Temperature Control on Soluble Reactive Phosphorus in the Lower Mississippi River?

Soluble reactive phosphorus (SRP) has recently been shown to be one of the limiting nutrients for the growth of phytoplankton in the northern Gulf of Mexico. We show here that during the past decade, SRP concentrations in the lower reaches of North America's largest river, the Mississippi River, were highest in summer and lowest in winter and positively correlated with water temperature. Upstream data showed this coupling to increase in a downstream trend in the Mississippi main stem. Water quality data analysis and phosphorus mass balances were conducted to examine the controls of this relationship. The results showed that the positive SRP–temperature correlation in the Mississippi River system was largely a result of gradual dilution of SRP-enriched upper Mississippi River waters, which contributed most to the Mississippi River during summer, by SRP-depleted waters from the Ohio and other tributaries. Particle buffering and organic matter mineralization might play a role in the observed SRP–temperature relationship, but their importance relative to tributary effects is not quantified. Future work on the seasonal dynamics of SRP in large river systems needs to consider the effects of both tributary dilution and in situ processes.     

Pink manganian phengite in a high P/T meta-conglomerate from northern Syros (Cyclades, Greece)

A new occurrence of Mn-rich rocks was discovered within the high-pressure/low-temperature metamorphic rocks on the Palos peninsula of Syros (Greece). Near the summit of Mount Príonas, a meta-conglomerate consists of calcite (~63 wt%), pink manganian phengite, blue–purple manganian aegirine–jadeite, microcline, albite and quartz. In addition, it contains abundant braunite-rich aggregates (up to ~1.5 cm in diameter) that include hollandite [(Ba_0.98–1.02K_<0.01Na_<0.02Ca_<0.03) (Mn _1.02–1.52 ³⁺ Fe _0.38–0.88 ³⁺ Ti_0.29–0.92Mn _5.11–5.76 ⁴⁺ )O₁₆], barite and manganian hematite. Due to metamorphic recrystallization and deformation, the contacts between clasts and matrix are blurred and most clasts have lost their identity. In back-scattered electron images, many aegirine–jadeite grains appear patchy and show variable jadeite contents (Jd_10–67). These pyroxenes occur in contact with either quartz or albite. Manganian phengite (3.41–3.49 Si per 11 oxygen anions) is of the 3T type and contains 1.4–2.2 wt% of Mn₂O₃. At the known P–T conditions of high-pressure metamorphism on Syros (~1.4 GPa/ 470 °C), the mineral sub-assemblage braunite + quartz + calcite (former aragonite) suggests high oxygen fugacities relative to the HM buffer (+7 ≤ ?f_O2 ≤ + 17) and relatively high CO₂ fugacities. The exact origin of the conglomerate is not known, but it is assumed that the Fe–Mn-rich and the calcite-rich particles originated from different sources. Braunite has rather low contents of Cu (~0.19 wt%) and the concentrations of Co, Ni and Zn are less than 0.09 wt%. Hollandite shows even lower concentrations of these elements. Furthermore, the bulk-rock compositions of two samples are characterized by low contents of Cu, Co and Ni, suggesting a hydrothermal origin of the manganese ore. Most likely, these Fe–Mn–Si oxyhydroxide deposits consisted of ferrihydrite, todorokite, birnessite, amorphous silica (opal-A) and nontronite. Al/(Al + Fe + Mn) ratios of 0.355 and 0.600 suggest the presence of an aluminosilicate detrital component.     

Integration of a limit-equilibrium model into a landslide early warning system

Landslides are a significant hazard in many parts of the world and exhibit a high, and often underestimated, damage potential. Deploying landslide early warning systems is one risk management strategy that, amongst others, can be used to protect local communities. In geotechnical applications, slope stability models play an important role in predicting slope behaviour as a result of external influences; however, they are only rarely incorporated into landslide early warning systems. In this study, the physically based slope stability model CHASM (Combined Hydrology and Stability Model) was initially applied to a reactivated landslide in the Swabian Alb to assess stability conditions and was subsequently integrated into a prototype of a semi-automated landslide early warning system. The results of the CHASM application demonstrate that for several potential shear surfaces the Factor of Safety is relatively low, and subsequent rainfall events could cause instability. To integrate and automate CHASM within an early warning system, international geospatial standards were employed to ensure the interoperability of system components and the transferability of the implemented system as a whole. The CHASM algorithm is automatically run as a web processing service, utilising fixed, predetermined input data, and variable input data including hydrological monitoring data and quantitative rainfall forecasts. Once pre-defined modelling or monitoring thresholds are exceeded, a web notification service distributes SMS and email messages to relevant experts, who then determine whether to issue an early warning to local and regional stakeholders, as well as providing appropriate action advice. This study successfully demonstrated the potential of this new approach to landslide early warning. To move from demonstration to active issuance of early warnings demands the future acquisition of high-quality data on mechanical properties and distributed pore water pressure regimes.     

Implementing the Kyoto Protocol without the USA: the strategic role of energy tax adjustments at the border

Abstract

This article explores options for countries that have ratified the 1997 Kyoto Protocol to the UN Framework Convention on Climate Change and that intend to implement ambitious climate protection strategies—the ‘Kyoto coalition’—to deal with possible comparative disadvantages vis-à-vis third parties, in particular industrialized countries that do not adhere to the Kyoto Protocol. Specifically, the article focuses on the instrument of border adjustments for energy taxes. We outline the rationale for such adjustments and examine in detail whether certain border adjustments for energy taxes would be permissible under world trade law, in particular the General Agreement on Tariffs and Trade and the Agreement on Subsidies and Countervailing Measures. We conclude that despite remaining ambiguity in both the legal provisions and the pertinent case law, border tax adjustments are under certain circumstances compatible with world trade law. Yet, given persisting legal uncertainty, it seems likely that affected members of the World Trade Organization would challenge such energy tax adjustments at the border before the WTO dispute settlement mechanism.     

Hydraulic fracturing in unconventional gas reservoirs: risks in the geological system, part 2

Hydraulic fracturing is a method used for the production of unconventional gas resources. Huge amounts of so-called fracturing fluid (10,000–20,000 m³) are injected into a gas reservoir to create fractures in solid rock formations, upon which mobilised methane fills the pore space and the fracturing fluid is withdrawn. Hydraulic fracturing may pose a threat to groundwater resources if fracturing fluid or brine can migrate through fault zones into shallow aquifers. Diffuse methane emissions from the gas reservoir may not only contaminate shallow groundwater aquifers, but also escape into the atmosphere where methane acts as a greenhouse gas. The working group “Risks in the Geological System” as part of ExxonMobil’s hydrofracking dialogue and information dissemination processes was tasked with the assessment of possible hazards posed by migrating fluids as a result of hydraulic fracturing activities. In this work, several flow paths for fracturing fluid, brine and methane are identified and scenarios are set up to qualitatively estimate under what circumstances these fluids would leak into shallower layers. The parametrisation for potential hydraulic fracturing sites in North Rhine-Westphalia and Lower Saxony (both in Germany) is derived from literature using upper and lower bounds of hydraulic parameters. The results show that a significant fluid migration is only possible if a combination of several conservative assumptions is met by a scenario.     

The lithosphere–asthenosphere boundary in the eastern part of the Dead Sea Basin (DSB) from S-to-P receiver functions

Clear S-to-P converted waves from the crust–mantle boundary (Moho) and lithosphere–asthenosphere boundary (LAB) have been observed on the eastern part of the Dead Sea Basin (DSB), and are used for the determination of the depth of the Moho and the LAB. A temporary network consisting of 18 seismic broad-band stations was operated in the DSB region as part of the DEad Sea Integrated REsearch project for 1.5 years beginning in September 2006. The obtained Moho depth (～35 km) from S-to-P receiver functions agrees well with the results from P-to-S receiver functions and other geophysical data. The thickness of the lithosphere on the eastern part of the DSB is about 75 km. The results obtained here support and confirm previous studies, based on xenolith data, geodynamic modeling, heat flow observations, and S-to-P receiver functions. Therefore, the lithosphere on the eastern part of the DSB and along Wadi Araba has been thinned in the Late Cenozoic, following rifting and spreading of the Red Sea. The thinning of the lithosphere occurred without a concomitant change in the crustal thickness and thus an upwelling of the asthenosphere in the study area is invoked as the cause of the lithosphere thinning.     

Cosmic‐ray exposure age and preatmospheric size of the Bunburra Rockhole achondrite

Abstract– Bunburra Rockhole is the first meteorite fall photographed and recovered by the Desert Fireball Network in Australia. It is classified as an ungrouped achondrite similar in mineralogical and chemical composition to eucrites, but it has a distinct oxygen isotope composition. The question is if achondrites like Bunburra Rockhole originate from the same parent body as the howardite‐eucrite‐diogenite (HED) meteorites or from several separate, differentiated parent bodies. To address this question, we measured cosmogenic radionuclides and noble gases in the Bunburra Rockhole achondrite. The short‐lived radionuclides ²²Na and ⁵⁴Mn confirm that Bunburra Rockhole is a recent fall. The concentrations of ¹⁰Be, ²⁶Al and ³⁶Cl as well as the ²²Ne/²¹Ne ratio indicate that Bunburra Rockhole was a relatively small object (R approximately 15 cm) in space, consistent with the photographic fireball observations. The cosmogenic ³⁸Ar concentration yields a cosmic‐ray exposure (CRE) age of 22 ± 3 Myr, whereas ²¹Ne and ³He yield approximately 30% and approximately 60% lower ages, respectively, due to loss of cosmogenic He and Ne, mainly from plagioclase. With a CRE age of 22 Myr, Bunburra Rockhole is the first anomalous eucrite that overlaps with the main CRE peak of the HED meteorites. The radiogenic K‐Ar age of 4.1 Gyr is consistent with the U‐Pb age, while the young U,Th‐He age of approximately 1.4 Gyr indicates that Bunburra Rockhole lost radiogenic ⁴He more recently.