Noble gas composition of the solar wind as collected by the Genesis mission

We present the elemental and isotopic composition of noble gases in the bulk solar wind collected by the NASA Genesis sample return mission. He, Ne, and Ar were analyzed in diamond-like carbon on a silicon substrate (DOS) and ^84,86Kr and ^129,132Xe in silicon targets by UV laser ablation noble gas mass spectrometry. Solar wind noble gases are quantitatively retained in DOS and with exception of He also in Si as shown by a stepwise heating experiment on a flown DOS target and analyses on other bulk solar wind collector materials. Solar wind data presented here are absolutely calibrated and the error of the standard gas composition is included in stated uncertainties. The isotopic composition of the light noble gases in the bulk solar wind is as follows: ³He/⁴He: (4.64 ± 0.09) × 10⁻⁴, ²⁰Ne/²²Ne: 13.78 ± 0.03, ²¹Ne/²²Ne: 0.0329 ± 0.0001, ³⁶Ar/³⁸Ar 5.47 ± 0.01. The elemental composition is: ⁴He/²⁰Ne: 656 ± 5, and ²⁰Ne/³⁶Ar 42.1 ± 0.3. Genesis provided the first Kr and Xe data on the contemporary bulk solar wind. The preliminary isotope and elemental composition is: ⁸⁶Kr/⁸⁴Kr: 0.302 ± 0.003, ¹²⁹Xe/¹³²Xe: 1.05 ± 0.02, ³⁶Ar/⁸⁴Kr 2390 ± 150, and ⁸⁴Kr/¹³²Xe 9.5 ± 1.0. The ³He/⁴He and the ⁴He/²⁰Ne ratios in the Genesis DOS target are the highest solar wind values measured in exposed natural and artificial targets. The isotopic composition of the other noble gases and the Kr/Xe ratio obtained in this work agree with data from lunar samples containing “young” (∼100 Ma) solar wind, indicating that solar wind composition has not changed within at least the last 100 Ma. Genesis could provide in many cases more precise data on solar wind composition than any previous experiment. Because of the controlled exposure conditions, Genesis data are also less prone to unrecognized systematic errors than, e.g., lunar sample analyses. The solar wind is the most authentic sample of the solar composition of noble gases, however, the derivation of solar noble gas abundances and isotopic composition using solar wind data requires a better understanding of fractionation processes acting upon solar wind formation.     

Garnet reaction rims from the breakdown of Staurolite in polymetamorphic micashists from the Rappold complex, Austroalpine basement, Eastern Alps

In polymetamorphic pelites of the Rappold complex in the Wölz crystalline basement (Eastern Alps) reaction rim garnets at staurolite-quartz interfaces (type I) and single grain garnets along previous staurolite-white mica interfaces (type II) were formed. The garnet reaction rims were formed during the Cretaceous amphibolite facies metamorphic overprint of the pre-existing mineral assemblages comprising garnet, staurolite, and kyanite from an amphibolite facies metamorphic event probably of Variscian age. The newly formed garnet may take the form of reaction rims along the margins of large pre-existing staurolite blasts. The initial growth increments of garnet have low grossular content, and reaction rim growth was controlled by the transfer of Fe, Mg and Mn components from the staurolite-garnet interface to the quartz-garnet interface. Later garnet growth increments have relatively high grossular content due to consumption of matrix plagioclase, which was destabilized by successive pressure increase. The grossular content of newly formed garnet shows systematic increase towards sites where plagioclase breaks down indicating that transport of calcium through the matrix was sluggish. On the basis of reaction microstructures it is demonstrated that the mineral assemblage garnet?+?kyanite?+?biotite?+?paragonite was formed at the conditions of eo-alpine amphibolite facies overprint while staurolite and plagioclase broke down successively with increasing pressure.     

Enhanced red fluorescence emission in the oxygen minimum zone of the Arabian Sea

 Depth profiles of fluorescence at several excitation and emission wavelengths were measured along with CTD data during the cruise So119 of RV Sonne in the Arabian Sea from 12 May to 10 June 1997. In addition to chlorophyll fluorescence from phytoplankton in the near-surface layer, the profiles in the oxygen minimum region well below the euphotic zone show enhanced red fluorescence. Red fluorescence intensity is inversely related to the oxygen concentration in intermediate and deep waters. A relationship to characteristic water masses of the region cannot be found in the data, and this holds also with chemical data such as DOC. Absorbance spectra of water samples taken in the oxygen minimum zone show an absorption band at 420 nm wavelength with about 50 nm bandwidth, much weaker than gelbstoff absorbance in the same wavelength range. The absorption band remains stable after sample filtration with 0.45 μm glass fibre filters. Hence, the size of the absorbing matter is in the range of dissolved molecules or particles much smaller than 1 μm. Fluorescence spectra of unfiltered samples with 420 nm excitation show a weak emission band at 600 nm and a more pronounced one at 660 nm wavelength. The trailing edge of the 660 nm band falls into the range of chlorophyll emission, thus giving rise to the observed depth profiles of red fluorescence in the oxygen minimum zone. Red fluorescence measured on samples remain stable during a few hours after sampling even in the presence of oxygen. It is not detectable after several weeks of sample storage in the dark and cannot be reproduced even after depletion of dissolved oxygen. Received: 22 May 2002 / Accepted: 18 February 2003 Responsible Editor: Andreas Oschlies Acknowledgements. This work was supported by a grant from the Federal Minister of Education and Technology, Bonn, within the frame work of the JGOFS Arabian Sea program. We are grateful to the captain and the crew of RV Sonne for their support. We are indebted to Mrs. Kirsten Neumann from the Institute of Marine Chemistry and Biogeochemistry of the University of Hamburg for providing the oxygen data, and to Mr. Nikolai Delling from the same institute for making the DOC and chlorophyll data available to us.     

Climatology of Ozone, PAN, CO, and NMHC in the Free Troposphere Over the Southern North Atlantic

Free tropospheric measurements of ozone, peroxyacetylnitrate andprecursors (CO, NMHC) that were made within the framework of the EUROTRACsub-project TOR (Tropospheric Ozone Research) between 1990 and 1995 at theGAW station Izana, Tenerife (28°18N, 16°30W) arediscussed. The average annual cycles reveal the importance of transport fromnorthern mid-latitudes and the role of photo-chemistry. According toair-mass trajectories, which were supplied to us from AEROCE(Atmosphere/Ocean Chemistry Experiment), transport from northernmid-latitudes is associated with high precursor concentrations in winter,whereas ozone concentrations in winter are not much influenced by transportpatterns, suggesting a rather uniform distribution over the northern part ofthe Northern Hemisphere around mean value of 43 ± 5 ppb. In summer,high ozone concentrations of up to 90 ppb are often encountered duringtransport from north, while the levels of precursors are much lower than inwinter, because of photochemical destruction. Trajectories from southerlylatitudes and the Sahara usually have the lowest ozone concentrationsassociated with them.     

Modes of climate variability as simulated by a coupled general circulation model. Part I: ENSO-like climate variability and its low-frequency modulation

The El Niño-Southern Oscillation (ENSO) is investigated in a multicentury integration conducted with the coupled general circulation model (CGCM) ECHAM3/LSG. The quasiperiodic interannual oscillations of the simulated equatorial Pacific climate system are due to subsurface temperature anomaly propagation and a positive atmosphere-ocean feedback. The gravest internal wave modes contribute to the generation of these anomalies. The simulated ENSO has a characteristic period of 5–8 years. Due to the coarse resolution of the ocean model the ENSO amplitude is underestimated by a factor of three as compared to observations. The model ENSO is associated with the typical atmospheric teleconnection patterns. Using wavelet statistics two characteristic interdecadal modulations of the ENSO variance are identified. The origins of a 22 and 35?y ENSO modulation as well as the characteristic ENSO response to greenhouse warming simulated by our model are discussed.     

Chemical analysis of mineral dust grains by SIMS: Application to a cometary mission

Analysis of a dust sample (e.g. collected during a cometary rendezvous mission) by SIMS (Secondary Ion Mass Spectroscopy) can provide information on elemental abundances (? 100 amu), the molecular composition of grain surfaces, and isotopic ratios of selected elements. This can be accomplished with dust covering as little as 10^?4 of the collector surface area. In order to demonstrate these capabilities a special experimental set-up for substrate preparation, dust collection and SIMS analysis of dust under ultrahigh vacuum conditions was developed. The comparison of elemental abundance ratios for different olivines and pyroxenes measured with the special SIMS equipment with that measured by an electron microprobe indicated an accuracy for SIMS of the elemental abundance measurements of ? 30%. By varying the energy threshold of secondary ions to be mass-analysed from 0 to 50 eV it is possible to identify molecular ions in the spectra and to estimate their abundance with respect to elemental ions on the same mass line. The ratios of molecular to elemental ions vary by a factor of 1–25. The concept for a future cometary rendezvous experiment as well as first results of chemical investigation on mineral dust samples obtained are reported.     

Preliminary Analysis of V and Hp Light Curves of 26 Carbon Miras

Light variations of a representative sample of 26 more or less periodically variable carbon stars were analyzed on the basis of 2220 individual observations made by the Hipparcos satellite and 33 544 visual observations listed in AFOEV and VSOLJ databases within the interval JD = 2 448 000 (1988) ±6 cycles. We found the osculating linear ephemerides of all stars and their mean light curves, as well. We found that the light curves of the carbon Miras in our set can be satisfactorily expressed as a linear combination of only two basic light curves. The analysis was done by an own method combining robust regression and principal component analysis.     

An inflationary cosmological model in Dunn's scalar-tensor theory of gravitation

The gravitational field equations in Dunn's scalar-tensor theory of gravitation are generalized by including a cosmological constant. The resulting equations are solved for a Robertson-Walker line-element with flat three-space. The solution represents a cosmological model that develops into an inflationary era.     

Description and ESR dating of the Holsteinian interglaciation

The classical region of the Holsteinian interglacial is in the vicinity of Hamburg and the Lower Elbe. It is defined on the basis of pollen and is clearly distinguishable from the Eemian interglacial (Hallik, 1960; Müller, 1974). The Holsteinian interglacial is represented by a sequence of sediments up to 100 m in thickness. These consist of limnic, fluvial, and marine beds and show a transgression up to the height of present sea-level.Twenty-seven molluscs from Holsteinian deposits were used for ESR dating. The ages show that the Holsteinian may be correlated with stage 7 of the deep sea record V28-238 (Shackleton and Opdyke, 1973).