Galaxy groups at 0.3 ≤z≤ 0.55 – II. Evolution to z∼ 0

We compare deep Magellan spectroscopy of 26 groups at  0.3 ≤ z ≤ 0.55  , selected from the Canadian Network for Observational Cosmology 2 field survey, with a large sample of nearby groups from the 2PIGG catalogue. We find that the fraction of group galaxies with significant [O  ii ]λ3727 emission (≥5 Å) increases strongly with redshift, from ∼29 per cent in 2dFGRS to ∼58 per cent in CNOC2, for all galaxies brighter than  ∼ M _*+ 1.75  . This trend is parallel to the evolution of field galaxies, where the equivalent fraction of emission-line galaxies increases from ∼53 to ∼75 per cent. The fraction of emission-line galaxies in groups is lower than in the field, across the full redshift range, indicating that the history of star formation in groups is influenced by their environment. We show that the evolution required to explain the data is inconsistent with a quiescent model of galaxy evolution; instead, discrete events in which galaxies cease forming stars (truncation events) are required. We constrain the probability of truncation ( P _trunc) and find that a high value is required in a simple evolutionary scenario neglecting galaxy mergers  ( P _trunc≳ 0.3 Gyr⁻¹)  . However, without assuming significant density evolution, P _trunc is not required to be larger in groups than in the field, suggesting that the environmental dependence of star formation was embedded at redshifts   z ≳ 0.45  .     

Comparison of the structures of humic acids from marine sediments and degraded field diatoms by 13C- and 1H-NMR spectroscopy

Humic acids isolated from marine sediments of the Peru continental shelf and from a degraded field diatom population dominated by the diatoms Skeletonema costatum, Nitzschia seviata and Thalassiosira sp. were characterized on the basis of infrared spectra and ¹³C- and proton-NMR spectra. Aliphatic structures were found to constitute the major fraction of humic acids and they appear to be highly branched. Carbohydrates and to a lesser extent aromatic materials, carbonyl-, ether-, alcohol- and amino groups are important contributors to the structure of marine humic acids. A close relationship was observed between the chemical structure of the sedimentary humic acid and the plankton humic acid.     

The effect of low temperature on Antarctic endolithic green algae

Laboratory experiments show that undercooling to about -5 degrees C occurs in colonized Beacon sandstones of the Ross Desert, Antarctica. High-frequency temperature oscillations between 5 degrees C and -5 degrees C or -10 degrees C (which occur in nature on the rock surface) did not damage Hemichloris antarctica. In a cryomicroscope, H. antarctica appeared to be undamaged after slow or rapid cooling to -50 degrees C. 14CO2 incorporation after freezing to -20 degrees C was unaffected in H. antarctica or in Trebouxia sp. but slightly depressed in Stichococcus sp. (isolated from a less extreme Antarctic habitat). These results suggest that the freezing regime in the Antarctic desert is not injurious to endolithic algae. It is likely that the freezing-point depression inside the rock makes available liquid water for metabolic activity at subzero temperatures. Freezing may occur more frequently on the rock surface and contribute to the abiotic nature of the surface.     

Rapid transport of anthropogenic lead through soils in southeast Missouri

To investigate Pb transport and cycling, soils from the forest floor and cores from White Oaks (Quercus alba L.) were collected near a Pb smelter in SE Missouri at varying depths from the surface and varying distances. Lead concentrations in soil samples at the surface drop dramatically with distance from approximately 1500 mg/kg at less than 2 km from the smelter to around 100 mg/kg at localities greater than 2 km from the smelter. Lead contents in tree rings are below 0.5 mg/kg in samples dated prior to 1970, and rapidly increase in 1975–1990 samples. Isotopic compositions of soils and tree rings exhibit systematic variations of Pb isotopic compositions with depth and tree ring age. Distinguishable isotopic signatures for Pb sources allowed quantification of the contribution of smelter Pb to the soils. At depths where Pb concentrations decreased and approached constant values (10–25 cm, 10–30 mg/kg), 50–90%, 40–50% and 10–50% of the Pb could be derived from the smelter for the samples at locations less than 2, 2–4 and over 4 km from the smelter, respectively. The remaining portion was attributable to automobile emission and bedrock sources. Because the smelter operated from 1963 to 2003 and samples were collected in 1999, it is estimated that smelter Pb infiltrates at rates of 1 cm/yr (30 cm in 30 yr). At distances less than 1.5 km from the smelter, even though Pb concentrations become asymptotic at a depth of 30 cm, isotopic evidence suggests that Pb has migrated below this depth, presumably through exchange with naturally occurring Pb in the soil matrix. This implies that soils heavily polluted by Pb can exceed their Pb carrying capacity, which could have potential impacts on shallow groundwater systems and risk further exposure to human and ecological receptors.     

On counting the number of data pairs for semivariogram estimation

In planning spatial sampling studies for the purpose of estimating the semivariogram, the number of data pairs separated by a given distance is sometimes used as a comparative index of the precision which can be expected from a given sampling design. Because spatial data are correlated, this index can be unreliable. An alternative index which partially corrects for this correlation, themaximum equivalent uncorrelated pairs, is proposed for comparing spatial designs. The index is developed under the assumption that the underlying stochastic process is Gaussian and is appropriate when the (population) semivariogram is to be estimated by the sample semivariogram.     

Geology and genesis of the Toongi rare metal (Zr,Hf, Nb,Ta, Y and REE) deposit,NSW, Australia,and implications for rare metal mineralization in peralkaline igneous rocks

The Toongi Deposit, located in central NSW, Australia, hosts significant resources of Zr, Hf, Nb, Ta, Y and REE within a small (ca. 0.3 km²), rapidly cooled trachyte laccolith. Toongi is part of regional Late Triassic to Jurassic alkaline magmatic field, but is distinguished from the other igneous bodies by its peralkaline composition and economically significant rare metal content that is homogenously distributed throughout the trachyte body. The primary ore minerals are evenly dispersed throughout the rock and include lueshite/natroniobite and complex Na–Fe–Zr–Nb–Y–REE silicate minerals dominated by a eudialyte group mineral (EGM). The EGM occurs in a unique textural setting in the rock, commonly forming spheroidal or irregular-shaped globules, herein called “snowballs”, within the rock matrix. The snowballs are often protruded by aegirine and feldspar phenocrysts and contain swarms of fine aegirine and feldspar grains that often form spiral or swirling patterns within the snowball. Secondary ore minerals include REE carbonates, Y milarite, catapleiite and gaidonnayite that fill fractures and vesicles in the rock. Based on bulk-rock geochemical and Nd isotope data, and thermodynamic modelling of magma fractionation, the alkaline rocks of the region are interpreted to represent extrusive to hyperbyssal products of mantle-derived magma that ponded at mid-crustal levels (ca. 0.3 GPa) and underwent extensive fractionation under low-oxygen fugacity conditions. The high Na₂O, peralkaline nature of the Toongi Deposit trachyte developed via extensive fractionation of an alkali olivine basalt parental magma initially in the mid-crust and subsequently at shallow levels (ca. 0.1 GPa). This extended fractionation under low fO₂ and relatively low H₂O-activity conditions limited volatile release and allowed build-up of rare metal contents to ore grades. We speculate that the ore minerals may have originally formed from rare metal-rich sodic-silicate melt that formed immiscible globules (subsequently crystallized to EGM) in the magma shortly before emplacement and rapid cooling. Subsequent hydrothermal alteration caused relatively limited and localized remobilization of some ore metals into fractures and vesicles in the rock.     

EPR measurement of the effect of glass composition on the oxidation states of europium

The techniques of electron paramagnetic resonance (EPR) were used to measure the concentration ratio of Eu²⁺ to Eu³⁺ in quenched silicate liquids as a function of their compositions. The compositional end members were CaAl₂Si₂O₈ and either MSiO₃ or M₂Si0₄, M = Mg, (Ca_0.5, Mg_0.5), and Ca. All of the liquids were quenched from 1650 ± 25°C, 10^?6.9±0.6 atm of oxygen, and 10^?6.1±0.6 atm total pressure. For a particular choice of M, the ratio of Eu²⁺ to Eu³⁺ increased as much as a factor of 24 with increasing atomic ratio (Al + Si)/(O); for a constant value of (Al + Si)/(O), the ratio of Eu²⁺ to Eu³⁺ increased in the order Mg > (Ca_0.5,Mg_0.5) >Ca. In order to interpret the compositional dependence of the redox equilibrium of Eu in a systematic manner, the concept of a solvent coefficient was introduced.     

Viking 1 Lander on the surface of mars: Revised location

Late in 1977, the periapsis altitude of the Viking Orbiters was lowered from 1500 to 300 km. The higher resolution of pictures taken at the lower altitude (8 m/pixel) permitted a more accurate determination of the location of the Viking 1 Lander by correlating topographic features seen in the new pictures with the same features in lander pictures. The position of the lander on Viking Orbiter picture 452B11 (NGF Rectilinear) is line 293, sample 1099. This location of the Viking 1 Lander has been used in a revision of the control net of Mars (M.E. Davies, F.Y. Katayama, and J.A. Roth, R2309 NASA, The Rand Corp., Feb. 1978). The new areographic coordinates of the lander are lat 22.483° N and long 47.968° W. The new location is estimated to be accurate to within 50 m.