Method of Data Reduction and Uncertainty Estimation for Platinum-Group Element Data Using Inductively Coupled Plasma-Mass Spectrometry

A data reduction method is described for determining platinum-group element (PGE) abundances by inductively coupled plasma-mass spectrometry (ICP-MS) using external calibration or the method of standard addition. Gravimetric measurement of volumes, the analysis of reference materials and the use of procedural blanks were all used to minimise systematic errors. Internal standards were used to correct for instrument drift. A linear least squares regression model was used to calculate concentrations from drift-corrected counts per second (cps). Furthermore, mathematical manipulations also contribute to the uncertainty estimates of a procedure. Typical uncertainty estimate calculations for ICP-MS data manipulations involve: (1) Carrying standard deviations from the raw cps through the data reduction or (2) calculating a standard deviation from multiple final concentration calculations. It is demonstrated that method 2 may underestimate the uncertainty estimate of the calculated data. Methods 1 and 2 do not typically include an uncertainty estimate component from a regression model. As such models contribute to the uncertainty estimates affecting the calculated data, an uncertainty estimate component from the regression must be included in any final error calculations. Confidence intervals are used to account for uncertainty estimates from the regression model. These confidence intervals are simpler to calculate than uncertainty estimates from method 1, for example. The data reduction and uncertainty estimation method described here addresses problems of reporting PGE data from an article in the literature and addresses both precision and accuracy. The method can be applied to any analytical technique where drift corrections or regression models are used.     

Color diversity among Kuiper belt objects: The collisional resurfacing model revisited

A re-evaluation of the collisional resurfacing model based on up-to-date Kuiper belt objects size distribution and a more precise treatment of the cosmic-ray environment at the outer Solar System is presented. The result of the irradiation due to cosmic-rays with different energies altered in a different way the material of the objects, producing, under certain conditions, a thick irradiation mantle. Since the collisional resurfacing model is based in the competition between darkening by cosmic-rays and resurfacing due to impacts, the color of objects in different regions of the belt could vary if the projectile populations in those regions are truncated at a different radius.     

Discovery of lamproites near Vattikod Area, NW margin of the Cuddapah basin, Eastern Dharwar craton, southern India

A cluster of lamproite dykes are located 1 km west of Vattikod village at the NW margin of the Cuddapah basin, Eastern Dharwar craton, southern India, during the pursuit for locating primary diamond source rocks by adapting multifarious applications. These exotic rocks are emplaced along WNW-ESE to NW-SE trending fractures in the granitic rocks belonging to the Peninsular Gneissic Complex. Ten out of twelve lamproites occur near Vattikod village and one each is located in the vicinity of Marepalli and Gundrapalli villages respectively. These lamproites, though highly altered, contain microphenocrysts of altered olivine, clinopyroxene, phlogopite, leucite and sanidine and translucent to opaque, amoeboid shaped patches of glass set in a groundmass rich in carbonate, phlogopite, serpentine, and chlorite. This new cluster of lamproites constitutes a part of the recently discovered Ramadugu lamproite field. The Vattikod and Ramadugu lamproites, together with those from Krishna lamproite field and the Cuddapah basin, constitute, a wide spectrum of ultrapotassic magmatism emplaced in and around the Palaeo-Mesoproterozoic Cuddapah basin in southern India.     

Diagenetic development of unstable and stable magnetization in the St. Bees Sandstone (Triassic) of northern England

Thermal demagnetization of red and drab sandstones from the St. Bees Sandstone shows a wide range of directional stability. After the removal of a metastable secondary magnetization at temperatures up to 300°C red sandstones may show stable or unstable magnetization. Experiments indicate that both the stable and unstable magnetization is carried by coarse haematite particles (specularite).Drab sandstones, which have been subject to reduction and dissolution of haematite are generally unstable but specimens with a stable NRM occur and this must be carried by specularite because the pigment has been removed from these specimens.The stable magnetization is believed to have developed during deposition and early diagenesis by the oxidation of detrital iron oxides. Pole positions correspond to known Triassic poles and there are abundant normal and reversed zones typical of the Lower Triassic.The unstable magnetization of the red sandstones is apparently due to the development of authigenic overgrowths of haematite on the detrital specularites. This phase of authigenesis may have taken place over a long time, and after significant changes in the ambient geomagnetic field resulting in complex magnetizations in individual grains and hence whole rocks.     

Warm frontal structure in association with a rapidly deepening extratropical cyclone

Abstract

The detailed characteristics of a CASPII warm frontal passage are presented in this article. This storm, Intensive Operating Period (IOP) 13 (February 26–27, 1992), was observed in detail with an array of diverse instruments. It has the advantage over earlier freezing precipitation studies of having simultaneous, in situ and remote sensing measurements by aircraft and ground‐based Doppler radar.

The associated precipitation was in the form of banded structures parallel to the front. Within these bands were embedded precipitation cores, some parallel to the band, some perpendicular. The warm front itself was characterized by major perturbations in its kinematic and thermodynamic features. The cores oriented parallel to the front were the result of embedded convection generated, at least in part, by the irregularities in the frontal surface.

The cores oriented perpendicular to the front were closely associated with the 0°C isotherm on the underside of the frontal inversion. Precipitation phase changes played a significant role in the occurrence of wide near 0°C regions, both vertically and horizontally. These regions had a profound influence on the observed precipitation types and led to complex precipitation‐thermodynamic‐dynamic interactions. Instabilities produced by these interactions are seen in wave‐like features observed by the Doppler radar in these regions, both parallel and perpendicular to the frontal zone.     

Rectangular tank surface aerators: scale up criteria and energy conservation

Surface aeration experiments were conducted in two types of rectangular tanks of aspect ratios i.e., length to width ratio (L/W) of 1.5 and 2 and developed simulation equations to correlate the oxygen transfer coefficient, k and power number, P₀ with a parameter governing theoretical power per unit volume X. The parameter X is defined as equal to F^4/3R^1/3, where F and R are impellers’ Froude and Reynolds numbers respectively). Results have shown that the P₀ can not be simulated singularly with either Reynolds number, R or Froude number, F, which results in scale-effects; there appears to be a need to incorporate the effects of both F and R. It was found that P⁰ is uniquely related to X for rectangular aeration tanks of both aspect ratios, however, such relationships are different depending upon the aspect ratios. It has been demonstrated that energy can be saved substantially if the aeration tanks are run at relatively higher input powers. It is also demonstrated that smaller sized tanks are more energy conservative and economical when compared to big sized tanks, while aerating the same volume of water, and at the same time by maintaining a constant input power in all the tanks irrespective of their size.     

Environmental Factors Contributing to the Development and Demise of a Toxic Dinoflagellate (<Emphasis Type="Italic">Karlodinium veneficum</Emphasis>) Bloom in a Shallow,Eutrophic, Lagoonal Estuary

A dense bloom of the ichthyotoxic dinoflagellate Karlodinium veneficum was discovered in the Neuse River Estuary, North Carolina, on 19 October 2006 and was associated with four subsequent fish kills. Microscopic, photopigment, DNA, and toxicological techniques confirmed bloom identity and toxicity. High-resolution spatio-temporal data from ship-board and fixed automated sampling stations provided a unique opportunity to investigate the environmental conditions that initiated, maintained, and terminated the K. veneficum bloom. Bloom initiation and growth were favored by high nutrient availability and reduced dispersal during the period of declining riverine discharge after Tropical Storm Ernesto. K. veneficum out-competed other co-occurring dinoflagellates, perhaps because of the production of karlotoxins that are known to act as grazing deterrents and to facilitate mixotrophic feeding. Once the bloom was established, small-scale hydrodynamic processes, coupled with vertical migration, concentrated cells along a frontal convergence to high densities (>200,000 cells per milliliter). By 26 October 2006, wind mixing and possible nutrient stress disrupted the bloom. Release of cell-bound toxins during the bloom collapse likely accounted for the associated fish kill events where fish were reported as exhibiting typical symptoms of karlotoxin poisoning. The dynamics of this bloom underscore the tight control of harmful algal blooms by meteorological forcing, hydrology, and sediment nutrient input in this shallow lagoonal estuary.     

Catastrophic landslides,glacier behaviour and moraine formation – A view from an active plate margin

The influence of large bedrock landslides (“rock avalanches”) on the behaviour of glaciers is incompletely recognised. Here we present an example from an active tectonic margin in South Island, New Zealand where large earthquakes leave a significant imprint on glacial records. We demonstrate that terminal moraines on the western side of the Southern Alps record both ‘ordinary’ (i.e. climate-driven) and landslide-initiated glacial advances. Following consideration of the processes involved in rock avalanche-initiated moraine construction we suggest ways of determining the nature of the advance that built the terminal moraine. The implications of these observations are important in breaking the conventional linkage of individual terminal moraines with climate forcing.     

Dating of Quaternary Sediments from Western Borneo, Using Optically Stimulated Luminescence

Optically Stimulated Luminescence (OSL) dates from five sites in western Kalimantan are compared with ¹⁴C and thermo-luminescence dates from other sediments in the region. There is now strong evidence that the Old Alluvium of Peninsular Malaysia is of late Pleistocene age and that it can be correlated with the White Sand Complexes of western Borneo. This contrasts with the late Pliocene to mid Pleistocene ages for Old Alluvium, based primarily on stratigraphic deductions, put forward by geoscientists examining the regional tin deposits. This study shows that the upper parts, at least, of the western Borneo White Sand Complexes were deposited mid-way through the last glaciation (76 ka), with extensive terminal Pleistocene re-deposition (11.2-9.8 ka) and at least two gully erosion events during the Holocene (5.8-3.8 ka and 0.48 ka).