of the main Mexican terranes that collided with Laurentia. These displacements, detachments, and amalgamations indicate a complex terrane transfer between Laurentia and Gondwana during Paleozoic times, following plate reorganizations and changes in the absolute motion of Gondwana.     

Understanding the dynamics and contamination of an urban aquifer system using groundwater age (14C, 3H,CFCs) and chemistry

The quality of the groundwater supplying drinking water to the Guadalajara metropolitan area has deteriorated due to both endogenic and exogenic processes. Previous studies of this complex neotectonic volcanic environment suggest that the sources of contamination here are underground fluids derived from an active volcanic center and surface wastewater derived from regional land‐use intensification. This study uses isotopic, gaseous, and chemical signatures to more comprehensively characterize this groundwater flow and its contamination paths. Groundwater is mainly recharged at the La Primavera Caldera to the west and is discharged into the Santiago River to the east. The exception to this trend is the Toluquilla area, where groundwater most likely represents rainfall originating from outside the basin limits. Evaporation affects groundwater in these areas, especially waters that have been affected by recycling below urban areas in the Atejamac area and by intensive agricultural activity in the Toluquilla area. Additionally, we present evidence that groundwater flow through alluvial sediments and tuffs in deeper wells mixes with a lower aquifer unit in basaltic‐andesitic rocks, which are in contact with hydrothermal fluids. Groundwater ages range from postbomb in the western and northwestern regions of the study area (i.e., the Atemajac aquifer unit) to Late Pleistocene in the southern and southeastern regions (i.e., the Toluquilla aquifer unit). Recently recharged water records little mixing and is located mostly in or near the La Primavera volcanic system. As groundwater undergoes gravitational flow towards discharge areas, it mixes with older water components. Chloride and sodium concentrations above natural background levels are primarily related to volcanic activity, nitrate is associated with human activities, and sulfate originates from both anthropogenic sources and water–rock interactions. Nitrate originating from land‐use activities (such as sewers, septic tanks, landfills, and agricultural fields) that is introduced into the deeper part of the groundwater system is expected to travel with the groundwater to the discharge areas because oxidizing conditions will prevent microbial reduction. See Supplementary Information.     

Characterization of the proto-Philippine Sea Plate:Evidence from the emplaced oceanic lithospheric fragments along eastern Philippines

The proto-Philippine Sea Plate(pPSP)has been proposed by several authors to account for the origin of the Mesozoic supra-subduction ophiolites along the Philippine archipelago.In this paper,a comprehensive review of the ophiolites in the eastern portion of the Philippines is undertaken.Available data on the geology,ages and geochemical signatures of the oceanic lithospheric fragments in Luzon(Isabela,Lagonoy in Camarines Norte,and Rapu-Rapu island),Central Philippines(Samar,Tacloban,Malitbog and Southeast Bohol),and eastern Mindanao(Dinagat and Pujada)are presented.Characteristics of the Halmahera Ophiolite to the south of the Philippines are also reviewed for comparison.Nearly all of the crust-mantle sequences preserved along the eastern Philippines share Early to Late Cretaceous ages.The geochemical signatures of mantle and crustal sections reflect both mid-oceanic ridge and suprasubduction signatures.Although paleomagnetic information is currently limited to the Samar Ophiolite,results indicate a near-equatorial Mesozoic supra-subduction zone origin.In general,correlation of the crust-mantle sequences along the eastern edge of the Philippines reveal that they likely are fragments of the Mesozoic pPSP.     

Homogeneous Catalytic Ozonation of Lipids Involving Fe2+ and Mn2+: An Experimental and Modeling Study

Given the issue of lipids in effluent treatment systems and their negative impact on the environment, this study aimed to examine lipid degradation by homogenous catalytic ozonation with the aid of iron and manganese ions. This technology presents the possibility of completely mineralizing pollutants using hydroxyl radicals. Milk is chosen as the lipid source because of the high concentration of triglycerides in its matrix, this kind of lipid being the one found most frequently in food and, consequently, in effluent treatment systems. The milk pH value is controlled, and acidic, neutral, and basic conditions are evaluated. The rates of pseudo‐first‐order reactions and the effective value are estimated. It is shown that under acidic conditions low catalyst dosages are enough to cause the complete degradation of lipids. Under neutral conditions, a similar behavior is observed. Under basic conditions, higher catalyst dosages give higher reaction rates. The order of effectiveness of the catalysts under acidic and basic conditions is Fe²⁺ > Mn²⁺, with Mn²⁺ > Fe²⁺ under neutral conditions. Homogeneous catalytic ozonation is therefore efficient at lipid degradation. This technique is viable economically, since the lipid removal occurred at low ozone levels. In addition, the ions used as catalysts are naturally abundant.