Chromium Removal through Biosorption and Bioaccumulation by Bacteria from Tannery Effluents Contaminated Soil

Four bacterial isolates (two resistant and two sensitive to chromium) were isolated from soil contaminated with tannery effluents at Jajmau (Kanpur), India, and were identified by 16S rDNA gene sequencing as Stenotrophomonas maltophilia, Exiguobacterium sp., Pantoea sp., and Aeromonas sp. Biosorption of chromium by dried and living biomasses was determined in the resistant and sensitive isolates. The effect of pH, initial metal concentration, and contact time on biosorption was studied. At pH 2.5 the living biomass of chromium resistant isolate Exiguobacterium sp. ZM‐2 biosorbed maximum amount of Cr⁶⁺ (29.8 mg/g) whereas the dried biomass of this isolate biosorbed 20.1 mg/g at an initial concentration of 100 mg/L. In case of chromate sensitive isolates, much difference was not observed in biosorption capacities between their dried and living biomasses. The maximum biosorption of Cr³⁺ was observed at pH 4.5. However, biosorption was identical in resistant and sensitive isolates. The data on chromium biosorption were analyzed using Langmuir and Freundlich isotherm model. The biosorption data of Cr⁶⁺ and Cr³⁺ from aqueous solution were better fitted in Langmuir isotherm model compared to Freundlich isotherm model. Metal recovery through desorption was observed better with dried biomasses compared to the living biomasses for both types of chromium ions. Bioaccumulation of chromate was found higher in chromate resistant isolates compared to the chromate sensitive isolates. Transmission electron microscopy confirmed the accumulation of chromium in cytoplasm in the resistant isolates.     

Use of Chemotaxonomy To Study the Influence of Benzalkonium Chloride on Bacterial Populations in Biodegradation Testing

Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days).     

New urban map of Eurasia using MODIS and multi-source geospatial data

Urban areas are of paramount significance to both the individuals and communities at local and regional scales. However, the rapid growth of urban areas exerts effects on climate, biodiversity, hydrology, and natural ecosystems worldwide. Therefore, regular and up-to-date information related to urban extent is necessary to monitor the impacts of urban areas at local, regional, and potentially global scales. This study presents a new urban map of Eurasia at 500 m resolution using multi-source geospatial data, including Moderate Resolution Imaging Spectroradiometer (MODIS) data of 2013, population density of 2012, the Defense Meteorological Satellite Program’s Operational Linescan System (DMSP-OLS) nighttime lights of 2012, and constructed Impervious Surface Area (ISA) data of 2010. The Eurasian urban map was created using the threshold method for these data, combined with references of fine resolution Landsat and Google Earth imagery. The resultant map was compared with nine global urban maps and was validated using random sampling method. Results of the accuracy assessment showed high overall accuracy of the new urban map of 94%. This urban map is one product of the 20 land cover classes of the next version of Global Land Cover by National Mapping Organizations.     

Long-range precipitation forecasts using paleoclimate reconstructions in the western United States

Long-range precipitation forecasts are useful when managing water supplies.Oceanicatmospheric oscillations have been shown to influence precipitation.Due to a longer cycle of some of the oscillations,a short instrumental record is a limitation in using them for long-range precipitation forecasts.The influence of oscillations over precipitation is observable within paleoclimate reconstructions;however,there have been no attempts to utilize these reconstructions in precipitation forecasting.A data-driven model,KStar,is used for obtaining long-range precipitation forecasts by extending the period of record through the use of reconstructions of oscillations.KStar is a nearest neighbor algorithm with an entropy-based distance function.Oceanic-atmospheric oscillation reconstructions include the El Nino-Southern Oscillation(ENSO),the Pacific Decadal Oscillation(PDO),the North Atlantic Oscillation(NAO),and the Atlantic Multi-decadal Oscillation(AMO).Precipitation is forecasted for 20 climate divisions in the western United States.A 10-year moving average is applied to aid in the identification of oscillation phases.A lead time approach is used to simulate a one-year forecast,with a 10-fold cross-validation technique to test the models.Reconstructions are used from 1658-1899,while the observed record is used from 1900-2007.The model is evaluated using mean absolute error(MAE),root mean squared error(RMSE),RMSE-observations standard deviation ratio(RSR),Pearson’s correlation coefficient(R),NashSutcliffe coefficient of efficiency(NSE),and linear error in probability space(LEPS) skill score(SK).The role of individual and coupled oscillations is evaluated by dropping oscillations in the model.The results indicate ’good’ precipitation estimates using the KStar model.This modeling technique is expected to be useful for long-term water resources planning and management.     

Fluxes of Sr into the headwaters of the Ganges

Himalayan weathering is recognized as an important agent in modifying sea water chemistry, but there are significant uncertainties in our understanding of Himalayan riverine fluxes. This paper examines causes of the variability, including that of the seasons, by analysis of downstream variations in Sr, ⁸⁷Sr, and major ions in the mainstream, in relation to the composition of tributary streams from subcatchments with differing geologic substrates.Water samples were collected over four periods spanning the premonsoon, monsoon, and postmonsoon seasons. Uncertainties in the relative fluxes have been estimated, using Monte Carlo techniques, from the short-term variability of mainstream chemistry and the scatter of tributary compositions. The results show marked seasonal variations in the relative inputs related to high monsoon rainfall in the High and Lesser Himalaya, contrasting with the major contribution from glacial melt waters from the Tibetan Sedimentary Series (TSS) at times of low rainfall. Much of the spread in previously published estimates of the sources of Sr in Himalayan rivers may result from these seasonal variations in Sr fluxes.The annual fluxes of Sr into the headwaters of the Ganges are derived from the three main tectonic units in the proportions 35 ± 1% from the TSS, 27 ± 3% from the High Himalayan Crystalline Series (HHCS), and 38 ± 8% from the Lesser Himalaya. The particularly elevated ⁸⁷Sr/⁸⁶Sr ratios characteristic of the HHCS and the Lesser Himalaya enhance their influence on seawater Sr-isotope composition. The TSS contributes 13 ± 1%, the HHCS 30 ± 3%, and the Lesser Himalaya 57 ± 11% of the ⁸⁷Sr flux in excess of the seawater ⁸⁷Sr/⁸⁶Sr ratio of 0.709.     

Markov CA,Multi Regression,and Multiple Decision Making for Modeling Historical Changes in Kirkuk City,Iraq

The cellular automata (CA) model is an important tool in land use change studies. Swift increases in population and long-term expectations of rapid urbanization have led to extensive land use change, and normal living conditions have affected the natural resources of the land. This paper highlights and analyzes the historical urban changes in Kirkuk City, Iraq, considering repeated changes undergone by the state such change as government infrastructures, wars, and economic blockade. In this paper, an integrated model, built-in multi regression model, and multi-criteria evaluation were considered to improve the representation of CA transition rules. Environmental and socioeconomic factors were used to produce Suitable Maps (SMs). These SMs were practicalities to create factor layers and weight usage, rating method process for variance expert decision-making groups, and geographic information systems for the periods 1984, 1990, 2000, and 2010. The roots of the equation (R²) values are compared and these values are chosen to produce a good model of suitable maps. The approach used in this study provides a mechanism for monitoring suitability maps in Kirkuk. Furthermore, the model Markov CA is implemented and evaluated. The results indicate that the model, its related concepts performs sufficiency     

Statistical landslide susceptibility assessment of the Mansehra and Torghar districts,Khyber Pakhtunkhwa Province,Pakistan

This paper presents laboratory experiments and numerical simulations of effects of submerged obstacles on tsunami-like solitary wave and its run-up. This study was carried out for the breaking and non-breaking solitary waves on 1:19.85 uniform slope which contains a submerged obstacle. New laboratory experiments are performed to describe the mitigation of tsunami amplitude and run-up under the effect of submerged obstacles. We are based on experimental results obtained to validate the numerical model. The numerical modeling using COULWAVE aims essentially to show the effect of the obstacle on the shape of solitary wave and the limit of this effect. Using a multiple nonlinear regression, we have determined a model to estimate height of run-up according to the amplitude of the wave and the obstacle peak depth.     

Late Ordovician glacial and glacio-fluvial paleovalley architecture and sedimentation in southeast Jordan and northwest Saudi Arabia

Four recently discovered glacio-fluvial paleovalleys in southeast Jordan and northwest Saudi Arabia are described for the first time. The paleovalleys formed as a result of glacial erosion by series of sub-parallel valley glaciers during the Late Ordovician (Hirnantian) southern hemisphere glaciation on the Arabian Plate. The southwest-northeast orientation of the paleovalleys, Proterozoic erratic clasts and paleocurrent vectors indicate the advance of glaciers and subsequent glacio-fluvial siliciclastics emanating from a paleo-ice sheet located to the south on the Arabian Shield. U-shaped, paleovalley cross-sectional morphologies and gently inclined longitudinal profiles indicate initial glacial erosion of the ‘finger-like’ paleovalleys, probably as wet-based valley glaciers, eroded up to 250 m depth into Late Ordovician marine bedrock formations. Paleovalley-fill sequences comprise a tripartite upwards succession: (a) basal sandstone-dominated tillite with well-rounded, grooved and striated granitoid and metamorphic basement clasts derived from the Proterozoic Arabian Shield together with locally derived, rounded and elongate boulders eroded from the local bedrock at the margins of the paleovalleys (Retrogradational Lowstand Sequence); (b) green chloritic siltstone (Zarqa Formation) deposited during a progradational sea-level rise with marine influence (Transgressive Sequence); (c) coarse-grained, trough cross-bedded sandstone (Sarah Formation) attributed to progradational fluvial sedimentation as glacial outwash. Rapid sea-level rise during latest Hirnantian to Early Llandovery time resulted in marine flooding of the glacio-fluvial alluvial plain and deposition of organic-rich mudstones representing transgressive and high-stand sequences.     

Numerical Prediction of Induced Pressure and Lift of the Planing Surfaces

This paper discusses the numerical prediction of the induced pressure and lift of the planing surfaces in a steady motion based on the potential flow solver as well as the spray drag by use of the practical method.The numerical method for computation of the induced pressure and lift is potential-based boundary element method.Special technique is identified to present upwash geometry and to determine the spray drag.Numerical results of a planing flat plate and planing craft model 4666 are presented.It is shown that the method is robust and efficient and the results agree well with the experimental measurements with various Froude humors.     

Field test to compare 3D imaging capabilities of three arrays in a site with high resistivity contrast regions

The applicability of three kinds of electrode configurations used to delineate a buried horizontal pipe was studied. A 3D resistivity imaging survey was carried out along eight parallel lines using pole-pole, pole-dipole, and dipole-dipole arrays with 1m minimum electrode spacings. Roll-along measurements were carried out to cover a rectangular grid. The 2D and 3D least squares algorithms based on the robust inversion method were used in the inversion of the apparent resistivity data sets. The 2D inversion of data sets could not delineate the orientation and dimension of the subsurface anomalies clearly. To obtain more accurate results, a 3D joint inversion of the pole-pole and pole-dipole data sets was performed, as well as of pole-pole and dipole-dipole data sets. In this case, both horizontal and vertical dimensions of subsurface structures were resolved. The resulting model obtained from each array was compared to those of joint inversion method. The result showed that the horizontal resolution does not improve so much as that in the vertical direction when joint inversion is applied.