Lower Cambrian patch reefs and associated sediments: southern Labrador, Canada

The complex pattern of biological accretion, internal sedimentation, early lithification, and biological destruction, that characterizes modern reefs and many fossil reefs has been recognized in archaeocyathid-rich patch reefs of Lower Cambrian age in the Forteau Formation, southern Labrador. Patch reefs occur as isolated masses or complex associations of many discrete masses of archaeocyathid-rich limestone and skeletal lime sands, surrounded by well-bedded skeletal limestones and shales. Each reef is composed of many loafshaped mounds stacked on top of one another. The limestone of each mound comprises archaeocyathids and Renalcis or Renalcis-like structures in a matrix of argillaceous lime mud rich in sponge spicules, trilobite and salterellid skeletons. Numerous growth cavities roofed by pendant Renalcis-like organisms and Renalcis are partially to completely filled with geopetal sediment indicating that much of the matrix was deposited as internal sediment. Two stages of diagenetic alteration are recognized: (1) syn-depositional, which affected only the reefs, and (2) post-depositional, which affected both reefs and inter-reef sediments. On the sea floor reef sediments were pervasively cemented and fibrous carbonate was precipitated in intraskeletal and growth cavities. These limestones and cements as well as archaeocyathid skeletons, were subsequently bored by endolithic organisms. Later post-depositional subaerial diagenesis resulted first in dissolution of certain skeletons and precipitation of calcite cement above the water table, followed by extensive precipitation of pore-filling calcite below the water table. These carbonate reefs are similar in structure to the basal pioneer accumulations of much younger lower and middle Palaeozoic reefs. They did not develop into massive ‘ecologic’ reefs because archaeocyathids never developed the necessary large, massive, hemispherical skeletons. This occurrence indicates that reefs developed more or less coincident with, and not long after, the appearance of skeletal metazoans in the Lower Cambrian.     

Non-point source pollution in Indian agriculture: Estimation of nitrogen losses from rice crop using remote sensing and GIS

The paper presents a detailed understanding of nitrogenous fertilizer use in Indian agriculture and estimation of seasonal nitrogen loosses from rice crop in Indo-Gangetic plain region, the ‘food bowl’ of the Indian sub-continent. An integrated methodology was developed for quantification of different forms of nitrogen losses from rice crop using remote sensing derived inputs, field data of fertilizer application, collateral data of soil and rainfall and nitrogen loss coefficients derived from published nitrogen dynamics studies. The spatial patterns of nitrogen losses in autumn or ‘kharif’ and spring or ‘rabi’ season rice at 1 × 1 km grid were generated using image processing and GIS. The nitrogen losses through leaching in form of urea-N, ammonium-N (NH₄-N) and nitrate-N (NO₃-N) are dominant over ammonia volatilization loss. The study results indicate that nitrogen loss through leaching in kharif and rabi rice is of the order of 34.9% and 39.8% of the applied nitrogenous fertilizer in the Indo-Gangetic plain region. This study provides a significant insight to the role of nitrogenous fertilizer as a major non-point source pollutant from agriculture.     

Karst groundwater protection in the Kupa River catchment area and sustainable development

One of the most significant water resources in the Republic of Croatia is the catchment area of the Kupa River, located in the region bordering the Republic of Slovenia. About 88% of the total amount of water in this catchment originates in Croatia and just 12% from Slovenia; therefore, the largest part of the catchment area (about 1000 km²) is on the Croatian side of the border. It is a typical karst area of the Dinarides with aquifers characterized by a relatively rapid water exchange, high groundwater flow velocities and aquifers open to human impact from the surface. Consequently, the aquifers are highly vulnerable and at risk. Due to the availability of large quantities of high-quality spring water (about 6 m³/s), the entire area has a strategic importance within the context of any future development strategy pertaining to the western part of Croatia. The catchment area on the Croatian side was investigated using a wide range of research methods that included a classical hydrogeological approach, the detailed hydrologic calculation of water balance to the hydrogeochemical analyses and modelling. The objective was to determine protection zones and protection measures for the whole area. The difficulties are increased due to the fact that the karst catchment area is crossed by major traffic corridors, oil pipelines and a railway and that many settlements and a highly developed wood industry are present. The combination of protecting water resources with adequate prevention measures and necessary remedial activities that should satisfy the very strict requirements necessary for the protection of the karst aquifers while still allowing for present and future human activities is difficult – but not impossible – to achieve. One good example is the present highway with a closed dewatering system and waste water treatment before the water passes into the karst underground system.     

Corundum- and kyanite-bearing anatexites from the Precambrian of tanzania

In the Precambrian near Morogoro (East Tanzania) there are anatectic gneisses which are composed of two different domains: (1) Medium grained gneiss with the assemblage (+ rutile + baddeleyite): albite (ab₉₅an₀₃or₀₂) + muscovite + phlogopite_ss + corundum, and albite (ab₈₈an₀₉or₀₃ + kyanite or sillimanite + phlogopite_ss. (2) Coarse grained nests of corundum and antiperthite with minor albite, muscovite, phlogopite, rutile, baddeleyite, and tourmaline. The bulk composition of the antiperthite id ab₇₅an₀₂or₂₃, the composition of the Na-phase ab₉₅an₀₃or₀₂, that of the K-phase ab₁₃an₀₀or₈₇. Phase relationship of the rock can be modelled in the Na-rich, Si-undersaturated part of the KNASH system. P-T conditions are close to the intersection of the melting curve muscovite_ss + H₂O = corundum + liquid with the kyanite-sillimanite transition, i.e. 7.7 kb/695°C assuming a_H2O = 1.     

Recent progress in estimating uncertainty in geomagnetic field modeling

Abstract

Recent work pertaining to estimating error and accuracies in geomagnetic field modeling is reviewed from a unified viewpoint and illustrated with examples. The formulation of a finite dimensional approximation to the underlying infinite dimensional problem is developed. Central to the formulation is an inner product and norm in the solution space through which a priori information can be brought to bear on the problem. Such information is crucial to estimation of the effects of higher degree fields at the Core-Mantle boundary (CMB) because the behavior of higher degree fields is masked in our measurements by the presence of the field from the Earth's crust. Contributions to the errors in predicting geophysical quantities based on the approximate model are separated into three categories: (1) the usual error from the measurement noise; (2) the error from unmodeled fields, i.e. from sources in the crust, ionosphere, etc.; and (3) the error from truncating to a finite dimensioned solution and prediction space. The combination of the first two is termed low degree error while the third is referred to as truncation error.

The error analysis problem consists of “characterizing” the difference δz = z—z, where z is some quantity depending on the magnetic field and z is the estimate of z resulting from our model. Two approaches are discussed. The method of Confidence Set Inference (CSI) seeks to find an upper bound for |z—?|. Statistical methods, i.e. Bayesian or Stochastic Estimation, seek to estimate E(δz² ), where E is the expectation value. Estimation of both the truncation error and low degree error is discussed for both approaches. Expressions are found for an upper bound for |δz| and for E(δz² ). Of particular interest is the computation of the radial field, B., at the CMB for which error estimates are made as examples of the methods. Estimated accuracies of the Gauss coefficients are given for the various methods. In general, the lowest error estimates result when the greatest amount of a priori information is available and, indeed, the estimates for truncation error are completely dependent upon the nature of the a priori information assumed. For the most conservative approach, the error in computing point values of B_r at the CMB is unbounded and one must be content with, e.g., averages over some large area. The various assumptions about a priori information are reviewed. Work is needed to extend and develop this information. In particular, information regarding the truncated fields is needed to determine if the pessimistic bounds presently available are realistic or if there is a real physical basis for lower error estimates. Characterization of crustal fields for degree greater than 50 is needed as is more rigorous characterization of the external fields.     

A summary of sulfur dioxide emission rate measuremnts from Guatemalan volcanoes

Measurements of the sulfur dioxide (SO₂) emission rate from three Guatemalan volcanoes provide data which are consistent with theoretical and laboratory studies of eruptive and shallow magma chamber processes. In particular, unerupted magma makes a major contribution to the measured SO₂ emission rates at Santiaguito, a continuously erupting dacitic volcanic dome. Varying shallow magma convection rates can explain the variations in SO₂ emission rates at Santiaguito. At Fuego, a basaltic volcano currently in repose, SO₂ emission rate measurements are consistent with a high level magma body that is crystallizing and releasing volatiles. At Pacaya, a continuously erupting basaltic volcano, recent SO₂ emission rate measurements support laboratory simulation studies of strombolian eruptions; these studies indicate that the majority of gas escapes during eruptions and little gas escapes between eruptions.Average SO₂ emission rates over the last 20 years for Santiaguito, Fuego and Pacaya are 80, 160 and 260 Mg/d, respectively. On a global scale, these three volcanoes account for 1% of the annual global volcanic output of SO₂. Santiaguito and Pacaya, together, emit 6% of the total annual SO₂ emitted by continuously erupting volcanoes.Even though SO₂ measurements at these volcanoes have been made infrequently and by different investigators, the collective data help to establish a useful baseline by which to judge future changes. A more complete record of SO₂ emission rates from these volcanoes could lead to a better understanding of their eruption mechanisms and reduce the impact of their future eruptions on Guatemalan society.     

Stochastic finite fault modelling of M w 4.8 earthquake in Kachchh, Gujarat, India

The modified stochastic finite fault modelling technique based on dynamic corner frequency has been used to simulate the strong ground motions of M _w 4.8 earthquake in the Kachchh region of Gujarat, India. The accelerograms have been simulated for 14 strong motion accelerographs sites (11 sites in Kachchh and three sites in Saurashtra) where the earthquake has been recorded. The region-specific source, attenuation and generic site parameters, which are derived from recordings of small to moderate earthquakes, have been used for the simulations. The main characteristics of the simulated accelerograms, comprised of peak ground acceleration (pga), duration, Fourier and response spectra, predominant period, are in general in good agreement with those of observed ones at most of the sites. The rate of decay of simulated pga values with distance is found to be similar with that of observed values. The successful modelling of the empirical accelerograms indicates that the method can be used to prepare wide range of scenarios based on simulation which provide the information useful for evaluating and mitigating the seismic hazard in the region.     

Sediment pathways and transport rates through a tide-dominated entrance, Rangaunu Harbour, New Zealand

Bed load sediment traps were deployed at two sections across channels in Rangaunu Harbour entrance. Traps were inspected and emptied by divers at hourly intervals through both spring and neap tidal cycles for a total of 292 trap deployments. Current velocities were measured simultaneously with the trap inspections. Transport is concentrated in sandy megaripple fields on the channel banks and sub-tidal platforms flanking the channels. There, transport is almost continuous throughout the tidal cycle, increasing with flow velocity but lagging by approximately one hour. The channel floors are lined with shell-gravel lag across which bedload transport rates are low and discontinuous. Tidal asymmetry produces a net seaward transport through the channel troughs and a net landward transport across the channel banks and flanking sub-tidal platforms. Sediment leaving the harbour recirculates in anticlockwise gyres across the ebb-tide delta to re-enter the harbou and maintain the supply of sand to the megaripple field. Transport during spring tides is typically 25–30 times that during neaps. Predictions of transport rates, from a method developed by Black & Healy utilizing the Yalin bedload equation, produced transport rates similar to the traps over sand beds. Transport over shell lag surfaces appears independent of near-bed velocity and more dependent on the passage of ribbons of sand across the lag surface.