Volcanogenic massive sulfide deposits of ophiolite associations

Volcanogenic massive sulfide deposits in ophiolite complexes are usually attributed to the Cyprus type. They associate with basaltic volcanics that are formed in mid-ocean or back-arc spreading centers and much less frequently in intra-plate settings. The deposits are characterized by copper or copper-zinc ores that are enriched in Ni, Co, and in places Mn and As, but are very poor in Pb and demonstrate a low to moderate content of Ag and Au. Typically, the deposits are low to very low in ore and metal reserves. Cyprus-type deposits were irregularly distributed during geological history. The most ancient of them were formed in the Neoproterozoic, while the bulk of the deposits are Ordovician or Cretaceous in age. Their possible Paleoproterozoic analogues can be found in the Svecofennian belt (Outokumpu ore district), while modern ones are confined to the Explorer and Endeavour Ridges and southern segment of the Juan de Fuca Ridge.     

Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.     

Chironomids as indicators of climate change: a 100‐lake training set from a subarctic region of northern Sweden (Lapland)

Multivariate numerical analyses (DCA, CCA) were used to study the distribution of chironomids from surface sediments of 100 lakes spanning broad ecoclimatic conditions in northern Swedish Lapland. The study sites range from boreal forest to alpine tundra and are located in a region of relatively low human impact. Of the 19 environmental variables measured, ordination by CCA identified mean July air temperature as one of the most significant variables explaining the distribution and the abundance of chironomids. Lossonignition (LOI), maximum lake depth and mean January air temperature also accounted for significant variation in chironomid assemblages. A quantitative transfer function was created to estimate mean July air temperature from sedimentary chironomid assemblages using weightedaveraging partial least squares regression (WAPLS). The coefficient of determination was relatively high (r² = 0.65) with root mean squared error of prediction (RMSEP, based on jack-knifing) of 1.13 °C and maximum bias of 2.1 °C, indicating that chironomids can provide useful quantitative estimates of past changes in mean July air temperature. The paper focuses mainly on the relationship between chironomid composition and July air temperature, but the relationship to LOI and depth are also discussed.     

Small-scale heterogeneities below the Gräfenberg array, Germany from seismic wavefield fluctuations of Hindu Kush events

Small-scale elastic heterogeneities (<5  km) are found in the upper lithosphere underneath the Gräfenberg array, southeast Germany. The results are based on the analysis of broadband recordings of 17 intermediate-depth (201–272  km) events from the Hindu Kush region. The wavefront of the first P arrival and the following 40  s coda are separated into coherent and incoherent (scattered) parts in the frequency range from 0.05 to 5  Hz. The frequency-dependent intensities of the mean and fluctuation wavefields are used to describe the scattering characteristics of the lithosphere underneath the receivers. It is possible to discriminate a weak-fluctuation regime of the wavefield in the frequency range below approximately 1.5–2.5  Hz and a strong-fluctuation regime starting at 2.0–2.5  Hz and continuing to higher frequencies. In order to explain the observed wavefield fluctuations, an approach with seismic scattering at random media-type structures is proposed. The preferred model contains heterogeneities with 3–7 per cent perturbations in seismic velocity and correlation lengths of 0.6–4.8  km in the crust. This is compatible with models from active seismic experiments. Scattering in the lithospheric mantle is not required, but cannot be excluded at weak velocity contrasts (<3 per cent).     

P- and S-wave anisotropy of a synthetic sandstone with controlled crack geometryl1

A method is reported for the production of synthetic porous sandstones containing cracks of known dimensions and geometry with respect to the matrix. A synthetic sandstone was manufactured from Sand cemented with an epoxy glue. The cracks of known geometry were introduced into the material in the manufacturing stage, by emplacing thin metallic discs in the Sand-epoxy matrix. These discs were chemically leached out of the consolidated porous sandstone. Acoustic anisotropy. and shear-wave splitting were observed in the synthetic sandstones. For the dry sample the observed angular dependence of the P- and S- wave velocities (at 100 kHz) compares well, qualitatively, with the theoretical models of Hudson and of Thomsen. Quantitatively, however, the experimental data fits Hudson's model better. For the case of a saturated sample the experimental results are in excellent agreement with Thomsen's model. Hudson's model, on the other hand, predicts a different angular dependence for P-waves. This demonstrates that the concept of fluid transfer between cracks and the ambient porosity can be a significant process. The results reported here are from the first successful experiment in which the theoretical models were tested on a porous material containing a known crack geometry.     

Distinct metamorphic evolution of alternating silica-saturated and silica-deficient microdomains within garnet in ultrahigh-temperature granulites: An example from Sri Lanka

Here we report the occurrence of garnet porphyroblasts that have overgrown alternating silica-saturated and silica deficient microdomains via different mineral reactions. The samples were collected from ultrahigh-temperature (UHT) metapelites in the Highland Complex, Sri Lanka. In some of the metapelites, garnet crystals have cores formed via a dehydration reaction, which had taken place at silica-saturated microdomains and mantle to rim areas formed via a dehydration reaction at silica-deficient microdomains. In contrast, some other garnets in the same rock cores had formed via a dehydration reaction which occurred at silica-deficient microdomains while mantle to rim areas formed via a dehydration reaction at silica-saturated microdomains. Based on the textural observations, we conclude that the studied garnets have grown across different effective bulk compositional microdomains during the prograde evolution. These microdomains could represent heterogeneous compositional layers (paleobedding/laminations) in the precursor sediments or differentiated crenulation cleavages that existed during prograde metamorphism. UHT metamorphism associated with strong ductile deformation, metamorphic differentiation and crystallization of locally produced melt may have obliterated the evidence for such microdomains in the matrix. The lack of significant compositional zoning in garnet probably due to self-diffusion during UHT metamorphism had left mineral inclusions as the sole evidence for earlier microdomains with contrasting chemistry.     

Reproductive biology of Spondias tuberosa Arruda (Anacardiaceae), an endemic fructiferous species of the caatinga (dry forest), under different management conditions in northeastern Brazil

In areas under different management conditions (management units, MUs) located either on a slope or at the base of a slope and either in a plantation or in a pasture, we compared the flower and fruit production, floral visitors, visitation rates and pre-emergent reproductive success (PERS) of Spondias tuberosa (Anacardiaceae) in an area of dry forest in NE Brazil. Individuals in the plantation MU produced more flowers per inflorescence than those in other MUs, but there were no statistical differences in mean fruit set among MUs. The only difference in mean visitation rates was between the plantation (65.83 ± 38.49) and the slope sites (11.5 ± 12.8). We observed visits by 19 insect species, including bees (31.6%), butterflies (31.6%), wasps (26.3%) and flies (10.5%). A clustering analysis based on the number of visits showed that a) the plantation site is most different from the other MUs, b) the pasture and the site at the base of the slope are similar to the slope site, and c) the higher frequency of visits of pollinators in the plantation MU was responsible for these differences. Of the 19 species of insects visiting the flowers, 12 were considered pollinators. The pollinator similarity analysis indicated a clear separation between areas and suggested that human activity has resulted in the replacement of native pollinators by exotic species. However, these changes apparently have not affected the pre-emergent reproductive success of S. tuberosa. Our results show that plant reproductive biology in semi-arid ecosystems may be modified by human action and that changes in floral production and pollinator guilds are the most conspicuous effects. However, the traditional management performed by local people may not affect the reproductive success of plant species.     

The neotectonics and geodynamics of the Lower Oka Region (East European Craton)

The neotectonic structures of the Lower Oka (Nizhneokskii) Region formed under different geodynamic conditions. This is attested by the morphology, orientation, internal structure, and jointing of the structures. The Oka-Tsna arc formed under the effect of tension from an inner source on the one hand and stress from the Alpian belt on the other hand. The latitudinally-oriented structures of the northwestern slope of the Tokmovo arc emerged as a result of uplift and widening. Both types of structure are combined within the limits of the Oka-Murom trough, which is a geodynamically active zone.