Extension of a fluctuating plume model of tracer dispersion to a sheared boundary layer and to a large array of obstacles

Fluctuating plume models provide a useful conceptual paradigm in the understanding of plume dispersion in a turbulent flow. In particular, these models have enabled analytical predictions of higher-order concentration moments, and the form of the one-point concentration probability density function (PDF). In this paper, we extend the traditional formalism of these models, grounded in the theory of homogeneous and isotropic turbulent flow, to two cases: namely, a simple sheared boundary layer and a large array of regular obstacles. Some very high-resolution measurements of plume dispersion in a water channel, obtained using laser-induced fluorescence (LIF) line-scan techniques are utilised. These data enable us to extract time series of plume centroid position (plume meander) and dispersion in the relative frame of reference in unprecedented detail. Consequently, experimentally extracted PDFs are able to be directly compared with various theoretical forms proposed in the literature. This includes the PDF of plume centroid motion, the PDF of concentration in the relative frame, and a variety of concentration moments in the absolute and relative frames of reference. The analysis confirms the accuracy of some previously proposed functional forms of model components used in fluctuating plume models, as well as suggesting some new forms necessary to deal with the complex boundary conditions in the spatial domain.     

Seismic energy partitioning and scattering in laterally heterogeneous ocean crust

We present finite difference forward models of elastic wave propagation through laterally heterogeneous upper oceanic crust. The finite difference formulation is a 2-D solution to the elastic wave equation for heterogeneous media and implicitly calculatesP andSV propagation, compressional to shear conversion, interference effects and interface phenomena. Random velocity perturbations with Gaussian and self-similar autocorrelation functions and different correlation lengths (a) are presented which show different characteristics of secondary scattering. Heterogeneities scatter primary energy into secondary body waves and secondary Stoneley waves along the water-solid interface. The presence of a water-solid interface in the model allows for the existence of secondary Stoneley waves which account for much of the seafloor noise seen in the synthetic seismograms for the laterally heterogeneous models.Random incoherent secondary scattering generally increases aska (wavenumber,k, and correlation length,a) approaches one. Deterministic secondary scattering from larger heterogeneities is the dominant effect in the models aska increases above one. Secondary scattering also shows up as incoherence in the primary traces of the seisograms when compared to the laterally homogeneous case. Cross-correlation analysis of the initialP-diving wave arrival shows that, in general, the correlation between traces decreases aska approaches one. Also, because many different wave types exist for these marine models, the correlation between traces is range dependent, even for the laterally homogeneous case.     

Depositional and Diagenetic History and Petroleum Geology of the Jurassic Norphlet Formation of the Alabama Coastal Waters Area and Adjacent Federal Waters Area

The discovery of deep (20,000 ft) gas reservoirs in eolian sandstone of the Upper Jurassic Norphlet Formation in Mobile Bay and offshore Alabama in the late 1970s represents one of the most significant hydrocarbon discoveries in the nation during the past several decades. Estimated original proved gas from Norphlet reservoirs in the Alabama coastal waters and adjacent federal waters is 7.462 trillion ft3 (Tcf) (75% recovery factor). Fifteen fields have been established in the offshore Alabama area. Norphlet sediment was deposited in an arid environment in alluvial fans, alluvial plains, and wadis in updip areas. In downdip areas, the Norphlet was deposited in a broad desert plain, with erg development in some areas. Marine transgression, near the end of Norphlet deposition, resulted in reworking of the upper part of the Norphlet Formation. Norphlet reservoir sandstone is arkose and subarkose, consisting of a simple assemblage of three minerals, quartz, albite, and K-feldspar. The present framework grain assemblage of the Norphlet is dominantly diagenetic, owing to albitization and dissolution of feldspar. Despite the simple framework composition, the diagenetic character of the Norphlet is complex. Important authigenic minerals include carbon ate phases (calcite, dolomite, Fe-dolomite, and breunnerite), feldspar (albite and K-feldspar), evaporite minerals (anhydrite and halite), clay minerals (illite and chlorite), quartz, and pyrobitumen. The abundance and distribution of these miner als varies significantly between onshore and offshore regions of Norphlet production. The lack of sufficient internal sources of components for authigenic minerals, combined with unusual chemical compositions of chlorite (Mg-rich), breunnerite, and some minor authigenic minerals, suggests that Louann-derived fluids influenced Norphlet diagenesis. In offshore Alabama reservoirs, porosity is dominantly modified primary poros ity. Preservation of porosity in deep Norphlet reservoirs is due to a combination of factors, including a lack of sources of cement components and lack of pervasive early cement, so that fluid-flow pathways remained open during burial. Below the dominantly quartz-cemented tight zone near the top of the Norphlet, pyrobitumen is a major contributor to reduction in reservoir quality in offshore Alabama. The highest reservoir quality occurs in those wells where the present gas water contact is below the paleohydrocarbon water contact. This zone of highest reservoir quality is between the lowermost occurrence of pyrobitumen and the present gas water contact.     

Stellar clustering as induced by a supernova

When the shock wave from a supernova expands, it sweeps up not only interstellar matter but also magnetic field. The field is greatly amplified by compression and will provide the dominant pressure during the cool radiative phase of an expanding supernova shell. We examine a hydromagnetic instability in this system (a form of the Parker instability) and find that it will concentrate gas at intervals of the order of parsecs. The length and time scales make the instability promising as an explanation of the stellar clustering that is seen in Canis Major R1.     

The environment and evolution of an early egyptian urban center: Archaeological and geochemical investigations at hierakonpolis

We describe and summarize the results of new interdisciplinary techniques for recovering and analyzing historical and paleoenvironmental data from mid-Holocene archaeological and geological deposits in the modern Nile floodplain at the site of Hierakonpolis in Upper Egypt. Application of these techniques has produced the first stratigraphic link between historic (Early Dynastic) and late prehistoric (Predynastic) periods in the Nile Valley at a site which played a central role in the evolution of Egyptian civilization.     

Matrix isolation technique for the study of some factors affecting the partitioning of trace elements

Some of the factors that affect the preferred positions of cations in ionic-solid solutions were investigated utilizing vibrational spectroscopy. Solid solutions of the sulfate and chromate ions codoped with La³⁺ and Ca²⁺ in a KBr host lattice were examined as a function of the polyvalent-cation concentration. The cation—anion pairing process was found to be random for Ca²⁺ whereas the formation of La³⁺SO₄^2? ion-pairs with a C_2v bonding geometry is highly preferential to any type of La³⁺CrO₄^2? ion-pair formation. The relative populations of ion-pair site configurations are discussed in terms of an energy—entropy competition which can be applied to the partition of trace elements during magmatic processes.     

Formation of freshwater Fe-Mn coatings on gravel and the behavior of 60Co, 90Sr,and 137Cs in a small watershed

Iron and manganese oxide coatings are actively forming on stream substrates in the White Oak Creek watershed in East Tennessee. Although oxidizing conditions are required for Fe-Mn oxide precipitation, coatings accumulate only if dissolved iron and manganese exceed 50 μg/L. Below this, coatings are lost by abrasion as fast as or faster than they form. Annual rates of formation of 3 mg/g on substrate (gravel) were observed. Manganese is dissolved from coatings between Eh values of 100 to 300 mV and below 1 mg/L dissolved O₂ at pH 6.5 to 7.5. Iron oxides can be precipitated under these conditions.Uncontaminated gravels with oxide coatings (composed of illite, quartz, and feldspar) adsorbed radionuclides rapidly from waters below MPC (Maximum Permissible Concentration) levels. Contaminated gravels placed in uncontaminated waters lost ⁶⁰Co by abrasion in oxidizing conditions and by dissolution of manganese coatings in reducing conditions. Exchangeable ⁹⁰Sr was completely lost after one month whereas nonexchangeable ⁹⁰Sr was lost more slowly; ¹³⁷Cs was totally retained by the gravels. Gravels such as these can be used to monitor the radionuclide content of waters in the environment.     

Stable isotopes and cellulase activity as evidence for detritus as a food source for juvenile Gulf menhaden

Menhaden are one of the most abundant components of fish communities in Gulf and Atlantic estuaries. Juvenile menhaden have been reported to have zooplankton, phytoplankton, andSpartina-derived detritus in their guts. However, there has been disagreement over the importance of the detritus as a food source. We show, using physiological and stable isotope evidence, that detritus can be used by juvenile Gulf menhaden. Their diet is very roughly 30% detritus- and 70% plankton-based.