Studying of liquid thermolysis products of various types of immature kerogen in sedimentary lacustrine rocks from the valjevo-Mionica basin,Serbia, and the effect of Pt<Superscript>4+</Superscript> and Ru<Superscript>3+</Superscript> ions on their yield and the hydrocarbon composition

Liquid thermolysis products of various types of immature kerogen from sedimentary lacustrine rocks from the Valjevo-Mionica basin in Serbia were studied to evaluate the generation potential of kerogen contained in the organic matter (OM) of the rocks, determine the composition of the biomarkers and alkylaromatics in the liquid thermolysis products, and elucidate the effect of Pt⁴⁺ and Ru³⁺ ions (which were added in the form of inorganic salts) on the yield and hydrocarbon composition of the liquid thermolysis products. For this purpose, representative bitumen-free samples A and B of the sedimentary rocks were subjected to thermolysis under various conditions. Rock A contains high amount of immature organic matter, which is dominated by kerogen type I/II and was generated under strongly reduced sedimentation conditions at a high salinity. Sample B is poorer in immature OM than sample A, and the OM of the former contains kerogen type II/III and was generated predominantly in a reduced environment. The content of the liquid products and the concentrations of hydrocarbons obtained in the course of thermolysis of bitumen-free sample A and the typical oil distribution of the biomarkers and alkylaromatics in the thermolysis products confirm a high generation potential of OM in this rock. In all of our experiments on the thermolysis of bitumen-free sample B, the yield of liquid products and hydrocarbons is low. According to the kerogen type, the thermolysis of this rock generates much gases. The Pt⁴⁺ and Ru³⁺ ions (added in the form of simple inorganic salts) increased the yield of liquid (kerogen type I/II) and gaseous (kerogen type II/III) products. During the thermolysis of various type of immature kerogen in the lacustrine sedimentary rocks at a temperature of 400°C, the OM attained maturation corresponding to the early catagenesis level. Saturated biomarkers and alkylaomatics in the thermolysis products of both samples display typical oil distributions. The type of the source OM most strongly affects the composition of n-alkanes and alkylnaphthalenes. The metal ions used in this research served as catalysts for the methylation process during the thermolysis of immature kerogen, regardless of its type. The effect of the Pt⁴⁺ and Ru³⁺ ions on other transformations of the hydrocarbons, for example, the destruction of high-molecular n-alkanes to low-molecular ones and on isomerization reactions in molecules of polycyclic biomarkers and alkylaromatics to thermodynamically more stable isomers in the thermolysis products is controlled, first of all, by the type of the source OM.     

A possible active galactic nucleus in M82?

MERLIN and VLA observations of the galaxy M82 have detected a jet-like feature emanating from one of the compact sources, 44.01+59.6. The proximity of this source to the dynamical centre of M82 led us to suspect that it could be a weak active nucleus rather than an SNR. We imaged this source using the EVN at 15 mas and although it shows a compact shell-like structure which could be consistent with an SNR, we note that the EVN image shows a bright region within the source which is elongated along the jet direction. There are distinct similarities between this source and the Sgr A complex at the centre of our own Galaxy which contains the compact AGN, Sgr A^*.     

Two strong radio bursts at high and medium Galactic latitude

The Nasu Observatory, which is composed of eight 20 m elements, was constructed for observing radio transients over a wide field at 1400 MHz. We report on two radio transients detected in consecutive drift scanning observations at declination 32° over a period of about two months. One of the two transients, WJN J1039+3200, appeared at =10^h39^m40^s±10^s, δ=32°±0.4° on March 4, 2005, and the other one, WJN J0645+3200, appeared at =06^h45^m25^s±10^s, δ=32°±0.4° on March 24, 2005. Both exhibited flux densities in excess of 1 Jy, and the burst durations were up to two days. Since there are few examples of radio transients outside the Galactic plane, these are very important observations. We have previously reported on four radio transients with features that look like the two transients detected this time. Of these six WJN transients in total, five had a duration of up to two days, and one up to three days. Four of the transients were detected at high Galactic latitude of b > 30°. Counterparts of the six WJN transients included X-ray sources in four events and had a consistency of 66%. The consistency of γ-ray, PGC Galaxy, NVSS, and FIRST sources was concentrated at about 50%. We were not able to find any special features in the counterparts. The distribution was verified by making a log N–log S plot using data for the four previously detected transients and the new ones. As a result, the distribution of the radio transients that we observed might have an isotropic distribution not dependent on Galactic longitude and Galactic latitude. The detection probability was calculated based on the assumption of an isotropic distribution. The 2σ upper probability limit for detection of transients of 1000 mJy or more is 0.0049 [deg⁻² yr⁻¹]. We cannot yet identify these two radio transients, because their features are different from any radio bursts observed in the past.     

The possiblity of detection of ultracool dwarfs with the UKIRT Infrared Deep Sky Survey

We present predictions for the numbers of ultracool dwarfs in the Galactic disc population that could be detected by the WFCAM/UKIDSS Large Area Survey and Ultra Deep Survey. Simulated samples of objects are created with masses and ages drawn from different mass functions and birthrates. Each object is then given absolute magnitudes in different passbands based on empirically derived bolometric correction versus effective temperature relationships (or model predictions for Y dwarfs). These are then combined with simulated space positions, velocities and photometric errors to yield observables such as apparent magnitudes and proper motions. Such observables are then passed through the survey selection mechanism to yield histograms in colour. This technique also produces predictions for the proper motion histograms for ultracool dwarfs and estimated numbers for the as yet undetected Y dwarfs. Finally, it is shown that these techniques could be used to constrain the ultra-low-mass mass function and birthrate of the Galactic disc population.     

Simulation of torsional shear test results with neuro-fuzzy control system

In the first part of this study, a series of stress-controlled hollow cylinder cyclic torsional triaxial shear tests were conducted on loose to medium dense saturated samples of clean Toyoura sand to investigate its liquefaction behavior. A uniform cyclic sinusoidal loading at a 0.1 Hz frequency was applied to air-pluviated samples where confining pressure and relative density was varied. Cyclic shear stress–strain changes, the number of cycles to reach liquefaction and pore pressure variations were recorded. Results indicate that the liquefaction resistances of uniform sands are significantly affected by the method of sample preparation and initial conditions.     

Evaluation of Estrogenic Activity and Measurement of EDCs in Wastewater Treatment Plants

1IntroductionDuringthe past several years,concern hasincreasedover the potential pollution of watershed by estrogeniccompounds,including steroidal hormones fromhumanand ani mal sources.Effluents from wastewater treat-ment plants are sources of endocrine-d…     

Interpolation and extrapolation of hydrodynamic coefficients

The solution to the problem of calculating the hydrodynamic forces on multiple floating bodies is summarised. The complex coefficients which characterise the forces at each frequency of oscillation are expensive to compute; interpolation of intermediate values and extrapolation to high frequencies appear difficult since the coefficients seem to vary arbitrarily with frequency. Interpolation and extrapolation schemes based on a novel representation of the coefficients are proposed and tested. The excellent numerical results indicate that the values of the coefficients at a few frequency points can characterise the hydrodynamics at all frequencies. These techniques can save economically significant amounts of computer time and permit investigations which would otherwise be prohibitively expensive.     

Light outburst of a compact galaxy

In a field near M3 photographed in U,B,V from 1963 to 1969 one of 750 compact galaxies shows a brightening of 1 mag in B during 1966/67.     

Structure of the 5-minute solar oscillations 1976–1980

The discrete structure in the 5 min velocity oscillations of the solar surface has been confirmed by a re-analysis of data obtained between 1976 and 1979, and in addition a preliminary analysis of 1980 data show excellent consistency of the determined frequencies over the five year period. It is further shown that atmospheric transparency, as measured by the power in the solar intensity fluctuations, shows no correlation with the measured amplitude of the velocity fluctuations, over 2 orders of magnitude.Proceedings of the 14th ESLAB Symposium on Physics of Solar Variations, 16–19 September 1980, Scheveningen, The Netherlands.