The Planetary Fourier Spectrometer (PFS) onboard the European Mars Express mission

The Planetary Fourier Spectrometer (PFS) for the Mars Express mission is an infrared spectrometer optimised for atmospheric studies. This instrument has a short wave (SW) channel that covers the spectral range from 1700 to (1.2-) and a long-wave (LW) channel that covers 250- (5.5-). Both channels have a uniform spectral resolution of . The instrument field of view FOV is about 1.6^° (FWHM) for the Short Wavelength channel (SW) and 2.8^° (FWHM) for the Long Wavelength channel (LW) which corresponds to a spatial resolution of 7 and 12 km when Mars is observed from an height of 250  km. PFS can provide unique data necessary to improve our knowledge not only of the atmosphere properties but also about mineralogical composition of the surface and the surface-atmosphere interaction.The SW channel uses a PbSe detector cooled to 200-220 K while the LW channel is based on a pyroelectric (L_iT_aO₃) detector working at room temperature. The intensity of the interferogram is measured every 150 nm of physical mirrors displacement, corresponding to 600 nm optical path difference, by using a laser diode monochromatic light interferogram (a sine wave), whose zero crossings control the double pendulum motion. PFS works primarily around the pericentre of the orbit, only occasionally observing Mars from large distances. Each measurements take 4 s, with a repetition time of 8.5 s. By working roughly 0.6 h around pericentre, a total of 330 measurements per orbit will be acquired 270 looking at Mars and 60 for calibrations. PFS is able to take measurements at all local times, facilitating the retrieval of surface temperatures and atmospheric vertical temperature profiles on both the day and the night side.     

The solar lithium abundance

A detailed observational study of the solar photospheric lithium feature has been carried out with emphasis on center-limb observations, continuum location, possible effects of telluric lines, effects of blending by atomic and molecular lines, and decomposition of the solar spectrum around λ6707 Å.     

Impacts of future climatic and land cover changes on the hydrological regime of the Madeira River basin

Brazilian strategic interest in the Madeira River basin, one of the most important of the southern Amazon tributaries, includes the development of hydropower to satisfy the country’s growing energy needs and new waterways to boost regional trade and economic development. Because of evidences that climate change impacts the hydrological regime of rivers, the aim of this study was to assess how global climate change and regional land cover change caused by deforestation could affect the river’s hydrological regime. To achieve this goal, we calibrated a large-scale hydrological model for the period from 1970–1990 and analyzed the ability of the model to simulate the present hydrological regime when climate model simulations were used as input. Climate change projections produced by climate models were used in the hydrological model to generate scenarios with and without regional land-use and land-cover changes induced by forest conversion to pasture for the period from 2011–2099. Although results show variability among models, consensus scenarios indicated a decrease in the low-flow regime. When the simulations included forest conversion to pasture, climate change impacts on low flows were reduced in the upper basin, while, in the lower basin, discharges were affected along the whole year due to the more vigorous land-use conversion in the Brazilian region of the basin.     

Solar Sources of Interplanetary Coronal Mass Ejections During the Solar Cycle 23/24 Minimum

We examine solar sources for 20 interplanetary coronal mass ejections (ICMEs) observed in 2009 in the near-Earth solar wind. We performed a detailed analysis of coronagraph and extreme ultraviolet (EUV) observations from the Solar Terrestrial Relations Observatory (STEREO) and Solar and Heliospheric Observatory (SOHO). Our study shows that the coronagraph observations from viewpoints away from the Sun–Earth line are paramount to locate the solar sources of Earth-bound ICMEs during solar minimum. SOHO/LASCO detected only six CMEs in our sample, and only one of these CMEs was wider than 120^°. This demonstrates that observing a full or partial halo CME is not necessary to observe the ICME arrival. Although the two STEREO spacecraft had the best possible configuration for observing Earth-bound CMEs in 2009, we failed to find the associated CME for four ICMEs, and identifying the correct CME was not straightforward even for some clear ICMEs. Ten out of 16 (63 %) of the associated CMEs in our study were “stealth” CMEs, i.e. no obvious EUV on-disk activity was associated with them. Most of our stealth CMEs also lacked on-limb EUV signatures. We found that stealth CMEs generally lack the leading bright front in coronagraph images. This is in accordance with previous studies that argued that stealth CMEs form more slowly and at higher coronal altitudes than non-stealth CMEs. We suggest that at solar minimum the slow-rising CMEs do not draw enough coronal plasma around them. These CMEs are hence difficult to discern in the coronagraphic data, even when viewed close to the plane of the sky. The weak ICMEs in our study were related to both intrinsically narrow CMEs and the non-central encounters of larger CMEs. We also demonstrate that narrow CMEs (angular widths ≤?20^°) can arrive at Earth and that an unstructured CME may result in a flux rope-type ICME.     

Experiments using new initial soil moisture conditions and soil map in the Eta model over La Plata Basin

An effort towards a more accurate representation of soil moisture and its impact on the modeling of weather systems is presented. Sensitivity tests of precipitation to soil type and soil moisture changes are carried out using the atmospheric Eta model for the numerical simulation of the development of a mesoscale convective system over northern Argentina. Modified initial soil moisture conditions were obtained from a hydrological balance model developed and running operationally at INPE. A new soil map was elaborated using the available soil profile information from Brazil, Paraguay, Uruguay, and Argentina and depicts 18 different soil types. Results indicate that more accurate initial soil moisture conditions and incorporating a new soil map with hydraulic parameters, more representative of South American soils, improve daily total precipitation forecasts both in quantitative and spatial representations.     

Understanding carbon trading: Effects of delegating CO2 responsibility on organizations’ trading behaviour

The establishment of a carbon market assumes that there is an effective means of transforming price information into technical carbon reduction measures. However, empirical evidence reveals that the links between price information and carbon management strategies are far from obvious. To understand how delegating CO₂ responsibility affects CO₂ trading behaviour, this article proposes a neo-institutionalist approach to answering the question of why companies became sellers, buyers or a combination of both during phase I of the European Emissions Trading Scheme (EU ETS). Original data from a survey on companies that participated in this scheme were collected and analysed. It was assumed that the trading scheme offered two ways to delegate decisions regarding emissions trading: decoupling from technical knowledge and financialization (i.e. delegating to financial departments) or coupling using technicalization (i.e. delegating to manufacturing departments). The results support the hypothesis that a company that adopts a decoupling strategy is more likely to buy certificates to fulfil their emissions targets. Adopting a coupling strategy indicates that a company is more likely to become a seller, all else equal. Professional identity is the theoretical basis for this relationship. Delegating carbon management to different departments represents either a stronger coupling or a stronger decoupling from core technological processes.

Policy relevance

The transaction data from phase I of the EU ETS open new questions and possibilities regarding the reasons that drive selling and buying in companies. It is important to look not only at the traditional sources of transaction costs, but rather also at the reasons for these tensions. One important source is the professional education of the people in charge of the EU ETS. Tailored information that directly addresses the different professional backgrounds of managers working in both financial departments and more technical departments might help to lower these types of transaction costs. In today's context, important emitter countries, such as China and Korea, have launched their own emissions markets, copying many aspects of the EU ETS. For the positive development of these markets and as a way of establishing a global emissions market, these new schemes should learn from the EU ETS experience.     

Decadal predictability and prediction skill of sea surface temperatures in the South Pacific region

The South Pacific Ocean is a key driver of climate variability within the Southern Hemisphere at different time scales. Previous studies have characterized the main mode of interannual sea surface temperature (SST) variability in that region as a dipolar pattern of SST anomalies that cover subtropical and extratropical latitudes (the South Pacific Ocean Dipole, or SPOD), which is related to precipitation and temperature anomalies over several regions throughout the Southern Hemisphere. Using that relationship and the reported low predictive skill of precipitation anomalies over the Southern Hemisphere, this work explores the predictability and prediction skill of the SPOD in near-term climate hindcasts using a set of state-of-the-art forecast systems. Results show that predictability greatly benefits from initializing the hindcasts beyond the prescribed radiative forcing, and is modulated by known modes of climate variability, namely El Niño-Southern Oscillation and the Interdecadal Pacific Oscillation. Furthermore, the models are capable of simulating the spatial pattern of the observed SPOD even without initialization, which suggests that the key dynamical processes are properly represented. However, the hindcast of the actual phase of the mode is only achieved when the forecast systems are initialized, pointing at SPOD variability to not be radiatively forced but probably internally generated. The comparison with the performance of an empirical prediction based on persistence suggests that initialization may provide skillful information for SST anomalies, outperforming damping processes, up to 2–3 years into the future.     

Metal ion remediation by polyamidoamine dendrimers: a comparison of metal ion,oxidation state,and titania immobilization

The exceptional ability of dendrimers to coordinate metal ions yields the potential for many applications including wastewater remediation, which is the focus of this study. Here, the comparison of metal ion removal rate from simulated wastewater by generation 4 dendrimers with external hydroxyl functional groups (G4-OH) is evaluated for Ni²⁺, Fe²⁺, and Fe³⁺ ions. Ni²⁺ to amine complexation occurred more rapidly than Fe³⁺, which was more rapid than Fe²⁺ complexation. These results indicate that both charge density and d-electron configuration are important toward the chelation rate. The impact of both factors is discussed in light of existing models in which precursor aquation rates have been proposed as a key intermediate step. Additionally, the application of the dendrimers as chelation agents is further advanced by immobilizing the dendrimer to titania and re-evaluating its chelation ability for Ni²⁺ removal. The dendrimer immobilization decreased the pseudo-first-order rate coefficient for Ni²⁺—amine complexation at a pH of 7 by a factor of 7.5. This result is significant as it suggests that mass transfer becomes important following immobilization of the dendrimer to titania.     

Application of Laser‐Induced Breakdown Spectroscopy and Hyperspectral Images for Direct Evaluation of Chemical Elemental Profiles of Coprolites

This study demonstrates the application of laser‐induced breakdown spectroscopy (LIBS) and hyperspectral imaging to the investigation of coprolite and fossil samples. Solid samples from the Permian (seven coprolites and one fossil), Cretaceous (one coprolite) and Oligo‐Miocene (two coprolites) periods were directly analysed, and emission spectra from 186 to 1042 nm were obtained in several areas covering coprolite/fossil and rock material. Initial exploratory analyses were performed using principal component analysis with the data set normalised by the norm (Euclidean norm = 1). After identification and selection of emission lines of eleven elements (Al, Ca, Cr, Fe, K, Mg, Mn, Na, Ni, P and Si), the signals were normalised again by the relative intensity of the selected element. Phosphorus was identified mainly in the coprolites, while K and Na were primarily found in the rock material. In several cases, there was a positive correlation between Ca and P. A sample from the Oligo‐Miocene series was also analysed using inductively coupled plasma‐optical emission spectrometry (ICP‐OES) (rock and coprolites were analysed separately). Based on the quantitative results from ICP‐OES, it was confirmed that the tendency was the same as that observed with the results obtained from LIBS directly in the solid sample.