Fluoride Biomonitoring around a Large Aluminium Smelter Using Foliage from Different Tree Species

In order to study the pollution gradient in the vicinity of a large aluminium production facility in Patagonia (Argentina), a passive biomonitoring was performed employing foliage from three tree species. Primary scope was to identify pollution gradients and to select suitable tree species which can be used as biomonitor plants in the study area. Therefore, leaves of Eucalyptus rostrata, Populus hybridus and different needle ages of Pinus radiata were collected at different distances from the industry and the fluoride concentration was analysed in washed and unwashed samples in order to determine the amount of external fluoride. Washing reduced the F‐concentrations by 24, 39 and 51% on average in E. rostrata, P. hybridus and P. radiata, respectively, indicating that species‐specific characteristics determine the accumulation and wash‐off of dust‐associated fluorine. F‐concentrations varied from 6 to 3652 ppm F in unwashed samples indicating a steep pollution gradient in the study area. The influence of F‐emissions was discernible in all samples up to a distance of 3500 m from the smelter. E. rostrata accumulated more fluorine than the other species at equal distance from the emission source. The present study confirms that aluminium smelting results in high F deposition in the study area. Establishing a biomonitor network around large emitters is suitable and feasible to evaluate the efficiency of air control measures.     

Land use and topography as predictors of nutrient levels in a tropical catchment

The influence of landscape on nutrient concentration and yield was analyzed in a tropical catchment, the Guare River in northern Venezuela. Spatial and temporal variation in nitrate, SRP and total P were determined in 15 sites located along the river mainstem and tributaries. Higher nitrate concentrations and yields were reported from upper sites and both decreased in the downstream direction along the river mainstem. These trends appear to be related to more pronounced slopes and larger proportions of agricultural and forest lands in subcatchments located in the upper part of the basin, and dense algal mats in the lower reaches. Nitrate values were higher during periods of high discharge, suggesting that nitrate is primarily transported by shallow subsurface flow. SRP represented between 60 and 80% of total P. Phosphorus concentrations were homogeneous along the river mainstem and showed little seasonal variation, while yields were higher in the upper basin. Multiple regression identified slope, runoff and agriculture as primary predictors of nitrate and phosphorus across the watershed, which suggests that both natural and anthropogenic landscape characteristics have a strong influence on nutrient levels in the Guare catchment.     

Social change and land tenure regimes in Mexico

This paper argues that the changing land tenure legislation in Mexico is a concrete reflection of generalized societal attitudes towards indigenous and traditional peasants. It contends that the 1992 neoliberal land-reform mimics the progress-oriented liberal project of the ninettenth century and continues a market-centered modernization process underway since the 1940s, which has been legitimized by an overt institutional disdain and discrimination against indigenous people, peasants and their ways of life. It concludes that this process of assimilation or eradication of traditional agro-ecosystems, cultural diversity and social organization will further increase the vulnerability of Mexican peasants to economic and cultural change. As peasants engage in market-controlled business ventures in the rural areas, migrate to cities, rent or sell their lands, they simultaneously adapt to new values and envision new strategies for subsistence that are increasingly mediated by political-economic forces largely beyond their sphere of influence.     

An Effective Approach to Rehabilitate Damaged Barrier System Against Piping and Contaminant Flow

The monitoring operation of an older impoundment (such as dams and waste barrier materials) during the service life of the structure cannot be overemphasized. Since older infrastructures seem to be more susceptible to piping and seepage failure, their construction design should be analyzed and monitored at places where a potential problem could occur. Once an impoundment is constructed without adequate filters layers and foundation treatments, then the prevention of piping or seepage may require an effective approach to constructing a cut-off wall to prevent eventual failure. In order to identify and understand theses failure modes, it is important to identify the physical parameters of the impoundment system, such as the zones of various soil gradations, the compaction of these zones, the hydraulic conductivity, the compatibility of the soil formations within and beneath the core or liner, as well as the cohesive and dispersive properties of soils at various location within the structure. Once these parameters are known and quantified, an adequate assessment of the structure’s susceptibility to piping or contaminant transport can be established. This type of an analysis will enable the proper design of a cut-off wall and predetermine the effectiveness of its long-term performance. The Vermont Waterbury Dam (built in 1938) is example of seepage related problem that implemented a cut-off wall design to prevent piping paths from undermining the structure. In this case, some forensic sampling had to be performed and the parameters of the soils as just mentioned were key factors in determining the wall design. In this paper, the Waterbury dam rehabilitation is investigated as case studies, in order to better understand how older designs and poor construction of impoundments can lead to piping condition in dams as well as failures in waste barrier systems. The Secant Cut-off wall (constructed at Waterbury Dam) is mentioned as a corrective measure taken for this dam and there is a brief discussion as to how this construction rehabilitation technique can be applied to waste barrier impoundments.     

Absence of overall feedback in a benthic estuarine community: A system potentially buffered from impacts of biological invasions

Species introductions are among the most dramatic human-induced impacts on aquatic and terrestrial ecosystems around the world. Stability patterns of an estuarine benthic community were investigated through guild interaction models representing the community before and after human-mediated species invasions. The study area was Yaquina Bay, a developed estuary on the central Oregon coast, U.S., where at least 12 species of nonindigenous invertebrates have been inadvertently introduced. Three of the introduced species (the polychaetes Hobsonia florida and Pseudopolydora kempi and the cumacean Nippoleucon hinumensis) are probably among the 10 most abundant invertebrate species in the intertidal benthic community. To estimate effects and potential risks of species introductions on the native community we constructed 2 types of community models based on functional-group interactions, namely, activity guild models and trophic guild models. In both cases we observed that overall feedback has a strong tendency towards zero in pre-invasion and post-invasion models. We generated 12,000 random models of similar size and could not detect this tendency. We suggest that the weak or absent overall feedback in this community may be an ecological property and not an intrinsic property of large systems as such. The reduced response to input from either invertebrate invasions or removal of native top predators, may to some extent buffer the community from such impacts. Alternative guild models suggested increased risk of stability decline in the invaded community even after accounting for potential complexity effects on stabllity. Further species introductions in this intermediately invaded estuary should be avoided.     

Empirical P-L-C relation for δ scuti stars

Empirical period-luminosity-colour (P-L-C) relations are obtained for the four lowest modes corresponding to radial pulsations. Agreement with predicted values indicates that, in general, both Strömgren photometric calibration and pulsation theory work well for these stars.Paper presented at the 11 th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.     

Multivariate analysis of contamination in the mining district of Linares (Jaén, Spain)

Historically, a significant level of mining activity has taken place in the batholite-related metalogenic enclave of Linares (Jaén province, Spain), associated with Pb–Ag, Cu, Zn and Fe sulphides and Ba sulphate mineralization, though mining here has now been abandoned. Additionally, the area features a significant amount of urban, industrial and agricultural activities. These considerations, taken together, explain the need to assess the levels of concentration of trace elements and to determine their relationship with geogenic and anthropogenic factors. For geochemical characterisation of the soil, the region has been divided into 126 grid squares with an area of 1 km². For each grid square, 32 trace elements have been analysed. Elemental concentrations of Cu, Pb, Zn, As and Mn have been included in statistical analyses. According to the reference levels established by the Regional Government (Junta de Andalucía), soils in a large part of the study area require amendment applications. The comparison of the mean content for each grid square with the reference levels reveals a significant degree of contamination of the soil by Cu (719 mg kg⁻¹), Pb (22,964 mg kg⁻¹) and As (100 mg kg⁻¹) in those grid squares affected by metallurgic activities. By means of factor analysis, four scores have been identified which together account for 80% of the variance observed. The first score is highly correlated with the logarithms of the variables Fe, Th, La, Ti, Al, Na, K, Zr, Y, Nb, Be and Sc. It is a “natural” factor that indicates the type of soil matrix (fundamentally granites and, to a lesser degree, Triassic materials). The second score shows high correlation with the logarithms of the variables Mo, Cu, Pb, Zn, Ag, Co, Mn, As, Cd, Sb, Ba, W and Sn, and is the “metallization” factor related to the mineralization that has been exploited. The third score is mainly determined by the logarithms of the variables Sr, Ca and Mg. This is a “natural” factor that indicates a type of carbonate soil matrix (Miocene). Finally, the fourth factor groups the logarithms of the variables Ni, V and Cr, elements that are associated with the combustion of fossil fuels. Analysis of the patterns of each of the factors identified enabled achieving a global characterisation of the study area. Cluster analysis of the observations showed there to be five clusters relating to the grid squares, differentiated by lithologies and degrees of contamination. These clusters are used to determine the background of granite and to calculate the anomalous load.