Relation entre fabriques de la sanidine et mise en place des magmas trachytiques (exemple de massif de Hradiště, Bohême du nord)

Résumén

La distribution des fabriques dans un dôme trachytique a été analysée sur la base des orientations préférentielles des cristaux de sanidine. L’orientation préférentielle des plans (010) des cristaux de sanidine a été quantifiée par le calcul du tenseur d’orientation. Le sens de cisaillement a été déterminé à l’aide de relations entre les plans S et C.

Les plans (010) des cristaux de sanidine montrent une fabrique résultant d’un aplatissement dans la partie centrale du dôme et d’un cisaillement simple dans les parties marginales. Les critères de cisaillement montrent le mouvement uni forme de magma trachytique à l’échelle de tout le massif. Nous interprétons la disposition des plans S-C et la répartition des fabriques dans le massif à la superposition de lames successives de magma les unes sur les autres. L’acquisition des fabriques dans le massif est comparée aux expériences en compression uniaxiale le Tullis (1976) et la mise en place des magmas trachytiques est assimilée au mouvement d’un piston dans des conditions de basse pression de confinement et de haute vitesse de déformation pendant le stade d’intrusion précuce. Le gonflement faible a modifié tardivement les fabriques initiales surtout dans la partie de déversement et sommitale.     

Maximum likelihood algorithm for parametric component separation in cosmic microwave background experiments

We discuss an approach to the component separation of microwave, multifrequency sky maps as those typically produced from cosmic microwave background (CMB) anisotropy data sets. The algorithm is based on the two-step, parametric, likelihood-based technique recently elaborated on by Eriksen et al., where the foreground spectral parameters are estimated prior to the actual separation of the components. In contrast with the previous approaches, we accomplish the former task with help of an analytically derived likelihood function for the spectral parameters, which, we show, yields estimates equal to the maximum likelihood values of the full multidimensional data problem. We then use these estimates to perform the second step via the standard, generalized-least-squares-like procedure. We demonstrate that the proposed approach is equivalent to a direct maximization of the full data likelihood, which is recast in a computationally tractable form. We use the corresponding curvature matrices to characterize statistical properties of the recovered parameters. We incorporate in the formalism some of the essential features of the CMB data sets, such as inhomogeneous pixel domain noise, unknown map offsets as well as calibration errors and study their consequences for the separation. We find that the calibration is likely to have a dominant effect on the precision of the spectral parameter determination for a realistic CMB experiment. We apply the algorithm to simulated data and discuss the results. Our focus is on partial sky, total intensity and polarization, CMB experiments such as planned balloon-borne and ground-based efforts, however, the techniques presented here should be also applicable to the full-sky data as for instance, those produced by the Wilkinson Microwave Anisotropy Probe ( WMAP ) satellite and anticipated from the Planck mission.     

Niobium-tantalum oxide minerals in the Jezuitsk�� Lesy granitic pegmatite, Bratislava Massif, Slovakia: Ta to Nb and Fe to Mn evolutionary trends in a narrow Be,Cs-rich and Li,B-poor dike

A complex assemblage of Nb-Ta-(Sn) oxide minerals occur in a relatively narrow (~1?2 m thick) extensively albitized, Hercynian granitic pegmatite dike intruding biotite granodiorites near Bratislava, SW Slovakia. The dike shows enrichment in beryl (locally Cs-rich) but absence of Li- and B-rich phases. Compositions and textural relationships indicate complex evolutions of Nb-Ta oxide phases with several generations presenting distinct textural and compositional features. The first generation of the Nb-Ta minerals from the quartz-microcline-muscovite zone show Ta,Fe-rich compositions with Ta# [Ta/(Ta + Nb)]?=?0.52?0.70 (Ct I columbite-tantalite), 0.88?0.90 (Tap I ferrotapiolite) and 0.73?0.86 (Fw I ferrowodginite); Mn# [Mn/(Mn + Fe)]?=?0.32?0.49 (Ct I), 0.06?0.10 (Tap I) and 0.33?0.41 (Fw I). The 2nd generation is represented by ferrocolumbite to ferrotantalite (Ct II) in saccharoidal albite zone, replacement zones of Ct II in Ct I, and irregular overgrowths of ferrotapiolite (Tap II) and ferrowodginite (Fw II) on Tap I grains. The minerals of the 2nd generation show decreasing of Ta# in comparison to the 1st group: 0.10?0.60 (Ct II), 0.85?0.87 (Tap II) and 0.73?0.77 (Fw II); Mn# attains 0.30?0.45 (Ct II), 0.06?0.09 (Tap II) and 0.26?0.37 (Fw II). The 3rd generation includes fissure fillings, overgrowths and replacement zones of manganocolumbite and manganotantalite (Ct III), ferrotapiolite (Tap III) and ferrowodginite (Fw III) on the older Nb-Ta phases (Ct I, Tap I, Fw I, Fw II), in the coarse-grained unit. The 3rd population displays distinct Mn# increasing (Ct III: 0.51?0.69, Tap III: 0.11?0.24, Fw III: 0.40?0.41), Ta# values reach 0.16?0.79 (Ct III), 0.88?0.92 (Tap III) and 0.80?0.81 (Fw III). The latest, 4th generation of the Nb-Ta phases represents irregular veinlets and patches of fluorcalciomicrolite, replacing Ct I, Tap I, Fw I, Ct II and Tap III. Decrease of Ta/(Ta + Nb) values in Ct II from the saccharoidal albite unit can be explained by crystallization from the albite-rich melt, which was significantly impoverished in Ta with respect to Nb, after crystallization of Ta-rich phases from the 1st generation (ferrotapiolite I, ferrowodginite I).     

Solid solutions in the system acanthite (Ag<Subscript>2</Subscript>S)–naumannite (Ag<Subscript>2</Subscript>Se) and the relationships between Ag-sulfoselenides and Se-bearing polybasite from the Kongsberg silver district,Norway, with implications for sulfur–selenium fractionation

Sulfoselenides [Ag₂(S,Se)] and Se-bearing polybasite have been discovered at the Kongsberg silver district. The selenium-bearing minerals occur in two samples from the northern part of the district, forming either single or polyphase inclusions together with chalcopyrite within native silver. The Ag-sulfoselenides show large chemical variations, covering nearly the complete compositional range between acanthite (Ag₂S) and naumannite (Ag₂Se). For the data presented here, there is no local maximum at the composition Ag₄SSe attributed to the distinct phase called aguilarite, suggesting that this composition can be considered as one of many possible along the monoclinic Ag₂S–Ag₂S_0.4Se_0.6 solid solution series rather than a specific mineral phase. We present a model explaining the variations in the Se-content of Ag₂(S,Se) as a result of gradual de-sulfidization of the rock under oxidizing conditions. During this process, sulfur from the Ag₂S-component of Ag₂(S,Se) oxidized and dissolved in the fluid phase as SO₄^2?, resulting in the formation of native silver. The activity ratio \({a_{{{\text{S}}^{2 - }}}}/{a_{{\text{S}}{{\text{e}}^{2 - }}}}\) of the system gradually decreased due to the removal of SO₄^2?, which resulted in the stabilization of a sulfoselenide with higher selenium content. As a result of reaction progress, grains of Ag₂(S,Se) became gradually enclosed in newly formed native silver, and therefore isolated from further reactions with the grain-boundary fluid. Grains isolated early during the process show low content of Se reflecting high \({a_{{{\text{S}}^{2 - }}}}/{a_{{\text{S}}{{\text{e}}^{2 - }}}}\) of the equilibrium fluid, while grains showing high Se reflect the composition of late low \({a_{{{\text{S}}^{2 - }}}}/{a_{{\text{S}}{{\text{e}}^{2 - }}}}\) fluids. Analyses of Se-bearing polybasite show that selenium is preferentially partitioned into Ag₂(S,Se) compared to polybasite. The model presented here demonstrates how oxidation of sulfoselenides leads to fractionation of sulfur and selenium.     

Variscan deformation,microstructural zonation and extensional exhumation of the Moravian Cadomian basement

Abstract

The Cadomian Dyje Batholith, in the foot–wall of the Variscan Moravian nappe pile, has been involved in Variscan ductile deformation. The Cadomian Brunovistulian rocks were obliquely underthrusted during Carboniferous dextral transpression.

Strain intensity is inversely proportional to the distance from the contact of the Variscan thrust front. The microstructures of deformed granodiorites and quartz–diorites show a characteristic zonality marked by relatively high temperature flow in the west (550–580 °C) characterized by dynamic recrystallization of feldspars and grain boundary migration recrystallization of quartz. The size of quartz grains decreases with decreasing strain towards the east. At the easternmost part of the autochthonous Dyje massif, fracturing of feldspar and subgrain rotation recrystallization of quartz predominate. Flow stress estimates calculated from recrystallized quartz grain size show a regional increase of stress intensity from the highly strained margin towards the less deformed core of the Dyje massif. This microstructural zonation is oblique with respect to the major thrust boundary and corresponds roughly to metamorphic isogrades. The microstructural zonation reflects underthrusting of the Brunovistulian domain below the Moldanubian nappe.

The main ductile tectonic event D₁ is followed by a retrogressive brittle–ductile and brittle deformation D₂. D₂ results in the development of shear zones and faults superimposed on the D₁ mylonite fabric. D₂ is related to extension oblique to the D₁ fabric, associated with detachment and the westward movement of the Moravian nappes. © Elsevier, Paris     

Geochemistry and mineralogy of bentonites from Ishirini (Libya)

Smectites from the Ishirini bentonite deposit (Libya) were analysed for their oxygen and hydrogen isotopic ratios. Based on published isotopic fractionation data, the results indicate a predominantly meteoric origin of the fluids responsible for the transformation of pyroclastic rocks to bentonite at temperatures ranging from 30 to 90 °C. The thermal effect of the subsequent emplacement of volcanic intrusions was further evaluated by a detailed study of δ¹⁸O isotopic composition of smectites and fluid inclusions in quartz separated from silicified rings produced by the thermal action of a basalt dike. Five different groups of fluids were distinguished based on salinity and homogenization temperatures.

The contact zone of bentonite affected by high concentrated saline solution exhibit mineralogical changes. High salinity and high temperature also remarkably influence the technical parameters of bentonites and reduce, for example, the cation exchange capacity (CEC) or microporosity.     

Palaeoflood discharge estimation using dendrogeomorphic methods,rainfall-runoff and hydraulic modelling—a case study from southern Crete

Natural Hazards - This study represents the first palaeoflood discharge estimation using dendrogeomorphic evidence from two ungauged catchments in southern Crete. Dendrogeomorphological methods,...