North polar region of Mars: Advances in stratigraphy, structure, and erosional modification

We have remapped the geology of the north polar plateau on Mars, Planum Boreum, and the surrounding plains of Vastitas Borealis using altimetry and image data along with thematic maps resulting from observations made by the Mars Global Surveyor, Mars Odyssey, Mars Express, and Mars Reconnaissance Orbiter spacecraft. New and revised geographic and geologic terminologies assist with effectively discussing the various features of this region. We identify 7 geologic units making up Planum Boreum and at least 3 for the circumpolar plains, which collectively span the entire Amazonian Period. The Planum Boreum units resolve at least 6 distinct depositional and 5 erosional episodes. The first major stage of activity includes the Early Amazonian (∼3 to 1 Ga) deposition (and subsequent erosion) of the thick (locally exceeding 1000 m) and evenly-layered Rupes Tenuis unit (Abrt), which ultimately formed approximately half of the base of Planum Boreum. As previously suggested, this unit may be sourced by materials derived from the nearby Scandia region, and we interpret that it may correlate with the deposits that regionally underlie pedestal craters in the surrounding lowland plains. The second major episode of activity during the Middle to Late Amazonian (1 Ga) began with a section of dark, sand-rich and light-toned ice-rich irregularly-bedded sequences (Planum Boreum cavi unit, Abb_c) along with deposition of evenly-bedded light-toned ice- and moderate-toned dust-rich layers (Planum Boreum 1 unit, Abb₁). These units have transgressive and gradational stratigraphic relationships. Materials in Olympia Planum underlying the dunes of Olympia Undae are interpreted to consist mostly of the Planum Boreum cavi unit (Abb_c). Planum Boreum materials were then deeply eroded to form spiral troughs, Chasma Boreale, and marginal scarps that define the major aspects of the polar plateau's current regional topography. Locally- to regionally-extensive (though vertically minor) episodes of deposition of evenly-bedded, light- and dark-toned layered materials and subsequent erosion of these materials persisted throughout the Late Amazonian. Sand saltation, including dune migration, is likely to account for much of the erosion of Planum Boreum, particularly at its margin, alluding to the lengthy sedimentological history of the circum-polar dune fields. Such erosion has been controlled largely by topographic effects on wind patterns and the variable resistance to erosion of materials (fresh and altered) and physiographic features. Some present-day dune fields may be hundreds of kilometers removed from possible sources along the margins of Planum Boreum, and dark materials, comprised of sand sheets, extend even farther downwind. These deposits also attest to the lengthy period of erosion following emplacement of the Planum Boreum 1 unit. We find no evidence for extensive glacial flow, topographic relaxation, or basal melting of Planum Boreum materials. However, minor development of normal faults and wrinkle ridges may suggest differential compaction of materials across buried scarps. Timing relations are poorly-defined mostly because resurfacing and other uncertainties prohibit precise determinations of surface impact crater densities. The majority of the stratigraphic record may predate the recent (<20 Ma) part of the orbitally-driven climate record that can be reliably calculated. Given the strong stratigraphic but loose temporal constraints of the north polar geologic record, a comparison of north and south polar stratigraphy permits a speculative scenario in which major Amazonian depositional and erosional episodes driven by global climate activity is plausible.     

Peering through the stellar wind of IGR J19140+0951 with simultaneous INTEGRAL/RXTE observations

We have used the RXTE and INTEGRAL satellites simultaneously to observe the high-mass X-ray binary (HMXB) IGR J19140+0951. The spectra obtained in the 3–80 keV range have allowed us to perform a precise spectral analysis of the system along its binary orbit. The spectral evolution confirms the supergiant nature of the companion star and the neutron star nature of the compact object. Using a simple stellar wind model to describe the evolution of the photoelectric absorption, we were able to restrict the orbital inclination angle in the range 38°–75°. This analysis leads to a wind mass-loss rate from the companion star of  ∼5 × 10⁻⁸ M_⊙ yr⁻¹  , consistent with an OB I spectral type. We have detected a soft excess in at least four observations, for the first time for this source. Such soft excesses have been reported in several HMXBs in the past. We discuss the possible origin of this excess, and suggest, based on its spectral properties and occurrences around the superior conjunction, that it may be explained as the reprocessing of the X-ray emission originating from the neutron star by the surrounding ionized gas.     

Cs baseline levels in the Mediterranean and Black Sea: A cross-basin survey of the CIESM Mediterranean Mussel Watch programme

The common mussel Mytilus galloprovincialis was selected as unique biomonitor species to implement a regional monitoring programme, the CIESM Mediterranean Mussel Watch (MMW), in the Mediterranean and Black Seas. As of today, and upon standardization of the methodological approach, the MMW Network has been able to quantify ¹³⁷Cs levels in mussels from 60 coastal stations and to produce the first distribution map of this artificial radionuclide at the scale of the entire Mediterranean and Black Seas. While measured ¹³⁷Cs levels were found to be very low (usually <1 Bq kg⁻¹ wet wt) ¹³⁷Cs activity concentrations in the Black Sea and North Aegean Sea were up to two orders of magnitude higher than those in the western Mediterranean Basin. Such effects, far from representing a threat to human populations or the environment, reflect a persistent signature of the Chernobyl fallout in this area.     

Major and trace element and Sr–Nd isotope signatures of lavas from the Central Lau Basin: Implications for the nature and influence of subduction components in the back-arc mantle

New major and trace element and Sr–Nd isotope data are presented for basaltic glasses from active spreading centers (Central Lau Spreading Center (CLSC), Relay Zone (RZ) and Eastern Lau Spreading Center (ELSC)) in the Central Lau Basin, SW Pacific. Basaltic lavas from the Central Lau Basin are mainly tholeiitic and are broadly similar in composition to mid-ocean ridge basalts (MORB). Their generally high ⁸⁷Sr/⁸⁶Sr ratios, combined with relatively low ¹⁴³Nd/¹⁴⁴Nd ratios are more akin to MORB from the Indian rather than Pacific Ocean. In detail, the CLSC, RZ and ELSC lavas are generally more enriched in large ion lithophile elements (Rb, Ba, Sr, and K) than average normal-MORB, which suggests that the mantle beneath the Central Lau Basin was modified by subducted slab-derived components. Fluid mobile/immobile trace element and Sr – Nd isotope ratios suggest that the subduction components were essentially transferred into the mantle via hydrous fluids derived from the subducted oceanic crust; contributions coming from the subducted sediments are minor. Compared to CLSC lavas, ELSC and RZ lavas show greater enrichment in fluid mobile elements and depletion in high field strength elements, especially Nb. Thus, with increasing distance away from the arc, the influence of subduction components in the mantle source of Lau Basin lavas diminishes. The amount of hydrous fluids also influences the degree of partial melting of the mantle beneath the Central Lau Basin, and hence the degree of melting also decreases with increasing distance from the arc.     

Determination of both exposure time and denudation rate from an in situ-produced 10Be depth profile: A mathematical proof of uniqueness. Model sensitivity and applications to natural cases

Measurements of radioactive in situ-produced cosmogenic nuclide concentrations in surficial material exposed to cosmic rays allow either determining the long-term denudation rate assuming that the surface studied has reached steady-state (where production and losses by denudation and radioactive decay are in equilibrium) (infinite exposure time), or dating the initiation of exposure to cosmic rays, assuming that the denudation and post-depositional processes are negligible. Criteria for determining whether a surface is eroding or undergoing burial as well as quantitative information on denudation or burial rates may be obtained from cosmogenic nuclide depth profiles. With the refinement of the physical parameters involved in the production of in situ-produced cosmogenic nuclides, a unique well-constrained depth profile now permits determination of both the exposure time and the denudation rate affecting a surface. In this paper, we first mathematically demonstrate that the exponential decrease of the in situ-produced ¹⁰Be concentrations observed along a depth profile constrains a unique exposure time and denudation rate when considering both neutrons and muons. In the second part, an improved chi-square inversion model is described and tested in the third part with actual measured profiles.     

Influence of tide and waves on water renewal in Óbidos Lagoon, Portugal

The role of oceanic tide, wind stress, freshwater river inflows, and waves in the long-term circulation and residence time in óbidos Lagoon is investigated using a sensitivity analysis carried out by means of a two-dimensional model. MOHID modeling system coupled to Steady-State Spectral Wave model for simulate óbidos Lagoon circulation were implemented. For residence time calculus, a Lagrangian transport model was used. Tidal forcing is shown to be the dominant forcing, although storm waves must be considered to simulate accurately the long-term circulation. Tidal forcing enhances a spatial distribution in water residence time. Renewal time scales varies from values of 2 days in the near-ocean areas and 3 weeks in the inner areas. Freshwater river inflows decrease the residence time, while waves increase. In heavy rain periods, the water residence time decreases by about 40% in the upper lagoon. When wave forcing is considered, the residence time increases between 10% and 50% depending on lagoon area. The increase in residence time is explained by the sea level rise within lagoon (~1 m above average lagoon sea level) during storm wave periods. Average residence time is 16 days for tidal forcing, 9 days when the rivers are included (wet period), and 18 days when the waves are considered.     

Application of Laser‐Induced Breakdown Spectroscopy and Hyperspectral Images for Direct Evaluation of Chemical Elemental Profiles of Coprolites

This study demonstrates the application of laser‐induced breakdown spectroscopy (LIBS) and hyperspectral imaging to the investigation of coprolite and fossil samples. Solid samples from the Permian (seven coprolites and one fossil), Cretaceous (one coprolite) and Oligo‐Miocene (two coprolites) periods were directly analysed, and emission spectra from 186 to 1042 nm were obtained in several areas covering coprolite/fossil and rock material. Initial exploratory analyses were performed using principal component analysis with the data set normalised by the norm (Euclidean norm = 1). After identification and selection of emission lines of eleven elements (Al, Ca, Cr, Fe, K, Mg, Mn, Na, Ni, P and Si), the signals were normalised again by the relative intensity of the selected element. Phosphorus was identified mainly in the coprolites, while K and Na were primarily found in the rock material. In several cases, there was a positive correlation between Ca and P. A sample from the Oligo‐Miocene series was also analysed using inductively coupled plasma‐optical emission spectrometry (ICP‐OES) (rock and coprolites were analysed separately). Based on the quantitative results from ICP‐OES, it was confirmed that the tendency was the same as that observed with the results obtained from LIBS directly in the solid sample.     

Accumulation of lead and associated metals (Cu and Zn) at different growth stages of soybean crops in lead-contaminated soils: food security and crop quality implications

The Pb, Cu and Zn content, the physicochemical parameters in soils (EC, OM%, soil texture and pH) and the metal accumulation of Glycine max plants at different growth stages were evaluated. Topsoil and soybean samples were collected in the vicinity of a former battery-recycling plant, with the results showing that only the concentrations of Pb in soils corresponding to sites located near to the lead emission source were above the maximum permissible levels. However, soybean crops accumulated Pb above the permitted levels at all studied sites, revealing a potential toxicological risk for direct consumption. Thus, the accumulation of Pb in soybean was directly related to the translocation factor of the metal from roots to aerial parts of the plant. This was evidenced as a lower accumulation at early growth stages and a higher accumulation at maturity, with the distribution between organs coinciding with nutrient incorporation and remobilization in the plant. Moreover, the bioconcentration factor revealed that the bioaccumulation of lead in soybean was a consequence of the lead-recycling plant activity in the past. Taken together, results of the present study demonstrated that soybean crops can incorporate and accumulate potentially toxic metals, such as lead.     

Plankton carbon metabolism and air–water CO2 fluxes at a hypereutrophic tropical estuary

Multiple biotic and abiotic drivers regulate the balance between CO₂ assimilation and release in surface waters. In the present study, we compared in situ measurements of plankton carbon metabolism (primary production and respiration) to calculated air–water CO₂ fluxes (based on abiotic parameters) during 1 year (2008) in a hypereutrophic tropical estuary (Recife Harbor, NE Brazil – 08°03′S, 34°52′W) to test the hypothesis that high productivity leads to a net CO₂ flux from the atmosphere. The calculated CO₂ fluxes through the air–water interface (FCO₂) were negative throughout the year (FCO₂: –2 to –9 mmol C·m^?2·day^?1), indicating that Recife Harbor is an atmospheric CO₂ sink. Respiration rates of the plankton community ranged from 2 to 45 mmol C·m^?2·hr^?1. Gross primary production ranged from 0.2 to 281 mmol C·m^?2·hr^?1, exceeding respiration during most of the year (net autotrophy), except for the end of the wet season, when the water column was net heterotrophic. The present results highlight the importance of including eutrophic tropical shallow estuaries in global air–water CO₂ flux studies, in order to better understand their role as a sink of atmospheric CO₂.