Analyses of organic and inorganic contaminants in Salton Sea fish

Chemical contamination of fish from the Salton Sea, a quasi-marine lake in Southern California, could adversely impact millions of birds using the Pacific Flyway and thousands of humans using the lake for recreation. Bairdiella icistia (bairdiella), Cynoscion xanthulus (orangemouth corvina), and Oreochromis spp. (tilapia) were sampled from two river mouths and two nearshore areas of the Salton Sea. Muscle tissues were analyzed for a complete suite of 14 trace metals and 53 pesticides. Fish muscle tissues had concentrations of selenium ranging between 1.89 and 2.73 microg/g wet weight. 4,4'-DDE accounted for 94% of the total DDT metabolites. Total DDTs ranged between 17.1 and 239.0 and total PCBs between 2.5 and 18.6 ng/g wet weight. PCB congeners 132, 138, 153, 168, and 180 comprised over 50% of the total PCBs. Given the potential implementation of a commercial fishing at the Salton Sea in the future, the presence of persistent organic pollutants and selenium warrants further research into the effects of these mixtures on fish populations, and on wildlife and humans consuming fish.     

Numerical simulation of the diurnal cycle of rainfall in SW Amazon basin during the 1999 rainy season: the role of convective trigger function

In continental areas, the maximum rainfall simulated with the Brazilian developments on the Regional Atmospheric Modeling System (BRAMS) occurs around 4?h earlier than the one observed with rain gauges. This work presents the successful implementation of a new convective trigger function (CTF) in the convective parameterization scheme used in BRAMS that corrects this misfit between model and observations. The importance of the CTF formulation on the diurnal cycle of rainfall over the Amazon Basin is reflected by the following numbers: Over Rondonia (SW Amazonia), the original version of BRAMS simulates the maximum rainfall at 1400 UTC (1000 LST), with the new CTF maximum shifting to 1800?UTC (1400?LST), while the S-band radar rainfall maximum is at 1900?UTC (1500?LST). This is attributed to two factors: (1) the new CTF is now coupled to the sensible and latent heat fluxes at surface; (2) during the early morning, the convective available potential energy is reduced.     

Consistent realization of Celestial and Terrestrial Reference Frames

The Celestial Reference System (CRS) is currently realized only by Very Long Baseline Interferometry (VLBI) because it is the space geodetic technique that enables observations in that frame. In contrast, the Terrestrial Reference System (TRS) is realized by means of the combination of four space geodetic techniques: Global Navigation Satellite System (GNSS), VLBI, Satellite Laser Ranging (SLR), and Doppler Orbitography and Radiopositioning Integrated by Satellite. The Earth orientation parameters (EOP) are the link between the two types of systems, CRS and TRS. The EOP series of the International Earth Rotation and Reference Systems Service were combined of specifically selected series from various analysis centers. Other EOP series were generated by a simultaneous estimation together with the TRF while the CRF was fixed. Those computation approaches entail inherent inconsistencies between TRF, EOP, and CRF, also because the input data sets are different. A combined normal equation (NEQ) system, which consists of all the parameters, i.e., TRF, EOP, and CRF, would overcome such an inconsistency. In this paper, we simultaneously estimate TRF, EOP, and CRF from an inter-technique combined NEQ using the latest GNSS, VLBI, and SLR data (2005–2015). The results show that the selection of local ties is most critical to the TRF. The combination of pole coordinates is beneficial for the CRF, whereas the combination of \(\varDelta \hbox {UT1}\) results in clear rotations of the estimated CRF. However, the standard deviations of the EOP and the CRF improve by the inter-technique combination which indicates the benefits of a common estimation of all parameters. It became evident that the common determination of TRF, EOP, and CRF systematically influences future ICRF computations at the level of several \(\upmu \)as. Moreover, the CRF is influenced by up to \(50~\upmu \)as if the station coordinates and EOP are dominated by the satellite techniques.     

Evaluation and Monitoring of Service Quality: Discussing Ways to Meet INSPIRE Requirements

Service oriented architectures (SOA) are widely used nowadays. As the name implies such architectures rely on services. Germany developed a marine‐specific service oriented data infrastructure (MDI‐DE – Marine Dateninfrastruktur Deutschland) from 2010 to 2013. The services in MDI‐DE can contribute to fulfilling reporting commitments for various European and national legislation. The services of MDI‐DE (just like other services affected, for instance, by INSPIRE) have to meet specific requirements regarding performance, availability and conformity (quality of service, QoS). Although SOA is an important field in scientific research there are very few publications and studies available on QoS, especially regarding INSPIRE requirements. The services of MDI‐DE were analyzed using various existing tools. Their usefulness to reflect where either the aspect's performance, availability or conformity needs improvement was partly verified. Due to varying results and the neglect of some services for various reasons it can be stated that the more tools are used, the more conclusive the outcome. Furthermore, service quality was not coherent when measured with different tools. This means that measuring QoS in terms of INSPIRE will be very difficult to do in the future and there is the danger that people will choose the tools with which their services perform best.     

Glacial advances constrained by Be exposure dating of bedrock landslides, Kyrgyz Tien Shan

Numerous large landslide deposits occur in the Tien Shan, a tectonically active intraplate orogen in Central Asia. Yet their significance in Quaternary landscape evolution and natural hazard assessment remains unresolved due to the lack of "absolute" age constraints. Here we present the first ¹⁰Be exposure ages for three prominent (> 10⁷ m³) bedrock landslides that blocked major rivers and formed lakes, two of which subsequently breached, in the northern Kyrgyz Tien Shan. Three ¹⁰Be ages reveal that one landslide in the Alamyedin River occurred at 11–15 ka, which is consistent with two ¹⁴C ages of gastropod shells from reworked loess capping the landslide. One large landslide in Aksu River is among the oldest documented in semi-arid continental interiors, with a ¹⁰Be age of 63–67 ka. The Ukok River landslide deposit(s) yielded variable ¹⁰Be ages, which may result from multiple landslides, and inheritance of ¹⁰Be. Two ¹⁰Be ages of 8.2 and 5.9 ka suggest that one major landslide occurred in the early to mid-Holocene, followed by at least one other event between 1.5 and 0.4 ka. Judging from the regional glacial chronology, all three landslides have occurred between major regional glacial advances. Whereas Alamyedin and Ukok can be considered as postglacial in this context, Aksu is of interglacial age. None of the landslide deposits show traces of glacial erosion, hence their locations and ¹⁰Be ages mark maximum extents and minimum ages of glacial advances, respectively. Using toe-to-headwall altitude ratios of 0.4–0.5, we reconstruct minimum equilibrium-line altitudes that exceed previous estimates by as much as 400 m along the moister northern fringe of the Tien Shan. Our data show that deposits from large landslides can provide valuable spatio-temporal constraints for glacial advances in landscapes where moraines and glacial deposits have low preservation potential.     

Geochemical and isotopic zoning patterns of plagioclase megacrysts in gabbroic dykes from the Gardar Province, South Greenland: implications for crystallisation processes in anorthositic magmas

Chemical and Sr isotopic zoning patterns in plagioclase megacrysts from gabbroic dykes in the Gardar Province can be used to elucidate magma-chamber and emplacement processes. The megacrysts occur either as single crystals or assembled as anorthosite xenoliths. The size of the megacrysts varies from <1 cm to 1 m. They consist of a large core with variable zonation (An_58-39) and a relatively small (<600 µm), normally zoned rim (An_62-27). The contact between core and rim is sharp and marked by a sharp increase in anorthite content which can reach 11 mol% An. This gap is interpreted as having formed during dyke emplacement due to a sudden pressure release. Some of the megacryst cores show a fairly constant composition whereas others exhibit an unusual wavy-oscillatory zoning which has not been reported elsewhere to our knowledge. The oscillatory zoning has wavelengths of up to 2,500 µm and a maximum amplitude of 7 mol% An. It is interpreted as reflecting movements of the crystals in the magma reservoir. The Sr isotopic composition of one crystal shows a radiogenic inner core ((⁸⁷Sr/⁸⁶Sr)_i=0.7044) and a less radiogenic outer core ((⁸⁷Sr/⁸⁶Sr)_i=0.7039-0.7036). The lack of a significant change between outer core and rim ((⁸⁷Sr/⁸⁶Sr)_i=0.7037) is consistent with formation of the more An-rich rim due to pressure release. Variations in the core may be related to movements of the crystal and/or magma mixing. A trace-element profile across a megacryst shows a small increase in Sr and small decreases in Ba and La contents of the recalculated melt composition across the core-rim boundary, whereas P, Ce, Nd and Eu remain constant. Melt compositional changes upon emplacement are therefore considered to be of minor importance. Constant ratios of incompatible trace elements in the megacryst cores indicate a dominant influence of a lower crustal source on trace-element budgets.     

Multi-AUV Control and Adaptive Sampling in Monterey Bay

Operations with multiple autonomous underwater vehicles (AUVs) have a variety of underwater applications. For example, a coordinated group of vehicles with environmental sensors can perform adaptive ocean sampling at the appropriate spatial and temporal scales. We describe a methodology for cooperative control of multiple vehicles based on virtual bodies and artificial potentials (VBAP). This methodology allows for adaptable formation control and can be used for missions such as gradient climbing and feature tracking in an uncertain environment. We discuss our implementation on a fleet of autonomous underwater gliders and present results from sea trials in Monterey Bay in August, 2003. These at-sea demonstrations were performed as part of the Autonomous Ocean Sampling Network (AOSN) II project     

Clitellate worms (Annelida) in lateglacial and Holocene sedimentary DNA records from the Polar Urals and northern Norway

While there are extensive macro‐ and microfossil records of a range of plants and animals from the Quaternary, earthworms and their close relatives amongst annelids are not preserved as fossils and therefore the knowledge of their past distributions is limited. This lack of fossils means that clitellate worms (Annelida) are currently underused in palaeoecological research, even though they can provide valuable information about terrestrial and aquatic environmental conditions. Their DNA might be preserved in sediments, which offers an alternative method for detection. Here we analyse lacustrine sediments from lakes in the Polar Urals, Arctic Russia, covering the period 24 000–1300 cal. a BP, and NE Norway, covering 10 700–3300 cal. a BP, using a universal mammal 16S rDNA marker. While mammals were recorded using the marker (reindeer was detected twice in the Polar Urals core at 23 000 and 14 000 cal. a BP, and four times in the Norwegian core at 11 000 cal. a BP and between 3600–3300 cal. a BP), worm extracellular DNA ‘bycatch’ was rather high. In this paper we present the first reported worm detection from ancient DNA. Our results demonstrate that both aquatic and terrestrial clitellates can be identified in late‐Quaternary lacustrine sediments, and the ecological information retrievable from this group warrants further research with a more targeted approach.     

Size distribution of colloidal trace metals and organic carbon during a coastal bloom in the Baltic Sea

The physico-chemical speciation of organic carbon and selected metals was measured during a coastal bloom in Ekhagen Bay, Baltic Sea, using ultrafiltration.One important objective with the study was to see if any depletion of trace metals could be measured in the directly bioavailable fraction (<1000 Da, the soluble low molecular weight fraction, LMW) during a plankton bloom. Filters with five different cut-offs were used (1 kD (1000 Da), 5 kD, 10 kD, 100 kD and 0.22 μm) in order to delineate the size distribution of colloidal organic carbon (COC) and trace metals.During the bloom in May, LMW Al, Co, Cu, Mn and Ni concentrations decreased although the colloidal and particulate concentrations were relatively high. Data show that desorption of colloidal and particulate bound trace metals to the LMW fraction was slower than the process depleting the LMW fraction.Estimates of the maximum active uptake of Cu, Ni and Mn by the phytoplankton, and the loss of non-bioactive Al from the LMW fraction, indicate that processes other than active uptake by phytoplankton must contribute to the observed depletion of trace metals in the LMW fraction. Hence, in order to estimate the bioavailable pool of trace metals for plankton during bloom conditions, these other processes must be understood and quantified.Transparent Exopolymeric Particles (TEP, reflecting sugar-rich phytoplankton exudates) increased around eight times during the plankton bloom. We hypothesize that the formation of TEP is a process that might be important for the transfer of trace metals from the LMW to the particulate fraction during the phytoplankton bloom, but the significance of TEP for this depletion in Baltic Sea surface water remains to be shown.     

Cadmium release caused by the die-back of the saltmarsh cord grass Spartina anglica in Poole Harbour (UK)

As in many other areas, the perennial cord grass Spartina anglica C.E. Hubbard has been extremely successful at colonising the English and Irish south coasts, but it is dying back for reasons that are not completely understood. The present study considers the relationship between die-back and metal concentrations in estuarine sediment. No obvious impact of the metal contamination on the S. anglica growth/die-back could be detected in the study zone, Poole Harbour, although the die-back did seem to have substantially influenced the metal concentrations in the sediments of the estuary. Based on core profiles, the remaining patches of S. anglica still retain elevated concentrations and the overall cadmium concentrations in the sediments have risen since 1925. However, considerable quantities of the cadmium stored in the sediment by S. anglica appear to have been washed out rapidly in the die-back zones. Should serious erosion of the saltmarsh occur, triggered for example by sea-level rise, then sudden and high levels of cadmium release may cause harmful effects to marine biota.