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251.
Structure,composition, and location of organic matter in the enstatite chondrite Sahara 97096 (EH3) 总被引:1,自引:0,他引:1
Laurette PIANI François ROBERT Olivier BEYSSAC Laurent BINET Michèle BOUROT‐DENISE Sylvie DERENNE Corentin LE GUILLOU Yves MARROCCHI Smail MOSTEFAOUI Jean‐Noël ROUZAUD Aurélien THOMEN 《Meteoritics & planetary science》2012,47(1):8-29
Abstract– The insoluble organic matter (IOM) of an unequilibrated enstatite chondrite Sahara (SAH) 97096 has been investigated using a battery of analytical techniques. As the enstatite chondrites are thought to have formed in a reduced environment at higher temperatures than carbonaceous chondrites, they constitute an interesting comparative material to test the heterogeneities of the IOM in the solar system and to constrain the processes that could affect IOM during solar system evolution. The SAH 97096 IOM is found in situ: as submicrometer grains in the network of fine‐grained matrix occurring mostly around chondrules and as inclusions in metallic nodules, where the carbonaceous matter appears to be more graphitized. IOM in these two settings has very similar δ15N and δ13C; this supports the idea that graphitized inclusions in metal could be formed by metal catalytic graphitization of matrix IOM. A detailed comparison between the IOM extracted from a fresh part and a terrestrially weathered part of SAH 97096 shows the similarity between both IOM samples in spite of the high degree of mineral alteration in the latter. The isolated IOM exhibits a heterogeneous polyaromatic macromolecular structure, sometimes highly graphitized, without any detectable free radicals and deuterium‐heterogeneity and having mean H‐ and N‐isotopic compositions in the range of values observed for carbonaceous chondrites. It contains some submicrometer‐sized areas highly enriched in 15N (δ15N up to 1600‰). These observations reinforce the idea that the IOM found in carbonaceous chondrites is a common component widespread in the solar system. Most of the features of SAH 97096 IOM could be explained by the thermal modification of this main component. 相似文献
252.
253.
FRÉDÉRIC AMOUR MARIA MUTTI NICOLAS CHRIST ADRIAN IMMENHAUSER SUSAN M. AGAR GREGORY S. BENSON SARA TOMÁS ROBERT ALWAY LACHEN KABIRI 《Sedimentology》2012,59(4):1158-1189
Each simulation algorithm, including Truncated Gaussian Simulation, Sequential Indicator Simulation and Indicator Kriging is characterized by different operating modes, which variably influence the facies proportion, distribution and association of digital outcrop models, as shown in clastic sediments. A detailed study of carbonate heterogeneity is then crucial to understanding these differences and providing rules for carbonate modelling. Through a continuous exposure of Bajocian carbonate strata, a study window (320 m long, 190 m wide and 30 m thick) was investigated and metre‐scale lithofacies heterogeneity was captured and modelled using closely‐spaced sections. Ten lithofacies, deposited in a shallow‐water carbonate‐dominated ramp, were recognized and their dimensions and associations were documented. Field data, including height sections, were georeferenced and input into the model. Four models were built in the present study. Model A used all sections and Truncated Gaussian Simulation during the stochastic simulation. For the three other models, Model B was generated using Truncated Gaussian Simulation as for Model A, Model C was generated using Sequential Indicator Simulation and Model D was generated using Indicator Kriging. These three additional models were built by removing two out of eight sections from data input. The removal of sections allows direct insights on geological uncertainties at inter‐well spacings by comparing modelled and described sections. Other quantitative and qualitative comparisons were carried out between models to understand the advantages/disadvantages of each algorithm. Model A is used as the base case. Indicator Kriging (Model D) simplifies the facies distribution by assigning continuous geological bodies of the most abundant lithofacies to each zone. Sequential Indicator Simulation (Model C) is confident to conserve facies proportion when geological heterogeneity is complex. The use of trend with Truncated Gaussian Simulation is a powerful tool for modelling well‐defined spatial facies relationships. However, in shallow‐water carbonate, facies can coexist and their association can change through time and space. The present study shows that the scale of modelling (depositional environment or lithofacies) involves specific simulation constraints on shallow‐water carbonate modelling methods. 相似文献
254.
ERIC GALLAWAY ALAN S. TRENHAILE MARIA T. CIOPPA ROBERT G. HATFIELD 《Sedimentology》2012,59(6):1718-1734
A combined field and laboratory study in northern Lake Erie has provided new insights into the origin and dynamics of heavy mineral placer deposits on beaches consisting primarily of non‐magnetic sediment. Work was conducted on the cross‐shore and longshore transport of heavy magnetic minerals using magnetic susceptibility and fluorescent paints to trace the movement, in the field, of samples of magnetic (magnetite) and non‐magnetic (quartz and calcite) grains, respectively. Laboratory experiments examined how the burial of small, dense magnetic minerals is affected by the grain size of the non‐magnetic host material, and how grain burial affects magnetic susceptibility measurements at the surface. The field experiments demonstrated that the magnetic mineral tracers were buried rapidly beneath coarser, non‐magnetic grains under low to moderate wave conditions, and subsequently were unable to move in the longshore or cross‐shore directions. The laboratory experiments showed that the magnetic susceptibility rapidly decreased with the rate and depth of burial of the magnetic minerals, and that magnetic grain burial was most effective beneath coarser rather than finer non‐magnetic sand and, for the latter sediments, under less rather than more energetic conditions. The results imply that magnetic mineral concentrations develop in this area through magnetic grain burial under fairly mild conditions, and subsequent settling, exposure and concentration in the upper swash zone during more energetic periods, when the non‐magnetic grains are eroded. It is probably during these erosional periods, when the magnetic minerals are exposed in fairly homogeneous deposits, that longshore and cross‐shore transport takes place. 相似文献
255.
Siliciclastic intervals in Lower Permian carbonate–siliciclastic cyclothems in western Kansas record climate control on facies progression, deposition and preservation. The 26 000 km2 study area comprises seven marine‐continental (carbonate–siliciclastic) cyclothems caused by glacioeustasy. Core data and a three‐dimensional geological model provide a detailed view of the sub‐surface on a gently sloping ramp. Siliciclastic intervals in the cyclothems are fine‐grained red beds with extensive pedogenic features, indicating a continental origin. Bed geometry (sheet‐like deposits that thin to the east), lateral grading, grain size (very fine‐grained sand to silt) and grain angularity (sub‐angular to angular) suggest that the sediment is loess sourced from the west, probably the Ancestral Rocky Mountains. There is a repeated record of glacial‐cycle‐scale, climate‐controlled cyclicity within siliciclastic intervals that has not been recognized previously. Aeolian silt grain size coarsens upward towards the middle, then fines upward in each siliciclastic interval. When sea‐level was high (interglacial) and carbonate production flourished, aeolian sedimentation nearly ceased, suggesting increased vegetation and rainfall at the source. As sea‐level fell, fine‐grained siliciclastic sediments were deposited under relatively dry, but seasonally wet conditions on an exposed ramp. Laterally graded coarser grained siliciclastic sediments with diagnostic fabrics indicate drier conditions with seasonal rainfall during a continued relative fall in sea‐level. The coarsest siliciclastic sediments were deposited during the lowest sea‐level and driest conditions, but still with sufficient seasonal moisture to allow vegetative cover and bioturbation. Subsequent upward fining is correlated with sedimentological indications of wetter conditions during relative sea‐level rise. Unlike common sequence stratigraphic models that relate siliciclastic sediment accumulation to base‐level rise, continental deposits were preserved because plants and pedogenesis stabilized aeolian sediment. The aggradational landscape formed by this process had several metres of positive relief that reduced accommodation for overlying marine carbonate strata. Thus, this mechanism for continental siliciclastic aggradation has a significant effect on sequence stratigraphic architecture. 相似文献
256.
ROBERT M. HIRSCH 《水文科学杂志》2013,58(4):475-505
Abstract This report demonstrates two techniques for evaluating risks in the operation of a water supply system. Both rely on reconstructed historical streamflow data to develop estimates of the probabilities of certain specific events occurring in the future. These techniques are applied to the Occoquan Reservoir which was experiencing an unprecedented low level of storage in the autumn of 1977. The two techniques are used respectively to evaluate the overall adequacy of the existing reservoir and to evaluate the risks in the 1977 crisis. In the first technique, the general risk analysis model (GRAM), simulations of the reservoir's contents are carried out under a set of assumptions about withdrawal rates and emergency procedures. The results of the GRAM simulation for the Occoquan Reservoir are in the form of estimates of the probabilities that in any year contain emergency procedures will have to be invoked. These estimates are given for a range of rates of withdrawals and for four different stages of emergency actions. Also given are the estimated probabilities of entering emergency conditions in one year given that an emergency has occurred in the previous year. Due to the year-to-year persistence of low flows, these latter (conditional) probabilities are higher than the former (marginal) probabilities. The second technique used is position analysis. In this procedure probability distributions of future storages are estimated under existing storage conditions and an assumed rate of withdrawal from the reservoir. The position analysis which was initialized at the 1 October 1977 conditions indicates that the probability of entering a Stage III emergency (the prohibition of all uses of water non-essential to life, health, and safety) in the autumn of 1977 or winter of 1978 was 10 per cent at that time. With a reduction in water use by 8 million gallons per day, however, this probability would have fallen to 4 per cent. If a long reconstructed historical streamflow record is available to a water supply agency, then the agency will have the capability to undertake its own risk analyses. It can carry out comparisons of alternative operating policies by using techniques such as GRAM. It can also evaluate the short-term risks of different plans of operation during crisis situations by using position analysis. 相似文献
257.
ROBERT ARGENBRIGHT 《Geographical review》2013,103(1):20-36
In this article I examine Moscow's role in the political‐economic space of the Russian Federation. A broad range of data supports the thesis that the capital has become a primate city, one that serves no longer as the command center of a closed system but as the primary node of interconnection between Russia and the rest of the world. The effort to create a larger, polycentric “New Moscow” next to the ancient capital is marked by a tightening of central control, in contrast to governance regimes of European megaregions. Nevertheless, expansion of the capital region very likely will further boost Moscow's dominance over the country. 相似文献
258.
Abstract The debate between training and education in GIS in a university or college setting and whether or not commercial systems should be used in such institutions may be far from resolution, but an indication of the level of interest shown in hands-on, computer-based GIS education using a commercial system is the appearance and growth of the Institute for GIS in Education. The Curriculum Development Toolkit produced by the Institute has involved academic input and evaluation, and contains both generic GIS background information and system-specific computer-based learning materials, used in over 200 academic institutions world-wide. 相似文献
259.
RUDOLPH R. STEA ROBERT J. MOTT 《Boreas: An International Journal of Quaternary Research》2005,34(3):345-362
In the summer of 1999, the Maritimes and Northeast Pipeline Company excavated a 3-m-deep trench across northern Nova Scotia exposing a continuous transect of surficial deposits along a 237-km corridor. A Lateglacial palaeosol with preserved A horizon (peat and wood) buried under 2-10 m of surface till consisted mainly of herbaceous plant material with few large wood fragments. Large pieces of wood from two sites yielded conventional radiocarbon ages of 10.9 14C kyr BP (GSC-6435) and 10.8 14C kyr BP (GSC-6419). Previous to these finds, only a few localities were known to reveal till overlying peat, so the extent of Younger Dryas (YD) glaciers could not be clearly established. Glacial flow lines indicated by fabric and fluting of the YD surface till sheet in northern Nova Scotia and ice-marginal deposits imply an ice cap centred over eastern P.E.I. and the southern Gulf of St. Lawrence. This glacier also dammed a series of glacial lakes against the highland-rimmed west coast of Cape Breton Island. Glaciers developed and advanced during the YD in the uplands and offshore shelf areas from small remnants of Late Wisconsinan ice. Renewed ice growth was enabled by increased precipitation and local cooling in the Gulf of St. Lawrence due to deflection of the jet stream and expanded sea-ice cover in the North Atlantic. The YD may provide an analogy to glacier development in Maritime Canada during the interglacial/glacial transition. 相似文献
260.
DAVID W. KICKLIGHTER MICHELE BRUNO SILKE DÖNGES GERD ESSER MARTIN HEIMANN JOHN HELFRICH FRANK IFT FORTUNAT JOOS JÖRG KADUK GUNDOLF H. KOHLMAIER A. DAVID McGUIRE JERRY M. MELILLO ROBERT MEYER BERRIEN MOORE III REAS NADLER I. COLIN PRENTICE WALTER SAUF ANNETTE L. SCHLOSS STEPHEN SITCH UWE WITTENBERG GUDRUN WÜRTH 《Tellus. Series B, Chemical and physical meteorology》1999,51(2):343-366