Geochemistry of metabauxites in the Bergsträsser Odenwald (Mid German Crystalline Rise) and palaeoenvironmental implications

Summary Pre- to early Variscan metamorphosed volcano-sedimentary series of the western (Bergstr?sser) Odenwald have been intruded by Variscan calc-alkaline magmatites with plate margin affinities. Within the NE-SW trending metabasic and metapelitic series, intercalations of anomalously aluminous- and iron-rich compositions representing former bauxites are distinguishable. Geochemical data indicate that the Al-, Fe-rich rocks are the metamorphic equivalents of a former bauxitic-ferralitic weathering profile, now comprising spinel fels (top) with relics of pisolitic structures, corundum-chlorite fels, corundum-cordierite-plagioclase gneiss, sillimanite-cordierite-plagioclase gneiss, cordierite-plagioclase gneiss and kinzigite (base) displaying a decrease of weathering in the order as listed. The evolution of such terrestrial sediments is related to specific climatic, environmental, and physico-chemical conditions similar to those of the present-day tropical to subtropical humid regions with high seasonal rains and intensive drainage. Comparison with palaeomagnetic and palaeoclimatic data indicate that the Odenwald metabauxites originally formed during the Lower to Mid-Devonian. Our results imply that, during this geological time span, parts of the precursors of the Mid-German Crystalline Rise not only transversed low latitudes but also were exposed to terrestrial weathering.

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Zusammenfassung Die Geochemie der Metabauxite im Bergstr?sser Odenwald (Mitteldeutsche Kristallinschwelle) und ihre Bedeutung für das Pal?omilieu Im westlichen (Bergstr?sser) Odenwald intrudierten variszische Plattenrand-Kalkalkali-Magmatite in pr?- bis früh-variszische, ehemalige vulkano-sediment?re Serien. Innerhalb der heute NE-SW streichenden Metabasit- und Metapelitzüge treten lokal Al-Fe-reiche Einschaltungen auf, die strukturell und geochemisch als metamorphe ?quivalente eines ehemaligen bauxitisch-ferralitischen Verwitterungsprofils klassifiziert werden k?nnen. Sie umfassen Spinellfelse mit erhaltenen, ehemaligen zonierten Pisolithen, Korund-Chloritfelse, Korund-Cordierit-Plagioklasgneise, Sillimanit-Cordierit-Plagioklasgneise, Cordierit-Plagioklasgneise und Kinzigite. Bauxite k?nnen als terrestrische Bildungen nur unter speziellen klimatischen und physiko-chemischen Bedingungen entstehen. Pal?omagnetische und pal?oklimatische Daten legen die Bildung der ehemaligen Bauxite im unteren bis mittleren Devon nahe. Daraus folgt, da? w?hrend dieser geologischen Zeitspanne die Vorl?ufer der mitteldeutschen Kristallinschwelle bei der Norddrift nicht nur ?quatorn?he passierten, sondern auch partiell ungest?rte, terrestrische, tropisch-subtropische Verwitterungsprozesse abliefen.

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Received June 10, 1999; revised version accepted October 30, 2000     

Prospects for astrometry with the Hubble Space Telescope

The Hubble Space Telescope (HST), a large optical telescope having an aperture of 2.4 meters and a length of 8.8 meters, is being developed by the National Aeronautics and Space Administration. This telescope will be placed into earth orbit by the space shuttle. Astrometric observations with the HST are made using a Fine Guidance Sensor which is capable of measuring the position of one object relative to another with an accuracy of ±0.002 arcseconds. The astrometric user of HST will be provided with an Astrometric Data Reduction Software package (ADRS). The variety of astrometric problems to be investigated with HST is discussed.     

Going underground: in search of Carboniferous coal forests

The development of coal forests during the Carboniferous is one of the best-known episodes in the history of life. Although often reconstructed as steamy tropical rainforests, these ancient ecosystems were a far cry from anything we might encounter in the Amazon today. Bizarre giant club-mosses, horsetails and tree ferns were the dominant plants, not flowering trees as in modern rainforests. At their height, coal forests stretched all the way from Kansas to Kazakhstan, spanning the entire breadth of tropical Pangaea. Most of what we know of their biodiversity and ecology has been quite literally mined out of the ground through two centuries of hard labour. Without coal mining, our knowledge would be greatly impoverished. Over the past few years, we've been exploring underground coal mines in the United States, where entire forested landscapes have been preserved intact over huge areas. Never before have geologists had the opportunity to walk out through mile upon mile of fossilized forest. In this feature article, we describe some of our recent explorations and attempt to shed new light on these old fossils.     

The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.     

Zircon U–Pb age, trace element and Hf isotope composition of Kongling terrane in the Yangtze Craton: refining the timing of Palaeoproterozoic high-grade metamorphism

U–Pb age, trace element and Hf isotope compositions of zircon were analysed for a metasedimentary rock and two amphibolites from the Kongling terrane in the northern part of the Yangtze Craton. The zircon shows distinct morphological and chemical characteristics. Most zircon in an amphibolite shows oscillatory zoning, high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, high formation temperature, high trace element contents, clear negative Eu anomaly, as well as HREE-enriched patterns, suggesting that it is igneous. The zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2857 ± 8 Ma, representing the age of the magmatic protolith. The zircon in the other two samples is metamorphic. It has low Th/U ratios, low trace element concentrations, variable HREE contents (33.8 ≥ Lu_N≥2213; 14.7 ≤ Lu_N/Sm_N ≤ 354) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.000030–0.001168). The data indicate that the zircon formed in the presence of garnet and under upper amphibolite facies conditions. The metamorphic zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2010 ± 13 Ma. These results combined with previously obtained Palaeoproterozoic metamorphic ages suggest a c. 2.0 Ga Palaeoproterozoic collisional event in the Yangtze Craton, which may result from the assembly of the supercontinent Columbia. The zircon in two samples yields weighted mean two-stage Hf model ( T _DM2) ages of 3217 ± 110 and 2943 ± 50 Ma, respectively, indicating that their protoliths were mainly derived from Archean crust.     

Optimal deflection of NEOs en route of collision with the Earth

Recently, a method for the n-body analysis of the velocity change required to deflect a hazardous near-Earth object (NEO) was presented by Carusi et al. [Carusi, A., Valsecchi, G.B., D'Abramo, G., Boattini A., 2002. Icarus 159, 417-422]. We extent this method in order to optimize the velocity change vector instead of its along-track magnitude. From an application of both methods to a fictitious NEO we find Carusi's parallel approach to be reasonable for phases of unperturbed two-body motion. But, for orbit phases inhering third-body perturbations, i.e., for planetary close approaches or prior to a collision, the results obtained from the new method show the radial component of deflection impulse to play a major role. We show that a fivefold greater efficiency can be achieved by a deflection impulse being non-parallel to orbital velocity. The new method is applied to two possible 99942 Apophis impact trajectories in order to provide constraints for future Apophis deflection mission analysis.     

Impact processing of chondritic planetesimals: Siderophile and volatile element fractionation in the Chico L chondrite

Abstract— A large impact event 500 Ma ago shocked and melted portions of the L‐chondrite parent body. Chico is an impact melt breccia produced by this event. Sawn surfaces of this 105 kg meteorite reveal a dike of fine‐grained, clast‐poor impact melt cutting shocked host chondrite. Coarse (1–2 cm diameter) globules of FeNi metal + sulfide are concentrated along the axis of the dike from metal‐poor regions toward the margins. Refractory lithophile element abundance patterns in the melt rock are parallel to average L chondrites, demonstrating near‐total fusion of the L‐chondrite target by the impact and negligible crystal‐liquid fractionation during emplacement and cooling of the dike. Significant geochemical effects of the impact melting event include fractionation of siderophile and chalcophile elements with increasing metal‐silicate heterogeneity, and mobilization of moderately to highly volatile elements. Siderophile and chalcophile elements ratios such as Ni/Co, Cu/Ga, and Ir/Au vary systematically with decreasing metal content of the melt. Surprisingly small (?10²) effective metal/silicate‐melt distribution coefficients for highly siderophile elements probably reflect inefficient segregation of metal despite the large degrees of melting. Moderately volatile lithophile elements such K and Rb were mobilized and heterogeneously distributed in the L‐chondrite impact breccias whereas highly volatile elements such as Cs and Pb were profoundly depleted in the region of the parent body sampled by Chico. Volatile element variations in Chico and other L chondrites are more consistent with a mechanism related to impact heating rather than condensation from a solar nebula. Impact processing can significantly alter the primary distributions of siderophile and volatile elements in chondritic planetesimals.