Investigation of ammonia removal from polluted waters by Clinoptilolite zeolite

Ammonia nitrogen compounds in the wastewaters and effluents have harmful effects on water resources. Ion exchange with zeolites is a separation process for ammonia removal from effluents. The objective of this research was to study the efficiency of an ammonia removal and the factor affecting to this process. The Clinoptilolite was obtained from Semnan mines at the north part of Iran. The samples were grounded and sieved based on the U.S. standard mesh number 20, 30, 40 and conditioned by ammonia sulfate and sodium chloride solutions. The characteristics of samples for ammonia removal and the selectivity sequence for adsorbing interfering cations were then determined. Results shown that the average ion exchange capacity of zeolite in batch and continuous systems were 6.65–16 and 16.31–19.5 mg NH₄ ⁺ /g zeolite weight, respectively. In study on the zeolite for selective cations showed the ranking of K⁺, NH₄ ⁺, Na⁺, Ca²⁺ and Mg²⁺ respectively. Results indicated that high level of regeneration (95–98%) might be achieved with NaCl solution. Based on the results, Clinoptilolite may be effective applied in wastewater treatment, both from technical and economical aspects.     

Mineral inclusions in diamonds from the Sputnik kimberlite pipe, Yakutia

The Sputnik kimberlite pipe is a small “satellite” of the larger Mir pipe in central Yakutia (Sakha), Russia. Study of 38 large diamonds (0.7-4.9 carats) showed that nine contain inclusions of the eclogitic paragenesis, while the remainder contain inclusions of the peridotitic paragenesis, or of uncertain paragenesis. The peridotitic inclusion suite comprises olivine, enstatite, Cr-diopside, chromite, Cr-pyrope garnet (both lherzolitic and harzburgitic), ilmenite, Ni-rich sulfide and a Ti-Cr-Fe-Mg-Sr-K phase of the lindsleyite-mathiasite (LIMA) series. The eclogitic inclusion suite comprises omphacite, garnet, Ni-poor sulfide, phlogopite and rutile. Peridotitic ilmenite inclusions have high Mg, Cr and Ni contents and high Nb/Zr ratios; they may be related to metasomatic ilmenites known from peridotite xenoliths in kimberlite. Eclogitic phlogopite is intergrown with omphacite, coexists with garnet, and has an unusually high TiO₂ content. Comparison with inclusions in diamonds from Mir shows general similarities, but differences in details of trace-element patterns. Large compositional variations among inclusions of one phase (olivine, garnet, chromite) within single diamonds indicate that the chemical environment of diamond crystallisation changed rapidly relative to diamond growth rates in many cases. P-T conditions of formation were calculated from multiphase inclusions and from trace element geothermobarometry of single inclusions. The geotherm at the time of diamond formation was near a 35 mW/m² conductive model; that is indistinguishable from the Paleozoic geotherm derived by studies of xenoliths and concentrate minerals from Mir. A range of Ni temperatures between garnet inclusions in single diamonds from both Mir and Sputnik suggests that many of the diamonds grew during thermal events affecting a relatively narrow depth range of the lithosphere, within the diamond stability field. The minor differences between inclusions in Mir and Sputnik may reflect lateral heterogeneity in the upper mantle.     

On error bounds and initialization in satellite orbit theories

The order of magnitude of the error is investigated for a first-order von Zeipel theory of satellite orbits in an axisymmetric force field, i.e., first-order long period and short-period effects are included along with second order secular rates. The treatment is valid for zero eccentricity and/or inclination. In the case where initial position and velocity vectors are known, the in-track position error over time intervals of order 1/J ₂ is kept at 0(J ₂ ²), like the other position errors and velocity errors, by calibration of the mean motion with the aid of the energy integral. The results are specifically applicable to accuracy comparisons of the Brouwer orbit prediction method with numerical integration. A modified calibration is presented for the general asymmetric force field which includes tesseral harmonics.     

Energetic solar electrons in the interplanetary medium

ISEE-3 measurements extending down to 2 keV energy have provided a new perspective on energetic solar electrons in the interplanetary medium. Impulsive solar electron events are observed, on average, several times a day near solar maximum, with 40% detected only below 15 keV. The electron energy spectra have a nearly power-law shape extending smoothly down to 2 keV, indicating that the origin of these events is high in the corona. These coronal flare-like events often produced ³He-rich particle events.In large solar flares which accelerate electrons and ions to relativistic energies, the electron spectrum appears to be modified by a second acceleration which results in a double power-law shape above 10 keV with a break near 100 keV and flattening from 10–100 keV. Large flares result in long-lived (many days) streams of outflowing electrons which dominate the interplanetary fluxes at low energies. Even in the absence of solar activity, significant fluxes of low energy electrons flow out from the Sun.Solar type-III radio bursts are produced by the escaping 2–10² keV electrons through a beam-plasma instability. The detailed ISEE-3 measurements show that electron plasma waves are generated by the bump-on-tail distribution created by the faster electrons running ahead of the slower ones. These plasma waves appear to be converted into radio emission by nonlinear wave-wave interactions.     

Variations of global water exchange under changing climate

Variations of Global Sea Level are considered as an integral indicator of global water exchange. The results of analysis of Global Sea Level variations over past 140 years are estimated from tide-gauge data. Level trend in the XX century is shown to amount to 1.8 mm/year. The contributions of various factors to the formation of Global Sea Level trend are discussed. The interannual variations of evaporation and precipitation over the World Ocean are estimated for the first time, and their difference is shown to significantly contribute to the level trend, especially in the recent decade. Moreover, the significant rise in Global Sea Level is associated with the thermosteric level variations and, possibly, with the bottom melting of Antarctic shelf glaciers.     

An 40Ar/39Ar study of a polymetamorphic complex in the Arunta Block,Central Australia

A polymetamorphic complex in the Arunta Block, Central Australia, which has undergone metasomatism involving introduction of Rb and loss of Sr has been investigated by ⁴⁰Ar/ ³⁹Ar step and total-degassing techniques in an attempt to date five metamorphic events (M1–M5) identified microstructurally. The complex isotopic data and apparent age spectra obtained have been interpreted in the light of constraints provided by an associated tectonometamorphic study, together with independent geochronological controls from the immediate study area and elsewhere in the Arunta Block. This has led to the delineation of ages of 1,780–1,820 M.y. for M1, 1,690–1,720 M.y. for M2, 1,450–1,500 M.y. for M3, 1,030–1,060 M.y. for M4 and 370–510 for M5. The polyphase M5 event is correlated with the Alice Springs Orogeny, previously accorded younger age limits of 330–370 M.y. The latter are interpreted to reflect closure of mica K/Ar systems as uplift continued subsequent to the close of the event, possibly culminating in minor high-level brittle deformation and the development of pseudotachylytes in the study area.Apparent age spectra recorded in this study do not all conform with generally accepted patterns of behaviour of mineral systems which have undergone polythermal histories. Two hornblendes have survived subsequent high temperature metasomatic reheating without loss of argon or resetting of their ages. Their resistance to argon loss may be attributable to low water contents, due to their growth under anhydrous granulite facies conditions, and may reflect a relationship between argon loss from hornblende and the water content of hornblende, which decreases with increasing metamorphic grade (Kostyuk and Sobolev 1969). Other samples display false plateaux in their apparent age spectra and in three cases the spectra are indistinguishable from those of undisturbed spectra.The age data recorded in this study suggest that during basement reactivation loss of argon is mainly confined to the vicinity of shear zones, implying that diffusion of argon from minerals in the deep crust may be dependent more on deformation than on reheating. However, thermal activity may also be associated with active shear zones, through the medium of superheated fluids streaming up the shear zones from below. The wide spread of K/Ar and ⁴⁰Ar/³⁹Ar ages (330–510 M.y.), recorded for the Alice Springs Orogeny in the Arunta basement, may reflect such controls.     

A preliminary case study of potential ceramic raw materials in the Aileu area of Timor Leste

The newly independent country of Timor Leste is located in the eastern half of Timor Island (Indonesian archipelago). Geological studies of the country’s mineral resources and extractive activities are practically non-existent. There is evidence of the exploitation of ceramic raw materials at outcrop level and two small brick kilns, nowadays inactive, in the Dili and Aileu areas. Near Aileu, there are light-coloured silt-rich deposits, interpreted as overbank deposits, interbedded with ancient river terraces (post-Pliocene) overlying metamorphic bedrock. These sediments are the subject of this study, which encompassed geological mapping and preliminary characterisation. Tectonically, the area is a graben, preserving alluvium and colluvium deposits. Five channel samples representative of the silt-rich deposits were collected. Semi-quantitative mineralogical analysis shows that the samples are made of illite, quartz and kaolinite clays, with accessory illite/vermiculite interstratified minerals and K-feldspar. The chemical data show agreement with the estimated mineralogical composition. The grain size distribution points to a silt-dominated assemblage. Most samples have a satisfactory extrudability but deficient moulding properties. After firing, the sampled raw materials form a final product with possible ceramic capability for whiteware production.     

澳大利亚的第三纪及第三纪—第四纪过渡期(英文)

第三纪的板块运动驱动着澳大利亚的气候和植被进行演化。广布的湿润森林区是澳大利亚老第三纪的特征。一直到始新世 ,生物多样性都在不断地提高。毫无疑问 ,这是澳大利亚由高南纬区向北部中纬区运移的结果。从始新世到上新世 ,澳大利亚的气候总体上要比现在湿润 ,但降水量季节性变化的增强推动了中新世以后硬叶植物和旱生植物的发展。上新世晚期似乎与第四纪一样 ,都出现过周期性干旱。这种干旱与冰期条件有关 ,至少由南澳大利亚晚第四纪的记录可以认识到这一点 ,澳大利亚的这段历史与东亚的气候变迁是同步发生的。在东亚 ,印—澳板块的运动致使青藏高原抬升 ,从而引发了区内乃至全球气候的巨变。穿越赤道区的季风和信风的环流格局 ,致使新第三纪和第四纪中国与澳大利亚的气候系统的相关性更强。     

Proterozoic–Paleozoic development of the basement of the Central Andes (18–26°S) — a mobile belt of the South American craton

The Late Precambrian–Early Paleozoic metamorphic basement forms a volumetrically important part of the Andean crust. We investigated its evolution in order to subdivide the area between 18 and 26°S into crustal domains by means of petrological and age data (Sm–Nd isochrons, K–Ar). The metamorphic crystallization ages and t_DM ages are not consistent with growth of the Pacific margin north of the Argentine Precordillera by accretion of exotic terranes, but favor a model of a mobile belt of the Pampean Cycle. Peak metamorphic conditions in all scattered outcrop areas between 18 and 26°S are similar and reached the upper amphibolite facies conditions indicated by mineral paragensis and the occurrence of migmatite. Sm–Nd mineral isochrons yielded 525±10, 505±6 and 509±1 Ma for the Chilean Coast Range, the Chilean Precordillera and the Argentine Puna, and 442±9 and 412±18 Ma for the Sierras Pampeanas. Conventional K–Ar cooling age data of amphibole and mica cluster around 400 Ma, but are frequently reset by Late Paleozoic and Jurassic magmatism. Final exhumation of the Early Paleozoic orogen is confirmed by Devonian erosional unconformities. Sm–Nd depleted mantle model ages of felsic rocks from the metamorphic basement range from 1.4 to 2.2 Ga, in northern Chile the average is 1.65±0.16 Ga (1σ; n=12), average t_DM of both gneiss and metabasite in NW Argentina is 1.76±0.4 Ga (1σ; n=22), and the isotopic composition excludes major addition of juvenile mantle derived material during the Early Paleozoic metamorphic and magmatic cycle. These new data indicate a largely similar development of the metamorphic basement south of the Arequipa Massif at 18°S and north of the Argentine Precordillera at 28°S. Variations of metamorphic grade and of ages of peak metamorphism are of local importance. The protolith was derived from Early to Middle Proterozoic cratonic areas, similar to the Proterozoic rocks from the Arequipa Massif, which had undergone Grenvillian metamorphism at ca. 1.0 Ga.