Trace element compositions of submicroscopic inclusions in coated diamond: A tool for understanding diamond petrogenesis

Trace element compositions of submicroscopic inclusions in both the core and the coat of five coated diamonds from the Democratic Republic of Congo (DRC, formerly Zaire) have been analyzed by Laser Ablation Inductively Coupled Mass Plasma Spectrometry (LA-ICP-MS). Both the diamond core and coat inclusions show a general 2-4-fold enrichment in incompatible elements relative to major elements. This level of enrichment is unlikely to be explained by the entrapment of silicate mantle minerals (olivine, garnet, clinopyroxene, phlogopite) alone and thus submicroscopic fluid or glass inclusions are inferred in both the diamond coat and in the gem quality diamond core. The diamond core fluids have elevated High Field Strength Element (Ti, Ta, Zr, Nb) concentrations and are enriched in U relative to inclusions in the diamond coats and relative to chondrite. The core fluids are also moderately enriched in LILE (Ba, Sr, K). Therefore, we suggest that the diamond cores contain inclusions of silicate melt. However, the Ni content and Ni/Fe ratio of the trapped fluid are very high for a silicate melt in equilibrium with mantle minerals; high Ni and Co concentrations in the diamond cores are attributed to the presence of a sulfide phase coexisting with silicate melt in the diamond core inclusions. Inclusions in the diamond coat are enriched in LILE (U, Ba, Sr, K) and La over the diamond core fluids and to chondrite. The coats have incompatible element ratios similar to natural carbonatite (coat fluid: Na/Ba ≈0.66, La/Ta≈130). The coat fluid is also moderately enriched in HFSE (Ta, Nb, Zr) when normalized to chondritic Al. LILE and La enrichment is related to the presence of a carbonatitic fluid in the diamond coat inclusions, which is mixed with a HFSE-rich hydrous silicate fluid similar to that in the core. The composition of the coat fluid is consistent with a genetic link to group 1 kimberlite.     

Early development of strike-slip faulting: palaeoseismic study along the Petersen Mountain fault,northern Walker Lane,Nevada

Characterising youthful strike-slip fault systems within transtensional regimes is often complicated by the presence of tectonic geomorphic features produced by normal faulting associated with oblique extension. The Petersen Mountain fault in the northern Walker Lane tectonic province exhibits evidence of both normal and strike-slip faulting. We present the results of geologic and geomorphic mapping, and palaeoseismic trenching that characterise the fault's style and sense of deformation. The fault consists of two major traces. The western trace displaces colluvial, landslide, and middle to late Pleistocene alluvial fans and is associated with aligned range front saddles, linear drainages, and oversteepened range front slopes. The eastern trace is associated with a low linear bedrock ridge, a narrow graben, right deflected stream channels, and scarps in late Pleistocene alluvial fan deposits. A trench on the eastern trace of the fault exposed a clear juxtaposition of disintegrated granodiorite bedrock against sand and boulder alluvial fan deposits across a steeply east-dipping fault. The stratigraphic evidence supports the occurrence of at least one late Pleistocene earthquake with a component of lateral displacement. As such, the Petersen Mountain fault accommodates part of the ~7 mm/yr of dextral shear distributed across the northern Walker Lane.     

On the dependence of the saturated hydraulic conductivity upon the effective porosity through a power law model at different scales

We study the scale dependence of the saturated hydraulic conductivity K_s through the effective porosity n_e by means of a newly developed power‐law model (PLM) which allows to use simultaneously measurements at different scales. The model is expressed as product between a single PLM (capturing the impact of the dominating scale) and a characteristic function κ^? accounting for the correction because of the other scale(s). The simple (closed form) expression of the κ^?‐function enables one to easily identify the scales which are relevant for K_s. The proposed model is then applied to a set of real data taken at the experimental site of Montalto Uffugo (Italy), and we show that in this case two (i.e. laboratory and field) scales appear to be the main ones. The implications toward an important application (solute transport) in Hydrology are finally discussed. Copyright © 2016 John Wiley & Sons, Ltd.     

Simulation of site-scale water fluxes in desert and natural oasis ecosystems of the arid region in Northwest China

The study of water fluxes is important to better understand hydrological cycles in arid regions. Data-driven machine learning models have been recently applied to water flux simulation. Previous studies have built site-scale simulation models of water fluxes for individual sites separately, requiring a large amount of data from each site and significant computation time. For arid areas, there is no consensus as to the optimal model and variable selection method to simulate water fluxes. Using data from seven flux observation sites in the arid region of Northwest China, this study compared the performance of random forest (RF), support vector machine (SVM), back propagation neural network (BPNN), and multiple linear regression (MLR) models in simulating water fluxes. Additionally, the study investigated inter-annual and seasonal variation in water fluxes and the dominant drivers of this variation at different sites. A universal simulation model for water flux was built using the RF approach and key variables as determined by MLR, incorporating data from all sites. Model performance of the SVM algorithm (R² = 0.25–0.90) was slightly worse than that of the RF algorithm (R² = 0.41–0.91); the BPNN algorithm performed poorly in most cases (R² = 0.15–0.88). Similarly, the MLR results were limited and unreliable (R² = 0.00–0.66). Using the universal RF model, annual water fluxes were found to be much higher than the precipitation received at each site, and natural oases showed higher fluxes than desert ecosystems. Water fluxes were highest during the growing season (May–September) and lowest during the non-growing season (October–April). Furthermore, the dominant drivers of water flux variation were various among different sites, but the normalized difference vegetation index (NDVI), soil moisture and soil temperature were important at most sites. This study provides useful insights for simulating water fluxes in desert and oasis ecosystems, understanding patterns of variation and the underlying mechanisms. Besides, these results can make a contribution as the decision-making basis to the water management in desert and oasis ecosystems.     

Lake sedimentary processes and vegetation changes over the last 45k cal a bp in the uplands of south-eastern Amazonia

This study addresses paleoclimate influences in a southern Amazonia ecotone based on multiproxy records from lakes of the Carajás region during the last 45k cal a bp. Wet and cool environmental conditions marked the initial deposition in shallow depressions with detrital sediments and high weathering rates until 40k cal a bp. Concomitantly, forest and C3 canga plants, along with cool-adapted taxa, developed; however, short drier episodes enabled expansion of C4 plants and diagenetic formation of siderite. A massive event of siderite formation occurred approximately 30k cal a bp under strong drier conditions. Afterwards, wet and cool environmental conditions returned and persisted until the Last Glacial Maximum (LGM). The LGM was marked by lake-level lowstands and subaerial exposure. The transition from the LGM to the Holocene is marked by the onset of oscillations in temperature and humidity, with an expansion of forest and canga plants. Cool taxa were present for the last time in the Carajás region ~ 9.5–9k cal a bp. After 10k cal a bp , shallow lakes became upland swamps due to natural infilling processes, but the current vegetation types and structures of the plateaus were acquired only after 3k cal a bp under wetter climatic conditions.