Composition of organic matter in subducted and unsubducted sediments off the Nicoya peninsula, Costa Rica (ODP Leg 170, Sites 1039 and 1040)

Investigation of sediment samples from Sites 1039 and 1040 (ODP Leg 170) drilled off the Nicoya peninsula (Costa Rica) by organic geochemical and organic petrological methods has revealed that subduction has only little influence on the composition of the sedimentary organic matter. Organic carbon contents reached 1.5% in the Pleistocene samples but Miocene and Pliocene sediments had an average organic carbon content of less than 0.5%. Organic carbon/sulfur ratios are generally below 2.8, reflecting an intense sulfate reduction in the uppermost sediments which was enhanced by sulfate supply both from sea water and deeper strata. Microscopical examinations indicate that the organic matter is mainly derived from marine sources. A small amount of terrigenous organic matter is, however, present as well according to n-alkane and fatty acid distributions. The alkenone unsaturation index U₃₇^k′ shows only a slight decrease during the Miocene and Pliocene, and stronger variations in the Pleistocene, probably indicating more stable sea surface temperatures during the Miocene and Pliocene. Variations in the Pleistocene can possibly be related to glacial/interglacial changes.     

Emission of nitrous oxide from temperate forest soils into the atmosphere

N₂O emission rates were measured during a 13-month period from July 1981 till August 1982 with a frequency of once every two weeks at six different forest sites in the vicinity of Mainz, Germany. The sites were selected on the basis of soil types typical for many of the Central European forest ecosystems. The individual N₂O emission rates showed a high degree of temporal and spatial variabilities which, however, were not significantly correlated to variabilities in soil moisture content or soil temperatures. However, the N₂O emission rates followed a general seasonal trend with relatively high values during spring and fall. These maxima coincided with relatively high soil moisture contents, but may also have been influenced by the leaf fall in autumn. In addition, there was a brief episode of relatively high N₂O emission rates immediately after thawing of the winter snow. The individual N₂O emission rates measured during the whole season ranged between 1 and 92 g N₂O-N m^–2 h^–1. The average values were in the range of 3–11 g N₂O-N m^–2 h^–1 and those with a 50% probability were in the range of 2–8 g N₂O-N m^–2 h^–1. The total source strength of temperate forest soils for atmospheric N₂O may be in the range of 0.7–1.5 Tg N yr^–1.     

Population dynamics and natural hazard risk management: conceptual and practical linkages for the case of Austrian policy making

Natural Hazards - This contribution explores the conceptual and empirical linkages between population dynamics and natural hazard risk management (NHRM). Following a review of the international...     

Geological setting of the Tverrfjell copper/zinc deposit,Central Norway

The volcanogenic exhalative Tverrfjell deposit occurs in a sequence of predominantely mafic submarine meta-volcanics, interlayered with geosynclinal pelitic sediments, turbidites and volcanic breccias, belonging to the Early Cambrian to Early Arenigian Støren Group. Two major deformational phases and low to medium grade metamorphic conditions are recognized in the study area. Basalts are mainly tholeiitic but alkaline types occur as well. Extensive fractionation produced highly evolved basalts and even andesites. Basalt compositions are comparable to Type II-ocean floor basalt. The copper/zinc ores of the Tverrfjell deposit are strictly confined to an andesitic extrusive body. An extensive magma chamber is postulated to explain magma fractionation, and as a heat source that generated the exhalative Tverrfjell ore body. It is suggested that the deposit was formed at an intraplate volcanic center or back-arc spreading center.

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Zusammenfassung Die vulkanogen-exhalativ gebildete Tverrfjell-Lagerstätte befindet sich innerhalb einer Abfolge überwiegend mafischer, submariner Metavulkamte, die mit geosynklinalen pelitischen Sedimenten, Turbiditen und vulkanischen Brekkzien wechsellagern. Diese Gesteine gehören zur Støren-Gruppe, die vom Unterkambrium bis zum frühen Arenig reicht. Zwei Hauptdeformationsphasen in Verbindung mit niedrig bis mittelgradiger Metamorphose können im Arbeitsgebiet nachgewiesen werden. Die Basalte sind zumeist tholeiitisch, jedoch treten auch alkalibasaltische Typen auf. Durch starke Fraktionierung sind hoch entwikkelte Basaltmagmen und sogar Andesite entstanden. Die Basalte können mit Typ II-Ozeanbodenbasalten verglichen werden. Die Kupfer/Zinkerze der Tverrfjell-Lagerstätte sind strikt an einen andesitischen Extrusivkörper gebunden. Eine ausgedehnte Magmenkammer wird postuliert, in welcher die Magmenfraktionierung stattfand, und die als Wärmequelle für die Bildung des Tverrfjellerzkörpers angesehen wird. Aufgrund der Untersuchungsergebnisse wird angenommen, daß die Lagerstätte in einem Intraplatten-Vulkanzentrum oder in einem Back-arc spreading centre gebildet wurde.

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Résumé Le gisement volcanogénétique exhalatif du Tverrfjell se trouve au sein d'une série de métavolcanites sous-marines, surtout basiques, qui alternent avec des pélites géosynclinales, des turbidites et des brèches volcaniques. Ces roches appartiennent au groupe de Støren qui s'étend du Cambrien inférieur jusqu'à l'éo-Arénigien. Dans cette région, deux phases déformatives majeures ont été reconnues, liées à un métamorphisme de degré faible à moyen.La plupart des basaltes sont de type tholéiitique, mais il existe aussi des basaltes alcalins. Un fractionnement poussé a engendré magmas basaltiques très évolués et même des andésites. Les compositions des basaltes sont comparables à celles du «basalte océanique de type II». La minéralisation en Cu-Zn de Tverrfjell est liée strictement à une masse extrusive andésitique. Pour expliquer le fractionnement magmatique, on admet l'existence d'une de chaleur lors de la formation du gisement de Tverrfjell. Ce gisement a dû se former soit dans un centre volcanique intraplaque, soit dans une zone d'expansion d'arrière-arc.

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Organic sedimentary deposits in Titan’s dry lakebeds: Probable evaporite

We report the discovery of organic sedimentary deposits at the bottom of dry lakebeds near Titan’s north pole in observations from the Cassini Visual and Infrared Mapping Spectrometer (VIMS). We show evidence that the deposits are evaporitic, making Titan just the third known planetary body with evaporitic processes after Earth and Mars, and is the first that uses a solvent other than water.     

Sodic Pyroxene and Sodic Amphibole as Potential Reference Materials for In Situ Lithium Isotope Determinations by SIMS

Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g^?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g^?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g^?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ⁷Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ⁷Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request.     

Numerical simulations of block-and-ash flows using the Titan2D flow model: examples from the 2006 eruption of Merapi Volcano,Java, Indonesia

We present Titan2D simulations of two well-characterized block-and-ash flow (BAF) events of the 2006 eruption of Merapi (Java, Indonesia) that affected the Gendol valley on the volcano’s southern flank and adjacent, densely populated interfluve (non-valley) areas: (1) a single dome-collapse event to the south that generated one of the smaller, post-June 14 flows and (2) a sustained, multiple dome-collapse event, also directed to the south, that produced the largest flows of the 2006 eruption emplaced in the afternoon of June 14. Using spatially varying bed friction angles, Titan2D is capable of reproducing the paths, velocities, runout distance, areas covered and deposited volumes of these flows over highly complex topography. The model results provide the basis for estimating the areas and levels of hazards associated with BAFs generated during relatively short as well as prolonged dome-collapse periods and guidance during future eruptive crises at Merapi.     

Application of the water balance model J2000 to estimate groundwater recharge in a semi-arid environment: a case study in the Zarqa River catchment, NW-Jordan

Pollution and overexploitation of scarce groundwater resources is a serious problem in the Zarqa River catchment, Jordan. To estimate this resource’s potential, the amount and spatial distribution of groundwater recharge was calculated by applying the hydrological model J2000. The simulation period is composed of daily values gathered over a 30-year period (July 1977 to June 2007). The figure finally obtained for estimated groundwater recharge of the Zarqa River catchment is 105 × 10⁶ m³ per year (21 mm a^?1). This is 19 % higher than the value previously assumed to be correct by most Jordanian authorities. The average ratio of precipitation to groundwater recharge is 9.5 %. To directly validate modelled groundwater recharge, two independent methods were applied in spring catchments: (1) alteration of stable isotope signatures (δ¹⁸O, δ²H) between precipitation and groundwater and (2) the chloride mass balance method. Recharge rates determined by isotopic investigations are 25 % higher, and recharge rates determined by chloride mass balance are 9 % higher than the modelled results for the corresponding headwater catchments. This suggests a reasonably modelled safe yield estimation of groundwater resources.     

Modelling of a medium-term dynamics in a shallow tidal sea, based on combined physical and neural network methods

The paper presents an approach towards a medium-term (decades) modelling of water levels and currents in a shallow tidal sea by means of combined hydrodynamic and neural network models. The two-dimensional version of the hydrodynamic model Delft3D, forced with realistic water level and wind fields, is used to produce a two-year-database of water levels and currents in the study area. The linear principal component analysis (PCA) of the results is performed to reveal dominating spatial patterns in the analyzed dataset and to significantly reduce the dimensionality of the data. It is shown that only a few principal components (PCs) are necessary to reconstruct the data with high accuracy (over 95% of the original variance). Feed-forward neural networks are set up and trained to effectively simulate the leading PCs based on water level and wind speed and direction time series in a single, arbitrarily chosen point in the study area. Assuming that the spatial modes resulting from the PCA are ‘universally’ applicable to the data from time periods not modelled with Delft3D, the trained neural networks can be used to very effectively and reliably simulate temporal and spatial variability of water levels and currents in the study area. The approach is shown to be able to accurately reproduce statistical distribution of water levels and currents in various locations inside the study area and thus can be viewed as a reliable complementary tool e.g., for computationally expensive hydrodynamic modelling. Finally, a detailed analysis of the leading PCs is performed to estimate the role of tidal forcing and wind (including its seasonal and annual variability) in shaping the water level and current climate in the study area.     

Nitrogen recycling in subducted oceanic lithosphere: The record in high- and ultrahigh-pressure metabasaltic rocks

This paper provides the first measurements of the nitrogen (N) concentrations and isotopic compositions of high- and ultrahigh-pressure mafic eclogites, aimed at characterizing the subduction input flux of N in deeply subducting altered oceanic crust (AOC). The samples that were studied are from the Raspas Complex (Ecuador), Lago di Cignana (Italy), the Zambezi Belt (Zambia) and Cabo Ortegal (Spain), together representing subduction to 50-90 km depths. The eclogites contain 2-20 ppm N with δ¹⁵N_air values ranging from −1 to +8‰. These values overlap those of altered oceanic crust, but are distinct from values for fresh MORB (for the latter, ∼1.1 ppm N and δ¹⁵N_air ∼ −4‰). Based on N data in combination with other trace element data, the eclogite suites can be subdivided into those that are indistinguishable from their likely protolith, AOC, with or without superimposed effects of devolatilization (Lago di Cignana, Cabo Ortegal), and those that have experienced metasomatic additions during subduction-zone metamorphism (Zambezi Belt, Raspas). For the former group, the lack of a detectable loss of N in the eclogites, compared to various altered MORB compositions, suggests the retention of N in deeply subducted oceanic crust. The metasomatic effects affecting the latter group can be best explained by mixing with a (meta)sedimentary component, resulting in correlated enrichments of N and other trace elements (in particular, Ba and Pb) thought to be mobilized during HP/UHP metamorphism. Serpentinized and high-pressure metamorphosed peridotites, associated with the eclogites at Raspas and Cabo Ortegal, contain 3-15 ppm N with δ¹⁵N_air values ranging from +3 to +6‰, significantly higher than the generally accepted values for the MORB mantle (δ¹⁵N_air ∼ −5‰). Based on their relatively high N contents and their homogeneous and positive δ¹⁵N values, admixing of sedimentary N is also indicated for the serpentinized peridotites.One possible pathway for the addition of sediment-derived N into eclogites and peridotites involves mixing with fluids along the slab-mantle wedge interface. Alternatively, sedimentary N could be incorporated into peridotites during serpentinization at bending-related faults at the outer rise and, during later deserpentinization, released into fluids that then infiltrate overlying rocks. Deep retention of N in subducting oceanic crust should be considered in any attempt to balance subduction inputs with outputs in the form of arc volcanic gases. If materials such as these eclogites and serpentinized peridotites are eventually subducted to beyond sub-arc depths into the deeper mantle, containing some fraction of their forearc-subarc N inventory (documented here), they could deliver isotopically heavy N into the mantle to potentially be sampled by plume-related magmas.