On the tuning of a wave-energy driven oscillating-water-column seawater pump to polychromatic waves

Performance of wave-energy devices of the oscillating water column (OWC) type is greatly enhanced when a resonant condition with the forcing waves is maintained. The natural frequency of such systems can in general be tuned to resonate with a given wave forcing frequency. In this paper we address the tuning of an OWC sea-water pump to polychromatic waves. We report results of wave tank experiments, which were conducted with a scale model of the pump. Also, a numerical solution for the pump equations, which were proven in previous work to successfully describe its behavior when driven by monochromatic waves, is tested with various polychromatic wave spectra. Results of the numerical model forced by the wave trains measured in the wave tank experiments are used to develop a tuning criterion for the sea-water pump.     

The origin of groundwater arsenic and fluorine in a volcanic sedimentary basin in central Mexico: a hydrochemistry hypothesis

A groundwater sampling campaign was carried out in the summer of 2013 in a low-temperature geothermal system located in Juventino Rosas (JR) municipality, Guanajuato State, Mexico. This groundwater presents high concentrations of As and F^? and high Rn counts, mainly in wells with relatively higher temperature. The chemistry of major elements was interpreted with different methods, like Piper and D’Amore diagrams. These diagrams allowed for classification of four groundwater types located in three hydrogeological environments. The aquifers are hosted mainly in alluvial-lacustrine sediments and volcanic rocks in interaction with fault and fracture systems. The subsidence, faults and fractures observed in the study area can act as preferential channels for recharge and also for the transport of deep fluids to the surface, especially in the basin plain. The formation of a piezometric dome and the observed hydrochemical behavior of groundwater suggest a possible origin of the As and F^?. Geochemical processes occurring during water–rock interaction are related to high concentrations of As and F^?. High temperatures and alteration processes (like rock weathering) induce dissolution of As and F^?-bearing minerals, increasing the content of these elements in groundwater.     

An evaluation of trace metal distribution, enrichment factors and risk in sediments of a coastal lagoon (Ria de Aveiro, Portugal)

This paper describes a sediment survey undertaken to unravel patterns of distribution and dispersion of trace metals in an Iberian Peninsula northwestern coastal lagoon (Ria de Aveiro). Cadmium, lead, chromium, copper and zinc were analyzed in bottom sediments. Geochemical normalization is performed and two different regression models for each metal versus aluminum are tested and compared using the respective enrichment factors (EF), an estimation of the relative importance of anthropogenic contributions to the studied sediments. Mean sediment quality guideline quotients (mSQGQ) are used to evaluate sediment quality and associated potential risk to biota with effects range low as empirical sediment quality guideline (SQG) in the basis for mSQGQ calculation. Additionally, the geoaccumulation index is calculated to compare studied sediment levels to global baseline levels. The application of SQGs revealed insufficient characterization capability, especially when contrasted to EF calculated from the regression methods. These pointed a mildly enriched system with localized ??hot spot?? areas. Therefore, it can be considered that bottom sediments in the Ria de Aveiro system are in their majority unpolluted, zinc being the only metal of concern, presenting enrichment in all four main channels. The major rivers outlets (Caster, Antu?, and Vouga) constitute point sources, thus presenting potential risk for biota. Yet, the strong tidal influence creates a damping effect by efficiently redistributing sediment bound metals.     

Unroofing the core of the central Andean fold‐thrust belt during focused late Miocene exhumation: evidence from the Tipuani‐Mapiri wedge‐top basin,Bolivia

As the highest part of the central Andean fold‐thrust belt, the Eastern Cordillera defines an orographic barrier dividing the Altiplano hinterland from the South American foreland. Although the Eastern Cordillera influences the climatic and geomorphic evolution of the central Andes, the interplay among tectonics, climate and erosion remains unclear. We investigate these relationships through analyses of the depositional systems, sediment provenance and ⁴⁰Ar/³⁹Ar geochronology of the upper Miocene Cangalli Formation exposed in the Tipuani‐Mapiri basin (15–16°S) along the boundary of the Eastern Cordillera and Interandean Zone in Bolivia. Results indicate that coarse‐grained nonmarine sediments accumulated in a wedge‐top basin upon a palaeotopographic surface deeply incised into deformed Palaeozoic rocks. Seven lithofacies and three lithofacies associations reflect deposition by high‐energy braided river systems, with stratigraphic relationships revealing significant (～500 m) palaeorelief. Palaeocurrents and compositional provenance data link sediment accumulation to pronounced late Miocene erosion of the deepest levels of the Eastern Cordillera. ⁴⁰Ar/³⁹Ar ages of interbedded tuffs suggest that sedimentation along the Eastern Cordillera–Interandean Zone boundary was ongoing by 9.2 Ma and continued until at least ～7.4 Ma. Limited deformation of subhorizontal basin fill, in comparison with folded and faulted rocks of the unconformably underlying Palaeozoic section, implies that the thrust front had advanced into the Subandean Zone by the 11–9 Ma onset of basin filling. Documented rapid exhumation of the Eastern Cordillera from ～11 Ma onward was decoupled from upper‐crustal shortening and coeval with sedimentation in the Tipuani‐Mapiri basin, suggesting climate change (enhanced precipitation) or lower crustal and mantle processes (stacking of basement thrust sheets or removal of mantle lithosphere) as possible controls on late Cenozoic erosion and wedge‐top accumulation. Regardless of the precise trigger, we propose that an abruptly increased supply of wedge‐top sediment produced an additional sedimentary load that helped promote late Miocene advance of the central Andean thrust front in the Subandean Zone.     

Dynamical System Analysis and Forecasting of Deformation Produced by an Earthquake Fault

— We present a method of constructing low-dimensional nonlinear models describing the main dynamical features of a discrete 2-D cellular fault zone, with many degrees of freedom, embedded in a 3-D elastic solid. A given fault system is characterized by a set of parameters that describe the dynamics, rheology, property disorder, and fault geometry. Depending on the location in the system parameter space, we show that the coarse dynamics of the fault can be confined to an attractor whose dimension is significantly smaller than the space in which the dynamics takes place. Our strategy of system reduction is to search for a few coherent structures that dominate the dynamics and to capture the interaction between these coherent structures. The identification of the basic interacting structures is obtained by applying the Proper Orthogonal Decomposition (POD) to the surface deformation fields that accompany strike-slip faulting accumulated over equal time intervals. We use a feed-forward artificial neural network (ANN) architecture for the identification of the system dynamics projected onto the subspace (model space) spanned by the most energetic coherent structures. The ANN is trained using a standard back-propagation algorithm to predict (map) the values of the observed model state at a future time, given the observed model state at the present time. This ANN provides an approximate, large-scale, dynamical model for the fault. The map can be evaluated once to provide a short-term predictions or iterated to obtain a prediction for the long-term fault dynamics.     

Study of the Santa Catarina aquifer system (Mexico Basin) using magnetotelluric soundings

A tensor magnetotelluric test survey was carried out in the region of Santa Catarina, located in the Chalco sub-basin of the Mexico Basin. The objective was to define the stratification at depth with an emphasis on the geometry of the main aquifer of that region which is partially known from DC resistivity soundings and drilling. High-quality magnetotelluric soundings could be recorded in the immediate vicinity of large urban zones because the sub-surface is very conductive. Interpretation shows that the solid bedrock is located at a depth of at least 800 m to the south and 1300 m to the north; it could, however, be much deeper. Using complementary DC resistivity sounding and well-logging data, three main layers have been defined overlying the bedrock. These layers are, from surface to bottom, an unsaturated zone of sand, volcanic ash and clay about 10 m thick, followed by a very conductive (1.5 ohm·m) 200 m thick layer of sand and ash with intercalated clay, saturated with highly mineralized water, and finally a zone with resistivity increasing gradually to 60 ohm·m. The investigated deep aquifer constitutes most of this third layer. It consists of a sequence of sand, gravel, pyroclastites and mainly fractured basalts. MT resistivity soundings and magnetic transfer functions also indicate that a shallow resistive structure is dipping, from the northwest, into the lacustrine deposits of the basin. This geologic feature is likely to be highly permeable fractured basaltic flows, which provide a channel by which water contaminated by the Santa Catarina landfill may leak into the basin.     

Integrated modelling for water quality management in a eutrophic reservoir in south-eastern Portugal

The Enxoé Reservoir was built in 1998. Since 2000, it has exhibited frequent high chlorophyll-a concentrations, reaching a geometric mean three times higher than the national limit for eutrophication, presenting the reservoir with the highest eutrophic state in Portugal. Toxic algal blooms have also often been observed, which pose serious challenges to water managers, as the reservoir is used for potable water production (25,000 inhabitants). The objective of this study was to implement a reservoir model (CE-QUAL-W2), with inputs from a watershed model (SWAT), in order to represent the actual reservoir state and to test management measures to reduce its trophic level and algal bloom concentration peaks. The integrated model was used to depict the origin of its trophic status. Simulations were also compared to measured data at the reservoir surface (water level, nitrate, orthophosphate, suspended solids, and oxygen) and in water profiles (temperature, oxygen). The model was able to represent stratification and thermocline depths, as well as the actual chlorophyll-a and dissolved oxygen concentrations. The model results showed that internal phosphorus load from deposited sediments was an important factor in fuelling the algal blooms. This process occurs predominantly in summer, when stratification takes place and aeration is reduced, promoting anoxic conditions in the bottom waters. Since the reservoir is relatively shallow (average 5 m), released phosphorus is then easily able to reach the photic zone in most parts of the reservoir, where it is consumed. Different management scenarios were tested, suggesting that a mesotrophic level could barely be reached and maintained simply by reducing the nutrient loads (both external and internal). It is suggested that only an increase in the reservoir dam height could produce a mesotrophic level, averting anoxia by blocking the release of phosphorus from sediments to the photic zone. Future work should focus on a cost–benefit analysis to test the feasibility of each of the proposed scenarios, taking advantage of the integration strategy to assess where in the watershed load reductions would be most effective.     

The autonomous <Emphasis Type="Italic">Simpatico</Emphasis> system for real-time continuous water-quality and current velocity monitoring: examples of application in three Portuguese estuaries

This technical paper describes an autonomous recording system with remote data access for the continuous, long-term in situ monitoring of water quality and discharge, as well as current velocity. The Simpatico system has been recently deployed in three estuaries in Portugal (Mondego and Tagus in July 2007; Guadiana in March 2008), highly suitable to illustrate its multifaceted potential applications: surveillance of the effects of mitigation measures to combat eutrophication (lower Mondego Estuary); real-time implementation of boundary conditions for a water modelling system (upper Tagus Estuary); study of dam-induced impacts in terms of water quality, water discharge and sediment budgets (mouth of the Guadiana Estuary). An extract of recorded data serves as an example to discuss data reliability, as well as field maintenance of the system, with implications for labour and operational costs. The use of a new generation of copper-based anti-biofouling kits significantly reduced the need for field maintenance operations. Other examples of possible application of the system include the assessment of gas accumulation in coastal waters.     

The Rondonian-San Ignacio Province in the SW Amazonian Craton: An overview

The Rondonian-San Ignacio Province (1.56–1.30 Ga) is a composite orogen created through successive accretion of arcs, ocean basin closure and final oblique microcontinent–continent collision. The effects of the collision are well preserved mostly in the Paraguá Terrane (Bolivia and Mato Grosso regions) and in the Alto Guaporé Belt and the Rio Negro-Juruena Province (Rondônia region), considering that the province was affected by later collision-related deformation and metamorphism during the Sunsás Orogeny (1.25–1.00 Ga). The Rondonian-San Ignacio Province comprises: (1) the Jauru Terrane (1.78–1.42 Ga) that hosts Paleoproterozoic basement (1.78–1.72 Ga), and the Cachoeirinha (1.56–1.52 Ga) and the Santa Helena (1.48–1.42 Ga) accretionary orogens, both developed in an Andean-type magmatic arc; (2) the Paraguá Terrane (1.74–1.32 Ga) that hosts pre-San Ignacio units (>1640 Ma: Chiquitania Gneiss Complex, San Ignacio Schist Group and Lomas Manechis Granulitic Complex) and the Pensamiento Granitoid Complex (1.37–1.34 Ga) developed in an Andean-type magmatic arc; (3) the Rio Alegre Terrane (1.51–1.38 Ga) that includes units generated in a mid-ocean ridge and an intra-oceanic magmatic arc environments; and (4) the Alto Guaporé Belt (<1.42–1.34 Ga) that hosts units developed in passive marginal basin and intra-oceanic arc settings. The collisional stage (1.34–1.32 Ga) is characterized by deformation, high-grade metamorphism, and partial melting during the metamorphic peak, which affected primarily the Chiquitania Gneiss Complex and Lomas Manechis Granulitic Complex in the Paraguá Terrane, and the Colorado Complex and the Nova Mamoré Metamorphic Suite in the Alto Guaporé Belt. The Paraguá Block is here considered as a crustal fragment probably displaced from its Rio Negro-Juruena crustal counterpart between 1.50 and 1.40 Ga. This period is characterized by extensive A-type and intra-plate granite magmatism represented by the Rio Crespo Intrusive Suite (ca. 1.50 Ga), Santo Antonio Intrusive Suite (1.40–1.36 Ga), and the Teotônio Intrusive Suite (1.38 Ga). Magmatism of these types also occur at the end of the Rondonian-San Ignacio Orogeny, and are represented by the Alto Candeias Intrusive Suite (1.34–1.36 Ga), and the São Lourenço-Caripunas Intrusive Suite (1.31–1.30 Ga). The cratonization of the province occurred between 1.30 and 1.25 Ga.