Recent trends of urban development and town planning in Spain

With the socio-economic change from rural to industrial, Spain has experienced an enormous urbanisation boom during the last 20 years. This has produced a concentration of high-rise apartment blocks not only in the big cities but also in medium-sized towns and even within the medieval town centres. More astonishing, compared with Central Europe, seems however, the spatial distribution of the social classes which, with a centre-periphery gradient, still corresponds to the model of the pre-industrial town. The paper investigates the impact of town planning, house building policy, and behavioural aspects on these structural patterns.     

Are C1 chondrites chemically fractionated? a trace element study

Six C1 chondrite samples and a C2 xenolith from the Plainview H5 chondrite were analyzed by radiochemical neutron activation for the elements Ag, Au, Bi, Br, Cd, Ce, Cs, Eu, Ge, In, Ir, Lu, Nd, Ni, Os, Pd, Pt, Rb, Re, Sb, Se, Sn, Tb, Te, Tl, Yb, and Zn. The data were combined with 9 earlier analyses from this laboratory and examined for evidence of chemical fractionation in C1 chondrites.A number of elements (Br, Rb, Cs, Au, Re, Os, Ni, Pd, Sb, Bi, In, Te) show small but correlated variations. Those of the first 8 probably reflect hydrothermal alteration in the meteorite parent body, whereas those of Sb, Bi, In, and Te may at least in part involve nebular processes. Br and Au show systematic abundance differences from meteorite to meteorite, which suggests hydrothermal transport on a kilometer scale. The remaining elements vary from sample to sample, suggesting transport on a centimeter scale.There is no conclusive evidence for nebular fractionation affecting C1 's. Though C1 chondrites have lower $\text{Zr}\text{Hf}$ and $\text{Ir}\text{Re}$ ratios than do other chondrite classes, these ratios vary in other classes, suggesting that those classes rather than C1's are fractionated. Three fractionation-prone REE—Ce, Eu, and Yb have essentially the same relative abundances in C1's and all other chondrite classes, and hence apparently are not fractionated in C1's. We did not confirm the large Tb and Yb variations in C1's reported by other workers.We present revised mean C1 abundances for 35 elements, based on the new data and a critical selection of literature data. Changes are generally less than 10%, except for Br, Rb, Ag, Sb, Te, Au, and the REE.The Plainview C2 xenolith has normal trace element abundances, except for 3 elements falling appreciably above the C2 range: Rb, Cs, and Bi. Hydrothermal alteration may be the reason for all 3, though nebular fractionation remains a possibility for Bi.     

Buchbesprechungen

Ohne Zusammenfassung     

On the existence of a relation between the Kolmogoroff and von Kármán constants

A model is described, in which the mean vertical wind profile and turbulence spectra at different heights are calculated for a turbulent boundary layer without thermal stratification. The model makes use of Heisenberg's formula for the transfer of turbulent energy and is based on the assumption of a constant shearing stress in that boundary layer. As a result, a logarithmic wind profile follows with 0.39 as the value of von Kármán's constant, which is — in this model — strongly related to the inertial subrange of the turbulent energy spectra and therefore to the Kolmogoroff constant.This paper is based on studies done by the author during a one-year visit to CSIRO Division of Meteorological Physics, Aspendale, Australia, and was presented at the AGARD Specialists Meeting on The Aerodynamics of Atmospheric Shear Flows sponsored by the Fluid Dynamics Panel at Munich, Germany, during 15–17 Sept. 1969.     

Petrogenetic relationships of acid and basic rocks in iceland: Sr-isotopes and rare-earth elements in late and postglacial volcanics

Strontium isotope ratios and rare-earth element abundances have been measured in acid, intermediate and basic rocks from three late to postglacial volcanic complexes, and several other postglacial basalts in Iceland. Late and postglacial basalts in Iceland have been generated from a source region which is essentially homogeneous with respect to⁸⁷Sr/⁸⁶Sr. The mean⁸⁷Sr/⁸⁶Sr ratio for the basalts analysed is 0.70328 and the range is from 0.70317 ± 6to0.70334 ± 5 (2σ).Acid rocks from the Kerlinganfjöll and Namafjall volcanic complexes have⁸⁷Sr/⁸⁶Sr ratios which are indistinguishable from analysed basalts from the same complexes. However, intermediate and acid rocks from the Torfajökull complex have significantly higher⁸⁷Sr/⁸⁶Sr ratios and could not have been derived by fractional crystallization from basaltic magmas similar to those found in the same complex. These latter rocks have most probably been produced by remelting of Tertiary gabbroic rocks in Layer 3. Most of the basalts analysed have higher total rare-earth element abundances than typical dredged ocean-ridge tholeiites, and show less light rare-earth depletion. Intermediate and acid compositions show overall higher abundances and light rare-earth enrichments. The measured rare-earth abundances are compared with abundances generated by differential partial melting of various model source regions.It is shown that both the tholeiitic and alkali basalt compositions could be generated from the same source material by different degrees of partial melting. Variable partial melting of gabbroic material may account for the rare-earth element abundances of both the rhyolitic rocks (small degrees of melting) and the intermediate rocks (more extensive melting).     

Thermal modeling of Carboniferous to Triassic sediments of the Karawanken Range (Southern Alps) as a tool for paleogeographic reconstructions in the Alpine–Dinaridic–Pannonian realm

Vitrinite reflectance was measured in Late Carboniferous to Triassic shales, siltstones and marls of the Karawanken Range. Thermal models of the central South-Karawanken Range were calibrated on the basis of these data. They suggest an eroded overburden of more than 3,200 m of Jurassic to Cretaceous sediments and a heat flow in the range of 42 to 60 mW m^?2 during the time of maximum subsidence. Because the reconstructed thermal history of the South-Karawanken Range is very similar to the thermal history of the Generoso basin (western Southern Alps), these data provide strong evidence for a deep basinal position of the Southern Karawanken Range during Jurassic to Cretaceous times. A vitrinite reflectance anomaly at the northern margin of the South-Karawanken Range is explained by advective heat transport during the Oligocene. The heat source for the anomalies at the western margin of the Seeberg Rise and in the area between the Periadriatic Lineament and the Donat Fault Zone is unknown. Vitrinite reflectance in Late Triassic sediments indicates the South-Karawanken Range and the South-Zala Unit of the Pannonian basement as exotic blocks in the Sava Composite Unit. This is explained by Miocene displacement of structural units, which were derived from different paleogeographical segments of the Permo-Mesozoic western Tethyan margin.     

Long-Term Evolution of Objects in the Kuiper Belt Zone—Effects of Insolation and Radiogenic Heating

The Kuiper Belt zone is unique insofar as the major heat sources of objects a few tens of kilometers in size—solar radiation on the one hand and radioactive decay on the other—have comparable power. This leads to unique evolutionary patterns, with heat waves propagating inward from the irradiated surface and outward from the radioactively heated interior. A major radioactive source that is considered in this study is ²⁶Al. The long-term evolution of several models with characteristics typical of Kuiper Belt objects is followed by means of a 1-D numerical code that solves the heat and mass balance equations on a spherically symmetric grid. The free parameters considered are radius (10-500 km), heliocentric distance (30-120 AU), and initial ²⁶Al content (0-5×10⁻⁸ by mass). The initial composition assumed is a porous mixture of ices (H₂O, CO, and CO₂) and dust. Gases released in the interior are allowed to escape to the surface. It is shown that, depending on parameters, the interior may reach quite high temperatures (up to 180 K). The models suggest that Kuiper Belt objects are likely to lose the ices of very volatile species during early evolution; ices of less volatile species are retained in a surface layer, about 1 km thick. The models indicate that the amorphous ice crystallizes in the interior, and hence some objects may also lose part of the volatiles trapped in amorphous ice. Generally, the outer layers are far less affected than the inner part, resulting in a stratified composition and altered porosity distribution. These changes in structure and composition should have significant consequences for the short-period comets, which are believed to be descendants of Kuiper Belt objects.     

Sublimation pressure and sublimation enthalpy of H2O ice Ih between 0 and 273.16 K

The sublimation of water in the region of extremely low pressures and temperatures meets increasing interest for the exploration of icy cosmic bodies. At temperatures below 130 K, the shape of the sublimation curve of H₂O is not known; neither experimental data nor theoretical treatments exist for this region. Based upon theoretical upper and lower bounds for the heat capacity of water vapor in this range, a narrow region in the pressure-temperature diagram is identified which must necessarily enclose the sublimation curve down to virtually any lower pressures and temperatures. Within this region, an approximate sublimation curve is computed from the 2006 Gibbs potential of ice Ih, using available heat capacity data points of water vapor between 10 and 130 K. The theoretical zero-point limiting law of the sublimation pressure is derived. Valid between 20 and 273.16 K, correlation equations for the sublimation enthalpy and the sublimation pressure are fitted to the computed data. All quantities are expressed in the 1990 temperature scale ITS-90. Under cosmic conditions, our results suggest that the sublimation of ice is unlikely below 50 K and impossible below 23 K.     

Long-term effects of anthropogenic CO<Subscript>2</Subscript> emissions simulated with a complex earth system model

A new complex earth system model consisting of an atmospheric general circulation model, an ocean general circulation model, a three-dimensional ice sheet model, a marine biogeochemistry model, and a dynamic vegetation model was used to study the long-term response to anthropogenic carbon emissions. The prescribed emissions follow estimates of past emissions for the period 1751–2000 and standard IPCC emission scenarios up to the year 2100. After 2100, an exponential decrease of the emissions was assumed. For each of the scenarios, a small ensemble of simulations was carried out. The North Atlantic overturning collapsed in the high emission scenario (A2) simulations. In the low emission scenario (B1), only a temporary weakening of the deep water formation in the North Atlantic is predicted. The moderate emission scenario (A1B) brings the system close to its bifurcation point, with three out of five runs leading to a collapsed North Atlantic overturning circulation. The atmospheric moisture transport predominantly contributes to the collapse of the deep water formation. In the simulations with collapsed deep water formation in the North Atlantic a substantial cooling over parts of the North Atlantic is simulated. Anthropogenic climate change substantially reduces the ability of land and ocean to sequester anthropogenic carbon. The simulated effect of a collapse of the deep water formation in the North Atlantic on the atmospheric CO₂ concentration turned out to be relatively small. The volume of the Greenland ice sheet is reduced, but its contribution to global mean sea level is almost counterbalanced by the growth of the Antarctic ice sheet due to enhanced snowfall. The modifications of the high latitude freshwater input due to the simulated changes in mass balance of the ice sheet are one order of magnitude smaller than the changes due to atmospheric moisture transport. After the year 3000, the global mean surface temperature is predicted to be almost constant due to the compensating effects of decreasing atmospheric CO₂ concentrations due to oceanic uptake and delayed response to increasing atmospheric CO₂ concentrations before.