Micromechanical approach to effective viscoelastic properties of micro‐fractured geomaterials

The aim of this paper is to formulate a micromechanics‐based approach to non‐aging viscoelastic behavior of materials with randomly distributed micro‐fractures. Unlike cracks, fractures are discontinuities that are able to transfer stresses and can therefore be regarded from a mechanical viewpoint as interfaces endowed with a specific behavior under normal and shear loading. Making use of the elastic‐viscoelastic correspondence principle together with a Mori‐Tanka homogenization scheme, the effective viscoelastic behavior is assessed from properties of the material constituents and damage parameters related to density and size of fractures. It is notably shown that the homogenized behavior thus formulated can be described in most cases by means of a generalized Maxwell rheological model. For practical implementation in structural analyses, an approximate model for the isotropic homogenized fractured medium is formulated within the class of Burger models. Although the approximation is basically developed for short‐term and long‐term behaviors, numerical applications indicate that the approximate Burger model accurately reproduce the homogenized viscoelastic behavior also in the transient conditions.     

Hydrodynamic and geochemical conditions of the formation of stratiform Zn-Pb ore mineralization by chloride solutions

Ore mineralization is formed by postsedimentary (concentrated by evaporation to stage SW2) chloride brines metamorphosed in hydrogeochemical systems that are closed with respect to CO₂, evolve according to “calcic” trend, and have high 2mCa²⁺ > mHCO ₃ ^? + 2mCO ₃ ^2? ratios. In these situations at high R/W ratios (10–100) and temperatures (100–200°C), these brines concentrate ore elements (Zn, Pb, Fe, and Mn) that are geochemical analogues of Ca. The sulfide precipitation of these elements occurs under the effect of carbonate rocks at the abiogenic sulfate reduction of S(VI) of the original brines at low Eh values, which are created in carbonate rocks at higher (>100°C) temperatures. This origin of sulfide mineralization is intensified at decreasing R/W ratios during the dilution of the original brines by elision waters and an increase in the temperature. The hydrodynamics of these ore-forming brines is controlled by the elision hydrogeological regime, which is defined in hydrogeological structures by the geostatic pressure. The brines migrate into the zones of geochemical barriers during the relaxation of hydrogeological structures toward their equilibrium hydrostatic state. Hydrogeological structures, optimal for the precipitation of ore mineralization, are hydrodynamically active and able to maintain a steady (during 10⁵-10⁶ years) inflow of ore-forming brines into the zones of geochemical barriers and the maximum number of water-exchange cycles at these barriers. Modern analogues of these structures are miogeosyncline foredeeps with Cl-Na-Ca chloride brines with high concentrations of ore elements and overall flow rates ranging from 0.n to n m³/year. Stagnate hydrogeological platform structures in hydrostatic equilibrium cannot ensure water exchange needed for ore formation, and, hence, the brines of these structures are not able to deposit the ore elements contained in them, in spite of the high concentrations of these elements.     

Directionality of surface high-frequency geoacoustic emission during deformational disturbances

Changes in the directionality of surface high-frequency geoacoustic emission during periods of deformational disturbances on the diurnal time scale prior to strong seismic events on Kamchatka have been investigated. It has been shown that while the emission intensity grows by over an order of magnitude, sharp maxima appear in the direction of longitudinal acoustic oscillations. Based on their position, the orientation of the major compression axis can be determined, whose chaotic motion exhibits two metastable states around the direction to the epicenter of the earthquake.     

The Zn abundance and isotopic composition of diatom frustules,a proxy for Zn availability in ocean surface seawater

We have developed cleaning methods for extracting diatomopal from bulk marine sediment samples, for measurement of both zinc (Zn) abundance and isotope composition. This cleaning technique was then applied to a set of Holocene core-top samples from the Southern Ocean. The measured δ⁶⁶Zn (reported relative to the JMC_Lyon standard) and Zn/Si ratios from the Southern Ocean diatom_opal samples range from 0.7 to 1.5‰, and from 14 to 0.9 μmol/mol, respectively. The Zn abundance and isotope composition data show a clear correlation with opal burial rates and other oceanographic parameters. In common with previous work, we interpret the systematic changes in the Zn/Si ratio to be linked to the variability in the concentrations of bioavailable Zn in the ambient surface seawater where the diatom opal is formed. This variability is likely to be primarily controlled by the degree to which Zn is taken up into phytoplankton biomass. The observed systematic pattern in the δ⁶⁶Zn compositions of the diatom_opal core-top samples is, similarly, likely to reflect changes in the δ⁶⁶Zn composition of the ambient Zn in the surface waters above the core-top sites, which is progressively driven towards isotopically heavier values by preferential incorporation of the lighter isotopes into phytoplankton organic material. Thus, the systematic relationship between Zn isotopes and abundance observed in the core-top diatom_opal samples suggests a potential tool for investigating the biogeochemical cycling of Zn in the past surface ocean for down-core diatom_opal material. In this respect, it may be possible to test hypotheses that attribute variations in atmospheric CO₂ on glacial–interglacial timescales to the degree to which trace metals limited primary productivity in HNLC zones.     

Regional and temporal changes in bivalve diversity off the south coast of Portugal

From 2000 to 2006, a total of 75 bivalve species were identified, varying from 29 (spring 2001) to 54 species (spring 2005) per year. Seasonal tendencies in diversity varied according the year, thus the interpretation of long-term and regional scales is essential before drawing any conclusions in other studies. Richness and diversity consistently decreased with depth and increased with sediment grain size (from low in very coarse sand to high in coarse silt). Diversity decreased progressively from 3 to 16 m depth, thus the harsher shallower environments (due to waves and tidal air exposure) showed greater diversity than the most stable areas. Communities in finer sediments were more diverse than those in coarser sand. Evenness showed patterns opposite to diversity, overall.Diversity and evenness maps (produced with multivariate universal kriging), showed that most geographic areas with greater diversity were farer from river outflows and wastewater treatment plants. Two types of geographic pattern were observed: areas with persistently greater bivalve diversity through time and areas that changed locally from year to year. This spatial analysis can be used to establish priority conservation areas for management purposes, and to analyse the persistency of regional diversity patterns. The area with most habitat heterogeneity (Sotavento) corresponded to greatest diversity.There was a positive relationship between Spisula solida and Chamelea gallina landings and bivalve diversity 2 years and 1 year later, respectively. Possibly, local fisheries, by selectively withdrawing the commercial numerically dominant species from the ecosystem, increased diversity 1 to 2 years later, as the ecological niches of the dominants are quickly filled by several other species thereby creating a more even community. On regional scales, no significant impact was found on long-term bivalve diversity in local fisheries,     

Meteor Showers Associated with the Taurid Complex Asteroids

Recent theoretical and observational work has shown that the asteroids belonging to the Taurid meteoroid complex have a cometary nature. If so, then they might possess related meteoroid streams producing meteor showers in the Earth atmosphere. We studied the orbital evolution of ten numbered Taurid complex asteroids by the Halphen-Goryachev method. It turned out that all of these asteroids are quadruple crossers relative to the Earth's orbit. Therefore their proposed meteoroid streams may in theory each produce four meteor showers. The theoretical orbital elements and geocentric radiants of these showers are determined and compared with the available observational data. The existence of the predicted forty meteor showers of the ten Taurid complex asteroids is confirmed by a search of the published catalogues of observed meteor shower radiants and orbits, and of the archives of the IAU Meteor Data Center (Lund). The existence of meteor showers associated with the Taurid Complex Asteroids confirms that, most likely, these asteroids are extinct comets. This revised version was published online in July 2006 with corrections to the Cover Date.     

Thermal and isotopic profiling of the Pipeline hydrothermal system: Application to exploration for Carlin-type gold deposits

New exploration techniques are vital to the search for new orebodies in mature terranes, as well as for extensions of existing orebodies. This research focused on application of low-temperature dating techniques (primarily apatite fission-tracks) and stable isotope measurements (carbon and oxygen in carbonate rocks) in and around the Pipeline deposit, a Carlin-type gold system. The primary purpose of the project was to assess whether these techniques could provide exploration vectors that might be used in conjunction with other geologic, geochemical, and geophysical techniques to determine the locus of fossil hydrothermal fluid flow, and the attendant possibility of finding economic mineral deposits.At Pipeline, measurements of apatite fission-tracks and (U − Th) / He geochronometry yield a clear indication of the elevated temperatures associated with the fossil hydrothermal system. The pattern is one of a central target (Pipeline deposit) with decreasing thermal effects as far as several kilometers laterally from the known ore zone. Because of the irregular nature of fluid flow through fractures, a significant number of samples are required to discern this pattern, but the pattern is quite clear from the 32 samples in and around the Pipeline pit.Stable isotope measurements of carbonate rocks yield patterns centered on the Pipeline pit area. Oxygen isotopes in particular are shifted toward lower values as the result of interaction between the hydrothermal fluids and carbonate rocks. Carbon isotopes show a pattern, but it is somewhat more difficult to interpret than the oxygen isotope pattern. As with the geochronometric patterns, isotopic indications of fluid flow are present several kilometers from the ore zone at Pipeline. Also as with the geochronometric data, a relatively large sample set is required to see the pattern. At Pipeline, the patterns are evident in approximately 45 surface samples and very clearly in the cross-sections containing approximately 100 samples.From these data, it is clear that thermal and stable isotopic measurements on rocks at a significant distance from the known Pipeline hydrothermal system record the passage of hot fluids through the rock. Both techniques provide a footprint of the Pipeline system that is several diameters larger than the ore zone (as presently known). Therefore, thermochronologic and stable isotopic measurements can be utilized in conjunction with other techniques as part of an overall exploration strategy for Carlin-type deposits. Although these techniques do not provide a direct indication of the metal content of the fossil hydrothermal fluids, they do provide an indication of the robustness of fluid flow and the potential size of a hydrothermal system.     

Considered parameters in a least squares adjustment process

Least squares adjustment processes occasionally utilize constants with a known degree of uncertainty. If the covariance matrix of the adjusted parameters is estimated without considering those uncertainties the resulting estimate is invariably too optimistic. A method is proposed by which without altering the values of the adjusted parameters their a posteriori (after the adjustment) covariance matrix can be improved by the inclusion of the effect of uncertainties in the constants.     

Late Pleistocene and early Holocene rivers and wetlands in the Bonneville basin of western North America

Field investigations at Dugway Proving Ground in western Utah have produced new data on the chronology and human occupation of late Pleistocene and early Holocene lakes, rivers, and wetlands in the Lake Bonneville basin. We have classified paleo-river channels of these ages as “gravel channels” and “sand channels.” Gravel channels are straight to curved, digitate, and have abrupt bulbous ends. They are composed of fine gravel and coarse sand, and are topographically inverted (i.e., they stand higher than the surrounding mudflats). Sand channels are younger and sand filled, with well-developed meander-scroll morphology that is truncated by deflated mudflat surfaces. Gravel channels were formed by a river that originated as overflow from the Sevier basin along the Old River Bed during the late regressive phases of Lake Bonneville (after 12,500 and prior to 11,000 ¹⁴C yr B.P.). Dated samples from sand channels and associated fluvial overbank and wetland deposits range in age from 11,000 to 8800 ¹⁴C yr B.P., and are probably related to continued Sevier-basin overflow and to groundwater discharge. Paleoarchaic foragers occupied numerous sites on gravel-channel landforms and adjacent to sand channels in the extensive early Holocene wetland habitats. Reworking of tools and limited toolstone diversity is consistent with theoretical models suggesting Paleoarchaic foragers in the Old River Bed delta were less mobile than elsewhere in the Great Basin.     

Microseismicity and tectonics of Sinai

Five microearthquake seismographs were used at 11 sites in northern Sinai in the period February 1987 to February 1988 to study the microseismicity of the area around the Maghara coal mine for mine-development studies. A total of 270 events were recorded on 850 records. The magnitude, epicenter and depth of each event were calculated using suitable software for an Egyptian Geological Survey and Mining Authority's (EGSMA) XT computer. The interpretation of the seismic activity in the area is given in view of plate tectonics, the Sinai subplate boundary follows the Gulf of Aqaba and the Dead Sea. The plate and subplate boundaries are presently active, and there seems to be a diffuse zone of deformation between “NW Africa” and “Nubia” affecting the Cairo-Suez district.