Immobilization of toxic elements in mine residues derived from mining activities in the Iberian Pyrite Belt (SW Spain): Laboratory experiments

In the mining environments of the Iberian Pyrite Belt (IPB), the oxidation of sulphide wastes generates acid drainage with high concentrations of SO₄, metals and metalloids (Acid Mine Drainage, AMD). These acid and extremely contaminated discharges are drained by the fluvial courses of the Huelva province (SW Spain) which deliver high concentrations of potentially toxic elements into the Gulf of Cádiz. In this work, the oxidation process of mine tailings in the IPB, the generation of AMD and the potential use of coal combustion fly ash as a possible alkaline treatment for neutralization of and metal removal from AMD, was studied in non-saturated column experiments. The laboratory column tests were conducted on a mine residue (71.6 wt% pyrite) with artificial rainfall or irrigation. A non-saturated column filled solely with the pyrite residue leached solutions with an acid pH (approx. 2) and high concentrations of SO₄ and metals. These leachates have the same composition as typical AMD, and the oxidation process can be compared with the natural oxidation of mine tailings in the IPB. However, the application of fly ash to the same amount of mine residue in another two non-saturated columns significantly increased the pH and decreased the SO₄ and metal concentrations in the leaching solutions. The improvement in the quality of leachates by fly ash addition in the laboratory was so effective that the leachate reached the pre-potability requirements of water for human consumption under EU regulations. The extrapolation of these experiments to the field is a promising solution for the decontamination of the fluvial courses of the IPB, and therefore, the decrease of pollutant loads discharging to the Gulf of Cádiz.     

Inelastic response of one-storey asymmetric-plan systems subjected to bi-directional earthquake motions

The inelastic response of one-storey systems with one axis of asymmetry subjected to bi-directional base motion is studied in this paper. The effect of the system parameters on response is also evaluated: uncoupled torsional-to-lateral frequency ratio, stiffness eccentricity, and yield strength of the lateral resisting elements. The ensemble of earthquake records used consists of 15 two-component strong ground motions. The response to uni-directional excitation is considered first to examine the influence of the system parameters and to serve as a basis to examine the results of the bi-directional case, which are presented in terms of average spectra for bi- over uni-directional lateral-deformation ratios. It is shown that the effect of inelastic behaviour is, on the average, noteworthy for stiff structures, in turn, the same structures are the most affected by the action of bi-directional ground motions. The effect of the relative intensity of the two orthogonal ground motion components is also studied. Copyright © 1999 John Wiley & Sons, Ltd.     

Multidisciplinary approach of the hyperarid desert of Pampas de La Joya in southern Peru as a new Mars-like soil analog

The distribution of living organisms, organic matter, and chemical properties in Mars-like environments on Earth can be used as a model to guide the investigation of possible habitable environments on Mars. This work aims to demonstrate that the place known informally as the “Mar de Cuarzo” (Sea of Quartz) in the Pampas de La Joya desert southern Peru (between 16°S and 17°S latitude), contains soils with characteristics similar to those found on the Martian surface. Using a multidisciplinary approach, we studied the environmental data, geology, organic matter content, oxidant activity, and microbiology of this area. Our data show that (1) Mar de Cuarzo is a hyper arid area with a lower concentration of organic matter than those found in the Mars-like soils from Yungay area (Atacama Desert in Chile), while at the same time having, comparable extreme environmental conditions, and very low levels of microorganisms. (2) The detrital components of the soils come essentially from the Andean volcanic chain and local outcrops of Precambrian gneisses and Cretaceous granitic batholiths. (3) The presence of microclimates, geomorphological features, and the high influence of the “El Niño Southern Oscillation (ENSO)” allowed the formation of exotic and heterogeneous chemical deposits in these soils, including iron oxides, sulfates, and other evaporites. (4) Thermal volatilization in these soils (using methods similar to the Viking and Phoenix instruments) shows high oxidant activity. (5) Labeled release experiment (similar to the Viking instrument) shows high degradation of nutrients added in these soils.Altogether, the Mar de Cuarzo area in the Pampas de La Joya is an interesting place for astrobiological studies as a new analog to Mars, and for comparative analyses with other hyperarid analogs as Yungay.     

Influence of surface heterogeneities of building granite on its thermal response and its potential for the generation of thermoclasty

Surface properties, especially albedo, and aspect are widely accepted as strong influences on the surface thermal response of building stone to insolation. However, the influence that adjacent areas of stone with very different surface properties may have on the thermal response of a patch of stonework, and the ways in which spatial variation in thermal characteristics might enhance stone decay has received relatively little attention. This paper examines the differential thermal response of granite used in construction that results from the presence of dark coloured micro-granular enclaves within a leucocratic host. Surface temperatures and temperature differences between enclaves exhibiting mico-spalling, enclaves with no spalling and the surrounding stone were measured for different aspects and seasons on a 20th century building in Madrid. These data were used to calculate a number of “indices” related to short-term temperature cycling and temperature gradients that have the theoretical capability of generating irreversible deformation of the stone. These indices suggest that micro-spalling of enclaves, compared to a lack of similar decay on the host-rock, is related to their differential thermal response to insolation, most importantly the lower albedo and thermal conductivity values of the enclaves. However, these factors are not sufficient on their own to trigger spalling, and breakdown was only observed where enclaves also experienced repeated, short-term surface temperature cycling caused by, for example, temporary shading by adjacent vegetation. These rapid temperature reversals are identified as a key contributory factor to the thermally driven decay observed on some of the enclaves.     

Selective destruction and differentiation of clay minerals from natural diaspore admixture by mortar grinding

A dry grinding process at several periods has been used successfully in order to differentiate among the different minerals forming a natural diaspore clay. This is achieved by selective and incongruent destruction of the clay minerals of this admixture, on the basis of their disparate structural stability, hardness and relative amount present. Kaolin clays (represented mainly by kaolinite + halloysite) are destroyed after >3 hr grinding, anatase after ～40 hr, whereas the structure of α-AlOOH is still preserved after >250 hr, as ascertained from XRD. From IR spectroscopy analysis it is inferred that as a consequence of grinding prototropy takes place in some of the clay hydroxyls. This is supported by water losses results at 600°C.     

Basis for a streamflow forecasting system to Rincón del Bonete and Salto Grande (Uruguay)

This paper presents the basis for the design of streamflow prediction systems for the hydroelectric dams of Rincón del Bonete (Uruguay) and Salto Grande (Uruguay–Argentina). The prediction is made, independently, for each reservoir and each month of the year with two methodologies: data-driven statistical models and hybrid downscaling that includes atmospheric predictors. We determine a set of potential predictors and then fit linear models coupled with variable selection techniques, under the hypothesis of perfectly known predictors. The predictive skill of the schemes outperforms the climatological forecast throughout the year in both reservoirs (except August in Rincón del Bonete). This remains the case even when the forecast lead does not allow for the use of preceding flows as predictors. While in Rincón del Bonete it is not possible to distinguish a period of high predictability, in Salto Grande, there is a robust signal in March–May and October–December.     

Challenges at the early stages of the environmental licensing procedure and potential contributions from geomorphology

Defining impact significance is the main technical task that influences decision-making during the Environmental Licensing Procedure(ELP).The ELP begins with screening to determine potentially signif-icant impacts of the proposed project.Scoping then follows to address any interventions deemed worthy of attention in the production of an Environmental Impact Assessment(EIA).This will include consider-ation of relevant landforms and geomorphological processes.However,preliminary assessments of envi-ronmental impacts often lack the scientific robustness to procure substantive and transactive effectiveness.This review presents an examination of the established practices of screening and scoping while highlighting the foremost challenges to improve the technical grounds of the ELP.The analysis of screening and scoping practices stresses the need for novel methods that ensure the sequential reasoning between their criteria while improving the preliminary evaluation of impact significance.Reducing the inherent subjectivity of discretionary judgment requires scientific methodologies that acknowledge the interaction between the natural system and human interventions,which has been addressed by geomor-phological research.The knowledge consolidated in this review opens the gate to explore the compatibil-ity between the United Nations strategy of Ecosystem Approach(EA)with the ELP through a novel geomorphological interpretation of the EIA.Therefore,this diagnosis demonstrate that screening and scoping practices would benefit from reliable methods that balance the precautionary principle with the efficient character required in the ELP.     

Spatial pattern of photospheric granules in a sunspot neighborhood

Based on high-resolution (0.3 arcsec) observations, we studied the behavior of solar granulation in the neighborhood of a sunspot. The bright granules’ spatial distribution and the granules’ surface density as a function of distance from the center of the sunspot umbra were determined.Bright granules distribute delimiting cells of dimensions in the mesogranular scale. The mean diameter of these cells does not show significant variation with the variation of the magnetic field of the sunspot. The granules’ surface density does not show significant variation with distance to the sunspot umbra. Both results point to a very weak, if any, influence of the sunspot magnetic field at distances greater than 20 arcsec.