39Ar-40Ar ages of samples from the Apollo 17 station 7 boulder and implications for its formation

³⁹Ar-⁴⁰Ar ages and³⁷Ar-³⁸Ar exposure ages of samples representing four different lithologies of the Apollo 17 station 7 boulder were measured. The age of the dark veinlet material77015of3.98 ± 0.04AE is interpreted as representing the time of intrusion of this veinlet into the 77215 clast. The data obtained so far indicate that the vesicular basalt 77135 formed 100–200 m.y. later. However, this has to be confirmed by³⁹Ar-⁴⁰Ar investigations on separated mineral and/or grain-size fractions. A small clast enclosed in the 77135 basalt gives a well-defined high temperature age of3.99 ± 0.02AE. A sample of the noritic clast 77215 gave4.04 ± 0.03AE, the highest age found so far in this boulder. The³⁹Ar-⁴⁰Ar ages obtained are in agreement with the age relationships deduced from the stratigraphic evidence.Taking into account the shielding by the boulder itself, an average³⁷Ar-³⁸Ar exposure age of(27.5 ± 2.5)m.y. is obtained for the samples collected from the boulder.     

Characterization of sediments in an abandoned mining area; a case study of Mansfeld region,Germany

The distribution of selected heavy metals, including some radionuclides, metalloids and non-metals was determined in stream sediments in a region influenced by abandoned copper mining and ore processing activities. A considerable amount of the ore processing waste with a very complex composition and highly elevated concentrations of zinc, sulfur, lead, copper, arsenic, and a lot of other elements in the range between 100 and 1,000 mg/kg (Sb, Mn, Ni, Cr, Cd, Hg, and Ag) was piled up on mine dumps. The dispersion of the pollutants originating from this source and their environmental impact were investigated. Both, sediments and original waste material were studied to indicate the pathways and the mobilization behavior of different pollutants. For this purpose, the process of the elution of pollutants by application of different fractionation schemes was studied. The capabilities of different analytical techniques are shown for the analysis of solid samples (X-ray fluorescence spectrometry, Gamma-spectrometry) and liquid ones (ICP-atomic emission spectrometry, ICP-mass spectrometry and different techniques of atomic absorption). Additionally, the coupling of ion chromatography and ICP-MS detection was used to study the distribution of arsenic species in the sediment cores of a lake which acts as a natural sink for the region.     

A RAM-economizing domain decomposition technique for regional high-resolution groundwater simulation

A major limitation of the use of high-resolution groundwater models on a regional scale for resource management by water companies is the excessive RAM requirements of such models which surpass the capacity of today's PCs. A strategy is presented to overcome this problem by using overlapping domain decomposition techniques. Furthermore, because very long computing time is the bottleneck for the practical use of this technique for large groundwater models, an analysis is also presented of a number of methods implemented to increase calculation performance. The approach presented here is characterized by a fairly simple structure that represents a generalized relaxation algorithm. It can be adapted for use with finite element as well as with finite difference methods. Electronic Publication     

Dislocation structure of the crust-mantle boundary and low-velocity body within the crust beneath the Dabie Shan collision orogen

The Dabie Shan is located on the eastern side of the Qinling-Dabie orogenic belt, which marks a geological boundary between the Sino-Korean and Yangtze cra- ton. Since the 1980s, the discovery of coesite and mi- crodiamond in the Dabie Shan orogen motivates an extensive interest to the ultra-high pressure (UHP)metamorphism and its exhumation[1,2]. Many results about them were published, which deal with different disciplines, including tectonics, petrology and chro- nology[3?8]. Up to now,…     

The meta-igneous granulite xenoliths from Kerguelen Archipelago: evidence of a continent nucleation in an oceanic setting

Xenoliths of meta-igneous origin occur as one of the two main types of ultramafic and mafic xenoliths entrained by alkaline lavas of the Kerguelen islands. These are designated type II xenoliths and are subdivided into three mineralogical groups. Subtype IIa and IIc xenoliths are interpreted as crystallisation products of basaltic melts that were emplaced near the crust-mantle boundary during the early tholeiitic–transitional magmatic activity of the Kerguelen islands. Younger magmatism became more alkaline and subtype IIb xenoliths were formed as high-pressure alkaline cumulates related to the last alkaline volcanic stage. Subsequently, the plagioclase-bearing type II rocks have been re-equilibrated under granulite facies conditions. This addition of mafic material around the crust-mantle boundary is consistent with seismic evidence for crustal thickening to 14–20 km. Calculated compressional seismic velocities (Vp) for the basic granulites are consistent with the range of observed Vp in the low-velocity region underlying the oceanic crust. Such growth in the thickness of the oceanic crust may be caused by intrusion of basalts at different levels in the lithosphere and may provide the heat responsible for granulitic metamorphism in the oceanic setting. This study suggests that basic granulites can account for the observed seismic characteristics of oceanic plateaux and can be important components of Kerguelen oceanic lithosphere where there has been large-scale magma production. Moreover we speculate that the Kerguelen islands and perhaps the surrounding plateau represent a continental nucleation process. Received: 30 September 1997 / Accepted: 17 June 1998     

Cleavage mechanism and surface chemical characterization of phengitic Muscovite and Muscovite as constrained by X-Ray Photoelectron Spectroscopy

Freshly cleaved (001) natural muscovite was chemically characterized by X-ray Photoelectron Spectroscopy (XPS). The investigated muscovite crystals have composition ranging from pure end member to phengitic muscovite. XPS provides experimental evidence that the chemical composition of the near-surface region differs from the bulk. This difference is not due to analytical problems, but to extreme surface sensitivity of XPS. Depth profiling was also carried out after tilting of 60° or 70° of the sample along an axis perpendicular to [001]. After tilting of phengitic muscovite, the concentration of Al increases and of K decreases, and therefore Al is the topmost monolayer. Repulsion between the octahedral and tetrahedral sheets, stacking faults or more probably interlayered phases (gibbsite-like) are responsible for the cleavage. Possible perturbations of surface chemistry due to X-ray radiation and Ar⁺ ion sputtering have also been investigated. X-ray radiation is negligeable, but Ar⁺ ion sputtering introduces important structural modifications, perturbation of the chemical environment of elements and minor chemical variations. Received: 13 November 1996 / Revised, accepted: 21 March 1997     

Numerical modelling of airborne electromagnetic anomalies originating from low-conductivity 3D bodies1

Responses of a multifrequency, multicoil airborne electromagnetic (AEM) system were modelled numerically for 3D electrical conductors embedded in a resistive bedrock and overlain by an overburden of low to moderate conductivity. The results cover a horizontal coplanar coil configuration and two frequencies, 7837 Hz and 51 250 Hz. The models studied are single or multiple, poor conductors (conductance lower than 0.1 S) embedded in a host rock of high but finite resistivity (5000 Ωm) and overlain by a layer of overburden with finite thickness and low to moderate conductivity (conductance up to 2 S). On the basis of the modelling results, limits of detectability for poor conductors have been studied for the various model structures. The results indicate that the anomaly from a steeply dipping, plate-like conductor will decrease significantly when the conductor is embedded in a weakly conductive host rock and is overlain by a conductive overburden. However, an anomaly is obtained, and its magnitude can even increase with increasing overburden conductivity or frequency. The plate anomaly remains practically constant when only the overburden thickness is varied. Changes in overburden conductivity will cause the plate-anomaly values to change markedly. If the plate conductance is less than that of the overburden, a local anomaly opposite in sign to the normal type of anomaly will be recorded. Another major consequence is that conductors interpreted with free-space models will be heavily overestimated in depth or underestimated in conductance, if in reality induction and current channelling in the host rock and overburden make even a slight contribution to the anomalous EM field. The lateral resolution for the horizontal coplanar coil system was found to be about 1.7 times the sensor altitude. Similarly, the lateral extension of a horizontal conductive ribbon, required to reach the semi-infinite (half-space) behaviour, is more than three times the sensor altitude. Finally, screening of a steeply dipping plate, caused by a small, conductive horizontal ribbon, is much more severe than screening of the same plate by an extensive horizontal layer.     

Seismic hazard assessment for low-seismicity areas — Case study: Northern Germany

The problem of assessing seismic hazard in low-seismicity areas becomes obvious in many practical applications. A typical low-seismicity area, which experienced damaging earthquakes in historical times, is the North German Plain, for which a case study is presented. It is shown how seismic hazard assessments are influenced by different interpretations of historical key earthquakes, changes in b-value as well as variations of the upper bound magnitude assumed for the seismic source regions. The latter strongly influences the hazard results in the case of very low b-values for long return periods.     

Periphyton communities in Amazonian black- and whitewater habitats: Community structure, biomass and productivity

Chlorophyll a-concentrations, AFWD (ash-free-dry-weight) and photosynthesis rates were estimated for periphyton assemblages in Amazonian black-and white-water habitats over 14 months. Cellulose-acetate strips were incubated in situ and showed few major differences in periphyton quality as compared to natural substrata. The only exceptions were submersed Igapó forest leaves, which exhibited higher proportions of green algae and cyanobacteria though not producing differences in total periphyton biomass. Enclosure experiments showed a considerable nutrient release by inundated non-senescent Igapó forest leaves. Periphyton biomass and productivity were found to be highest in black-and white water mixing zones, where biomass peaked at 41.6 mg Chla/m² and 19.8 g/m² AFDW. Production was estimated to be 380 gC/m²·a. Maximum biomass of periphyton in floating meadows was 46 mg Chla/m² and 10.6 g/m² AFDW, with an annual production of 170 gC/m²·a. Solimões main channel periphyton values were low: maximum Chla was 7.1 mg/m², AFDW 0.8 g/m² and annual production was estimated to be 30 gC/m². Blackwater periphyton values were lower compared to whitewater and mixed water values but an enlarged trophogenic zone has to be taken into account. Highest Chla content reached 30.9 mg/m², AFDW 1.43 g/m². Estimated annual production was 110 gC/m². Observed mean periphyton productivity of Amazonian blackwater habitats approximately corresponded to mesotrophic attached algae productivity in temperate zones, whereas productivity of whitewater periphyton approached those of temperate eutrophic lakes. The role of periphyton in the Amazon food web is discussed.