Coma Structures in Comet 73P/Schwassmann-Wachmann 3, Components B and C,Between January and May 2006

The Jupiter family comet 73P/Schwassmann-Wachmann 3 has been widely observed since 1995 after a nucleus break-up event produced at least five components labeled 73P-A to E. During the 2006 appearance, two of them (B and C) showed very strong coma activity. Our R-filter imaging of 73P-B & C from 21 January to 25 May 2006 revealed the presence of fan-like structures in the comae of both components and evidence for further fragmentation events in component B. As of early April 2006, component C showed two jets emanating from the nucleus, with one continuously visible. Through a simulation of the orbital geometry we infer that the rotation axis of 73P-C has an inclination of 20° to the orbital plane and a longitude of 45° at perihelion. The coma activity of component B was highly variable, displaying signatures of at least 3 fragmentation events. The coma was characterized by the continuous presence of a jet roughly in sunward direction, starting from the beginning of May. The first fragmentation event of component B may have happened between April 16 and April 26, leading to the presence of at least 6 fragments detected in images of May 2. The second one happened on or shortly before May 8, the third one between May 18 and 24. For the rotation axis of 73P-B we infer an inclination of 5°–15° to the orbital plane and a longitude of 20°–30° at perihelion.     

Immobilization of toxic elements in mine residues derived from mining activities in the Iberian Pyrite Belt (SW Spain): Laboratory experiments

In the mining environments of the Iberian Pyrite Belt (IPB), the oxidation of sulphide wastes generates acid drainage with high concentrations of SO₄, metals and metalloids (Acid Mine Drainage, AMD). These acid and extremely contaminated discharges are drained by the fluvial courses of the Huelva province (SW Spain) which deliver high concentrations of potentially toxic elements into the Gulf of Cádiz. In this work, the oxidation process of mine tailings in the IPB, the generation of AMD and the potential use of coal combustion fly ash as a possible alkaline treatment for neutralization of and metal removal from AMD, was studied in non-saturated column experiments. The laboratory column tests were conducted on a mine residue (71.6 wt% pyrite) with artificial rainfall or irrigation. A non-saturated column filled solely with the pyrite residue leached solutions with an acid pH (approx. 2) and high concentrations of SO₄ and metals. These leachates have the same composition as typical AMD, and the oxidation process can be compared with the natural oxidation of mine tailings in the IPB. However, the application of fly ash to the same amount of mine residue in another two non-saturated columns significantly increased the pH and decreased the SO₄ and metal concentrations in the leaching solutions. The improvement in the quality of leachates by fly ash addition in the laboratory was so effective that the leachate reached the pre-potability requirements of water for human consumption under EU regulations. The extrapolation of these experiments to the field is a promising solution for the decontamination of the fluvial courses of the IPB, and therefore, the decrease of pollutant loads discharging to the Gulf of Cádiz.     

Selective destruction and differentiation of clay minerals from natural diaspore admixture by mortar grinding

A dry grinding process at several periods has been used successfully in order to differentiate among the different minerals forming a natural diaspore clay. This is achieved by selective and incongruent destruction of the clay minerals of this admixture, on the basis of their disparate structural stability, hardness and relative amount present. Kaolin clays (represented mainly by kaolinite + halloysite) are destroyed after >3 hr grinding, anatase after ～40 hr, whereas the structure of α-AlOOH is still preserved after >250 hr, as ascertained from XRD. From IR spectroscopy analysis it is inferred that as a consequence of grinding prototropy takes place in some of the clay hydroxyls. This is supported by water losses results at 600°C.     

The use of GIS tools to support decision-making in the expansion of chain stores

This article deals with a network competitive localization problem in which a firm seeks to determine the location of a new facility, which competes with all the facilities operating in the market, both belonging to the same firm and to the competing firms. In this context, two frequently conflicting objectives are involved: maximization of the total market share captured by the firm and minimization of market share losses for its existing facilities due to being captured by the new facility (cannibalization). We formulate the location problem as a multi-objective optimization model. Some GIS tools that provide some maps representing the market share and the cannibalization effect are proposed. This allows for the visualization of the effects produced by the opening of a new facility in the market and the trade-offs between the objectives. Finally, the advantages of using these tools have been shown by means of an application to a real data case.     

Free and open source software for geospatial applications (FOSS4G) to support Future Earth

ABSTRACT

The development, integration, and distribution of the information and spatial data infrastructure (i.e. Digital Earth; DE) necessary to support the vision and goals of Future Earth (FE) will occur in a distributed fashion, in very diverse technological, institutional, socio-cultural, and economic contexts around the world. This complex context and ambitious goals require bringing to bear not only the best minds, but also the best science and technologies available. Free and Open Source Software for Geospatial Applications (FOSS4G) offers mature, capable and reliable software to contribute to the creation of this infrastructure. In this paper we point to a selected set of some of the most mature and reliable FOSS4G solutions that can be used to develop the functionality required as part of DE and FE. We provide examples of large-scale, sophisticated, mission-critical applications of each software to illustrate their power and capabilities in systems where they perform roles or functionality similar to the ones they could perform as part of DE and FE. We provide information and resources to assist the readers in carrying out their own assessments to select the best FOSS4G solutions for their particular contexts and system development needs.     

Basis for a streamflow forecasting system to Rincón del Bonete and Salto Grande (Uruguay)

This paper presents the basis for the design of streamflow prediction systems for the hydroelectric dams of Rincón del Bonete (Uruguay) and Salto Grande (Uruguay–Argentina). The prediction is made, independently, for each reservoir and each month of the year with two methodologies: data-driven statistical models and hybrid downscaling that includes atmospheric predictors. We determine a set of potential predictors and then fit linear models coupled with variable selection techniques, under the hypothesis of perfectly known predictors. The predictive skill of the schemes outperforms the climatological forecast throughout the year in both reservoirs (except August in Rincón del Bonete). This remains the case even when the forecast lead does not allow for the use of preceding flows as predictors. While in Rincón del Bonete it is not possible to distinguish a period of high predictability, in Salto Grande, there is a robust signal in March–May and October–December.     

Assessment of phosphogypsum impact on the salt-marshes of the Tinto river (SW Spain): role of natural attenuation processes

About 120 Mton of phosphogypsum from the fertiliser industry were stack-piled on the salt-marshes of the Tinto river (Spain). This paper investigates the capacity of salt-marshes to attenuate contamination due to downward leaching from phosphogypsum. Solids and pore-waters were characterized at different depths of the pile to reach the marsh-ground. In superficial zones, metals were highly mobile, and no reduced sulphur was found. However, pollutant concentration decreased in the pore-water in deeper oxygen-restricted zones. Metal removal occurred by precipitation of newly formed sulphides, being this process main responsible for the contamination attenuation. Pyrite-S was the main sulphide component (up to 2528 mg/kg) and occurred as framboids, leading to high degrees of pyritization (up to 97%). The sulphidization reaction is Fe-limited; however, excess of acid-volatile sulphide over other metals cause precipitation of other sulphides, mainly of Cu and As. This decrease in metal mobility significantly minimises the impact of phosphogypsums on the salt-marshes.