Exploring CO pollution episodes observed at Rishiri Island by chemical weather simulations and AIRS satellite measurements: long-range transport of burning plumes and implications for emissions inventories

The summer of 2003 was an active forest fire season in Siberia. Several events of elevated carbon monoxide (CO) were observed at Rishiri Island in northern Japan during an intensive field campaign in September 2003. A simulation with a global chemistry-transport model is able to reproduce the general features of the baseline levels and variability in the observed CO, and a source attribution for CO in the model suggests that the contribution from North Asia dominated, accounting for approximately 50% on average, with contributions of 7% from North America and 8% from Europe and 30% from oxidation of hydrocarbons. With consideration of recent emission estimates for East Asian fossil fuel and Siberian biomass burning sources, the model captures the timing and magnitude of the CO enhancements in two pollution episodes well (17 and 24 September). However, it significantly underestimates the amplitude during another episode (11–13 September), requiring additional CO emissions for this event. Daily satellite images from AIRS reveal CO plumes transported from western Siberia toward northern Japan. These results suggest that CO emissions from biomass burning in western Siberia in 2003 are likely underestimated in the inventory and further highlight large uncertainties in estimating trace gas emissions from boreal fires.     

OPTIMAL MANAGEMENT OF THE SUBSURFACE ENVIRONMENT / L'aménagement optimal de l'environnement souterrain

Abstract

A mathematical model for the optimal, conjunctive management of a groundwater basin's quality and quantity resources is presented. The quality resource, the assimilative waste capacity, is the ability of the aquifer to degrade certain non-conservative constituents through the actions of molecular diffusion, hydrodynamic dispersion, adsorption, biochemical reactions and convective mass transport. The model is applicable to saturated, isothermal, porous media. The Galerkin method is used to express the spatial and temporal variations in hydraulic head and constituent concentrations as a function of possible recharge, pumping, and treatment decisions. The Galerkin procedure ensures that the constraint equations actually model the response characteristics (flow and mass transport) of the groundwater basin. In each planning period, the groundwater basin is required to meet an exogenous water demand while maintaining adequate water quality levels throughout the aquifer. The model, structured as a mathematical program, minimizes the sum of waste water treatment and pumping and recharge costs. The results indicate (1) the feasibility of conjunctive management of an aquifer's quality and quantity resources, and (2) that the assimilative waste capacity can function as a form of secondary or advanced waste water treatment.     

Mapping Submerged Aquatic Vegetation with GIS in the Caloosahatchee Estuary: Evaluation of Different Interpolation Methods

This article evaluates different spatial interpolation methods for mapping submerged aquatic vegetation (SAV) in the Caloosahatchee Estuary, Florida. Data used for interpolation were collected by the Submersed Aquatic Vegetation Early Warning System (SAVEWS). The system consists of hydro-acoustic equipment, which operates from a slow-moving boat and records bottom depth, seagrass height, and seagrass density. This information is coupled with geographic location coordinates from a Global Positioning System (GPS) and stored together in digital files, representing SAV status at points along transect lines. Adequate spatial interpolation is needed to present the SAV information, including density, height, and water depth, as spatially continuous data for mapping and for comparison between seasons and years. Interpolation methods examined in this study include ordinary kriging with five different semivariance models combined with a variable number of neighboring points, the inverse distance weighted (IDW) method with different parameters, and the triangulated irregular network (TIN) method with linear and quintic options. Interpolation results were compared with survey data at selected calibration transects to examine the suitability of different interpolation methods. Suitability was quantified by the determination coefficient (R2) and the root-mean-square error (RMSE) between interpolated and observed values. The most suitable interpolation method was identified as the one yielding the highest R2 value and/or the lowest RMSE value. For different geographic conditions, seasons, and SAV parameters, different interpolation methods were recommended. This study identified that kriging was more suitable than the IDW or TIN method for spatial interpolation of all SAV parameters measured. It also suggested that transect data with irregular spatial distribution patterns such as SAV parameters are sensitive to interpolation methods. An inappropriate interpolation method such as TIN can lead to erroneous spatial representation of the SAV status. With a functional geographic system and adequate computing power, the evaluation and selection of interpolation methods can be automated and quantitative, leading to a more efficient and accurate decision.     

Temporal and spatial sedimentation rate variabilities in the eastern Gotland Basin, the Baltic Sea

The present study examines sedimentation rates in the eastern Gotland Basin using a variety of methods that reveal considerable heterogeneity in the rates, both spatially and temporally. High-resolution seismic recordings and correlation with long sediment cores indicate increased thickness of strata and higher sedimentation rates (0.75 mm a -1 ) in the eastern part of the basin than in the western part (0.23 mm a -1 ) since the Littorina transgression some 8000 14 C years BP. This difference is apparently a consequence of a counterclockwise near-bottom circulation in the basin with periodically high current speeds that cause winnowing on the steep SE slope of the basin and differential settling of sediments in areas of low current speeds. On shorter time scales, recent sediment accumulation rates based on radiometric dating ( 210 Pb) are in general twice as high as those observed 25 years ago using the same method. The higher modern rates, compared to those of the 1970s, may partly be due to increased eutrophication, as more carbon is buried in the sediment, and partly due to increased erosion in shallow water areas. However, strong lateral variations are evident. The average sediment accumulation rates vary between 119 and 340 g m -2 a -1 (corresponding to sedimentation rates of 2.1-2.5 mm a -1 ) in the deepest part of the basin. Very high rates (6100 g m -2 a -1 , corresponding to sedimentation rates of 30 mm a -1 ) are observed on an intraslope basin site (offshore Latvia) at a water depth of only 70 m. The radiometrically determined sediment accumulation rates are up to three times higher than those estimated from average water column concentrations of suspended matter and from sediment trap flux rates. The discrepancy suggests that sedimentation in the deep basin may have a substantial contribution from near-bottom lateral transport.     

How Hannibal conquered geology

During his crossing of the Alps, Hannibal is said to have cleared a large rockfall with the aid of fire and ‘vinegar’. Would such a treatment have worked? Modern research suggests that it would.     

Geology and jungle fieldwork in eastern Indonesia

Collecting geological information from the jungles and islands of eastern Indonesia depends largely on traditional fieldwork methods involving much footwork and messing about in boats. Coupled with modern laboratory and computing techniques, information gained on the ground is being used to interpret the tectonic development of east Indonesia, the Philippine Sea and the western Pacific.     

The Late Quaternary sedimentary record in Scoresby Sund, East Greenland

Until recently, little was known about the Quaternary marine sedimentary record in East Greenland. Geophysical and geological investigations in Scoresby Sund were undertaken to characterize the nature and chronology of this record. Seismic records show that almost 70% of the outer fjord system is covered by about 10 m of unlithified sediments, making direct correlation with the Quaternary records on land and the adjacent continental margin difficult. These acoustically unstratified sediments are scoured by icebergs above 550 m water depth. Almost 90% of core material is massive diamicton of Holocene age, deposited mainly from iceberg rafting and turbid meltwater. Sedimentation rates are 0.1 -0.3 m 1000 yr-¹. Thicker accumulations of unlithified Quaternary sediments in Scoresby Sund occur as sediment ridges and in two other major depocentres. A low sediment ridge runs across the mouth of Scoresby Sund, and is interpreted as an end moraine of Late Weichselian Flakkerhuk stadial age. The very restricted sediment thickness suggests that grounded ice filled the fjord during the Flakkerhuk and an ice shelf was not present. High inputs of ice rafted debris to the continental margin at about 18 000 BP indicate this as a probable age for the moraine. During the Allerød Interstadial, ice probably retreated from the outer fjord system, since massive diamictons similar to those of Holocene age are present at the base of most cores. A major depocentre of acoustically stratified sediments at the head of Hall Bredning is interpreted to represent ice proximal deposits from a glacier margin extending across the fjord. It is adjacent to dated moraines on land and is inferred to be of Milne Land stadial age (about 10 000 BP). A similar age is interpreted for acoustically laminated sediments and a moraine at the entrance of Vikingebugt, on the south side of Scoresby Sund. Dated kame terraces in the inner fjord system indicate that ice retreated to its present position 6–7000 years ago.     

A climatological study of polar stratospheric clouds (1989–1997) from LIDAR measurements over Dumont d'Urville (Antarctica)

Backscatter lidar data from the French Antarctic base in Dumont d'Urville (66.40°S, 140.01°E), including aerosol background and observations of polar stratospheric clouds (PSCs), have been collected since 1989. In the present work we present a climatological study of PSCs, using a data base consisting of almost 90 observations. The seasonal evolution of PSCs, their optical classification, and their relationship with the observation temperature were studied. The first PSC was observed on day number 175 (15 June) and the last on day number 260 (7 September). The characteristic mid‐cloud altitude decreases through the season at a rate of 2.5 km/month. Type Ia, Ib, and II PSCs — identified by their optical properties — have been observed. External mixtures of these types have also been observed. These observations have been related to the local temperature measured by radiosondes. The relationship between PSC type and the period of the winter season was also investigated. Mixed (solid and liquid) type I clouds are mostly observed at the beginning of the winter. Type II clouds are observed only during the coldest period around midwinter, although temperatures below the frost point begin earlier and persist longer than this. Type Ia, solid‐particle, clouds are observed mostly at the end of the winter.     

Late Miocene Halimeda alga-microbial segment reefs in the marginal Mediterranean Sorbas Basin, Spain

A ～6 Ma Messinian (late Miocene) Bioherm Unit on the southern slope of the Sorbas Basin, SE Spain, contains numerous biotically diverse lensoid patch reefs that formed on a shelf to basin slope during a cycle of relative sea-level change. Halimeda reefs are the largest and most complex of the patch reefs and are divisible into core, cap, and flank facies. On the upper and midslope they are up to 40 m thick and 400 m long. They become smaller downslope. The core consists of jumbled Halimeda segments, released by spontaneous disaggregation of the alga. The segments were stabilized close to their sites of growth and rapidly lithified by micritic and peloidal microbial crusts. Residual cavities were further veneered by isopachous marine cements. Flank facies, consisting of bedded packstones to rudstones, form wedge-shaped units lateral to the mounds. Cap facies consist of bioclastic calcarenites/calcirudites and microbial carbonates. Synsedimentary lithification assisted rapid accretion and inhibited off-mound export of sediment. Allochthonous reef-derived blocks on the mid-slope reflect penecontemporaneous rigidity of the Halimeda bioherms. Proximal Porites coral frame patch reefs associated with calcarenites were located near the shelf margin during the initial lowstand stage. Halimeda segment reefs associated with calcarenites and silty marls developed on the midslope and bivalve-bryozoan-serpulid reefs formed on the lower slope in silty marls with occasional turbidites. During the transgressive stage, coral patch reefs near the shelfbreak were overgrown by Halimeda. During highstand progradation, cap facies spread basinward as a sheet connecting many of the midslope patch reefs. These ancient analogues differ from most modern Halimeda reefs in being discrete laterally restricted patch reefs, surrounded by marly sediment, and located on a slope. They are, however, broadly comparable in biota, thickness, and depositional depth. Intense early lithification by microbial crusts and marine cements is an important feature of these Messinian segment reefs. It has not been reported from modern examples.     

Early Cambrian braid-delta deposits, MacKenzie Mountains, north-western Canada

Latest Neoproterozoic to earliest Cambrian strata in north-western Canada provide an example of a pre-vegetation braid-delta depositional system. Depositional environments represented in the succession include braided fluvial and braid-delta distributary channels, aeolian dune fields and interdistributary lagoons/bays, as well as mouth bar, beach to shoreface, and prodelta to distal shelf settings. Three formations have been investigated: the Ingta Formation formed in wave-dominated nearshore to offshore shelf environments with little or no apparent deltaic influence, whereas the overlying Backbone Ranges and Vampire formations contain an extensive record of braid-delta deposits ranging from braidplain to distal prodelta facies. On the braid-plain, river channels reached widths of up to several kilometres. Such channels terminated seaward in braid deltas that showed some shoreline protuberance and were characterized by fluvial-dominated mouth-bar deposition with lesser wave influence; wave-dominated deltaic successions are rare in the succession. Interdeltaic areas were characterized by wave-dominated prograding shorelines. Interdistributary lagoons probably formed primarily in abandoned distributary channels. Delta-front/prodelta deposits are silt-rich and contain abundant soft-sediment deformation, including slumps. The deposits in these formations illustrate the significantly different nature of sedimentation prior to the advent of land plants. This is illustrated in the dominance of braided fluvial deposition and of silt-rich offshore facies that may have resulted from enhanced aeolian transport of loess. The non-actualistic effects of limited bioturbation and extensive microbial binding apparently exerted relatively little control on the distribution of facies. However, the absence of extensive bioturbation is manifest in pristine preservation of primary sedimentary structures, while the hypothesized latest Proterozoic-earliest Cambrian decline in microbial binding may be reflected in the upward increase in the abundance of sole marks in the succession.