Comparison of dissolved and particulate arsenic distributions in shallow aquifers of Chakdaha, India, and Araihazar, Bangladesh

Background  

The origin of the spatial variability of dissolved As concentrations in shallow aquifers of the Bengal Basin remains poorly understood. To address this, we compare here transects of simultaneously-collected groundwater and aquifer solids perpendicular to the banks of the Hooghly River in Chakdaha, India, and the Old Brahmaputra River in Araihazar, Bangladesh.     

The Almadén mercury mining district, Spain

The Almadén district is the largest mercury concentration in the world, with a total content of about 250 000 t of mercury, nearly one third of the known total mercury resources of the Earth. Mercury has been exploited since the Celtic and Roman times, with peak production during the Renaissance and between 1939–1945. The district is hosted by a Paleozoic synclinorium overlying Precambrian rocks. The Paleozoic sequence comprises epicontinental quartz arenite rocks, including black shales and quartzites. Diatremes, alkaline lavas of different composition, and late tholeiitic diabases account for the Ordovician to Devonian magmatism. The tectonic setting of this complex suite corresponds to the intraplate type. The mercury deposits of Almadén can be classified into two main types: type 1, early stratiform type ores characterized by cinnabar deposition on the lower Silurian quartzites (Criadero quartzite; e.g. the Almadén and El Entredicho deposits), and type 2, late discordant orebodies (e.g. Las Cuevas), largely hosted or related to diatremes (the `frailesca rocks') of alkaline basaltic composition. In type 1 cinnabar was deposited during diagenesis, in relation to hydrothermal circulation driven by magmatic activity. Type 2 include a variety of deposits having in common the discordant character of the orebodies (e.g. veins, stockworks, massive replacements), and their wide dispersion along the stratigraphic column, i.e. from Lower Silurian (e.g. Nueva Concepción) to Upper Devonian (e.g. Corchuelo). Received: 23 October 1998 / Accepted: 4 January 1999     

Time‐scale analysis in unsaturated porous media under external wave loads

Extreme waves caused by tsunamis and storm surges can lead to soil failures in the near‐shore region, which may have severe impact on coastal environments and communities. Multiphase flows in deformable porous media involve several coupled processes and multiple time scales, which are challenging for numerical simulations. The objective of this study is to investigate the roles of the various processes and their interactions in multiphase flows in unsaturated soils under external wave loading, via theoretical time‐scale analysis and numerical simulations. A coupled geomechanics–multiphase flow model based on conservation laws is used. Theoretical analysis based on coupled and decoupled models demonstrates that transient and steady‐state responses are governed by pore pressure diffusion and saturation front propagation, respectively, and that the two processes are essentially decoupled. Numerical simulations suggest that the compressibility of the pore fluids and the deformation of the soil skeleton are important when the transient responses of the media are of concern, while the steady‐state responses are not sensitive to these factors. The responses obtained from the fully coupled numerical simulations are explained by a simplified time‐scale analysis based on coupled and decoupled models. Copyright © 2010 John Wiley & Sons, Ltd.     

Fracture roughness and thermal exchange: A case study at Soultz-sous-Forêts

Heat exchange during laminar flow in an open fracture is studied numerically on the basis of the Stokes equation in the limit of hydrothermal lubrication. We examine the influence of fracture roughness on hydraulic permeability and heat flux through the fracture sides when a cold fluid is injected into a homogeneous hot host rock. Spatial temperature fluctuations inside the fluid are studied assuming the temperature of the rock to be constant and the fracture aperture to be self-affine. An application to the case study at the deep geothermal reservoir of Soultz-sous-Forêts, France, is presented. Finally, a thermal model based on sparse spatial information of the geometrical aperture is successfully proposed to reproduce the response of the fracture.     

Enhanced groundwater vulnerability assessment in geological homogeneous areas: a case study from the Argentine Pampas

The southeast area of the Argentine Pampas is characterized by the presence of an unconfined aquifer in a wide plain. A methodology is proposed that deals with the aquifer vulnerability where the homogeneity of the hydrogeological variables used by traditional methods (in this case, DRASTIC-P) causes vulnerability maps to show more than 80% of the territory under the same class. This absence of discrimination renders vulnerability maps of little use to decision-makers. In addition, the proposed methodology avoids the traditional vague classification (high, low, and moderate vulnerability) which is highly dependent on subjectivity in its association of each class with hydrogeological considerations. That traditional vulnerability assessment methodology was adapted using a geographic information system to reclassify classes, based on the Natural Breaks (Jenks) method. The pixel-to-pixel comparison between the result obtained by the DRASTIC-P and the reclassified classes generates the so-called operational vulnerability index (OVI), which shows four classes, associating each with different hydrogeological requirements to make decisions.     

Development of a Darcy-Brinkman model to simulate water flow and tracer transport in a heterogeneous karstic aquifer (Val d’Orléans, France)

Darcy’s law is the equation of reference widely used to model aquifer flows. However, its use to model karstic aquifers functioning with large pores is problematic. The physics occurring within the karstic conduits requires the use of a more representative macroscopic equation. A hydrodynamic model is presented which is adapted to the karstic aquifer of the Val d’Orléans (France) using two flow equations: (1) Darcy’s law, used to describe water flow within the massive limestone, and (2) the Brinkman equation, used to model water flow within the conduits. The flow equations coupled with the transport equation allow the prediction of the karst transfer properties. The model was tested by using six dye tracer tests and compared to a model that uses Darcy’s law to describe the flow in karstic conduits. The simulations show that the conduit permeability ranges from 5?×?10^?6 to 5.5?×?10^?5?m² and the limestone permeability ranges from 8?×?10^?11 to 6?×?10^?10?m². The dispersivity coefficient ranges from 23 to 53 m in the conduits and from 1 to 5 m in the limestone. The results of the simulations carried out using Darcy’s law in the conduits show that the dispersion towards the fractures is underestimated.     

Mafic magma batches at Vesuvius: a glass inclusion approach to the modalities of feeding stratovolcanoes

Glass inclusions in olivine and diopside phenocrysts from pyroclasts of various eruptions of Vesuvius are representative of the magmas that supplied the volcano in the last 4–5000 years. During this interval the volcano alternated between open conduit activity (e.g. 1944 and 1906 eruptions) with long pauses interupted by Plinian and sub-Plinian eruptions (e.g. 3360 B.P. Avellino, A.D. 79 Pompei, A.D. 472 Pollena). The eruptive behaviour was conditioned in all cases by the presence of shallow reservoirs: two cases are distinguished: (1) small and very shallow, 1906-type; (2) large and deeper Plinian-sub-Plinian magma chamber. Lapilli of 1906 lava fountains contain olivine (Fo_89.5–90.4) including Cr-spinel [Cr/(Cr+Al)] (Cr#>75) and volatile-K-rich tephritic glasses, which represent the first recognized Vesuvius primary magmas. Mg-poorer olivine (Fo_83–89) also occurs in 1906 and 1944 products; it formed within the shallow reservoir, together with pyroxene and leucite, between 1200 and 1130°C, from K-tephritic melts (MgO=6–8 wt%). The Plinian and sub-Plinian pumices contain diopside, phlogopite and minor olivine (Fo_85–87) representing adcumulates wrenched from the chamber walls. Glass inclusions in diopside (and some olivine) range from K-basalt to K-tephrite (MgO=6–8 wt%), with homogenization temperature of 1130–1170°C. They have been regarded as representative of the magmas supplying the Plinian-sub-Plinian chamber(s). The Avellino glass inclusions have K-basaltic compositions, contrasting with the mostly K-tephritic Pompei and Pollena inclusions. They display lower C1 and P contents with respect to the younger tephritic melts, and these variations should reflect primary features of the mantle-derived magmas. The primary and the near-primary Vesuvius magmas, as illustrated by melt inclusions, emphasize high K, P and volatile (H₂O, Cl, F, S) contents, with high K₂O/H₂O (2–2.5), Cl/F (2.5) and Cl/S (2–3) ratios, consistent with a metasomatized mantle source, and distinguishing the Vesuvius potassic primary magmas from those of the northern part of the Roman Province.     

Regional Seas and Sustainable Development Results of an International Workshop

Reports

Regional Seas and Sustainable Development Results of an International Workshop     

The role of principles and methods in loess-paleosol investigations

In the process of loessification, the development of loess fabric, the role of zonal, regional and partly of local environmental factors is regarded decisive. In the loess sequences various genetic types of loess pockets and paleosols occur and reflect different climatic and paleogeographical conditions.As a consequence, even within a single profile the colour, grain size and mineral composition, CaCO₃ content, degree of weathering and fabric of loess may vary. Zonal, regional or even local variations in such loess properties may equally derive from syngenetic or postgenetic processes. For similar reasons, spatially and temporally different forms, types and subtypes of paleosol also developed.This way, loess and soil formation resulted in various spatial types in the same glacial, interstadial or interglacial phase in the various geographical zones and regions. Although there exist major loess regions where the interglacial soils (eg brown forest soils) are markedly distinct from interstadial steppe soils or from other types of humic soils, continental loess areas can also be observed where the paleosols developed under interglacial and interstadial conditions (eg steppe or forest steppe soils) cannot be referred into different genetic types. In such cases the changes in paleoenvironments are difficult and uncertain to reconstruct.The interregional correlation of paleosols is occasionally hindered by the various terminologies applied to denote them. In addition, there are uncertainties concerning the dating and identification of paleoenvironments of polygenetic soils and of soil complexes consisting of paleosol units: how many soil formation phases they represent and how long erosional gaps can be reckoned with between these phases.