Characterization of deep saline aquifers in the Bécancour area,St. Lawrence Lowlands,Québec,Canada: implications for CO2 geological storage

The present paper provides a case study of the assessment of the potential for CO₂ storage in the deep saline aquifers of the Bécancour region in southern Québec. This assessment was based on a hydrogeological and petrophysical characterization using existing and newly acquired core and well log data from hydrocarbon exploration wells. Analyses of data obtained from different sources provide a good understanding of the reservoir hydrogeology and petrophysics. Profiles of formation pressure, temperature, density, viscosity, porosity, permeability, and net pay were established for Lower Paleozoic sedimentary aquifers. Lateral hydraulic continuity is dominant at the regional scale, whereas vertical discontinuities are apparent for most physical and chemical properties. The Covey Hill sandstone appears as the most suitable saline aquifer for CO₂ injection/storage. This unit is found at a depth of more than 1 km and has the following properties: fluid pressures exceed 14 MPa, temperature is above 35 °C, salinity is about 108,500 mg/l, matrix permeability is in the order of 3 × 10^?16 m² (0.3 mDarcy) with expected higher values of formation-scale permeability due to the presence of natural fractures, mean porosity is 6 %, net pay reaches 282 m, available pore volume per surface area is 17 m³/m², rock compressibility is 2 × 10^?9 Pa^?1 and capillary displacement pressure of brine by CO₂ is about 0.4 MPa. While the containment for CO₂ storage in the Bécancour saline aquifers can be ensured by appropriate reservoir characteristics, the injectivity of CO₂ and the storage capacity could be limiting factors due to the overall low permeability of aquifers. This characterization offers a solid basis for the subsequent development of a numerical hydrogeological model, which will be used for CO₂ injection capacity estimation, CO₂ injection scenarios and risk assessment.     

Assessing the effectiveness of non-structural flood management measures in the Thames Estuary under conditions of socio-economic and environmental change

Risk analysis and appraisal of the benefits of structural flood risk management measures such as embankments is well established. Here, a method to quantify, over extended timescales, the effectiveness of non-structural measures such as land use spatial planning, insurance and flood resilient construction is presented. The integrated approach couples socio-economic and climate change scenarios with long term land use modelling and flood risk analysis to generate maps and time series of expected annual damages. The analysis has been applied on a case study in the Thames Estuary in the UK. Stakeholders helped develop a number of scenarios that might lead to substantial changes in existing planning and insurance policies in the UK. The effectiveness of these changes was analysed and showed the substantial benefits in terms of reduction of future flood risks that are achievable with changes in planning policy, financial incentives and resilient property construction in the floodplain. Moreover, the reward can be increased through earlier action. Subsequently, the benefits of a range of policies are explored under the UK Foresight socio-economic scenarios. Different structural and non structural flood management interventions are tested and the results demonstrate that despite the potential for large increases in flood risk in the Thames Estuary, in all scenarios substantial flood risk reductions are possible. The effectiveness of non-structural measures is however sensitive to socio-economic changes and governance arrangements. The analysis described here will help to identify portfolios of non-structural and structural options that are robust to uncertainties.     

Field-Scale Evaluation of Bioaugmentation Dosage for Treating Chlorinated Ethenes

A field demonstration was performed to evaluate the impacts of bioaugmentation dosage for treatment of chlorinated ethenes in a sandy-to-silty shallow aquifer. Specifically, bioaugmentation using a commercially available Dehalococcoides (DHC)-containing culture was performed in three separate groundwater recirculation loops, with one loop bioaugmented with 3.9 × 10¹¹ DHC, the second loop bioaugmented with 3.9 × 10¹² DHC, and the third loop bioaugmented with 3.9 × 10¹³ DHC. Groundwater monitoring was performed to evaluate DHC growth and migration, dechlorination rates, and aquifer geochemistry. The loop inoculated with 3.9 × 10¹² DHC showed slower dechlorination rates and DHC migration/growth compared with the other loops. This relatively poor performance was attributed to low pH conditions. Results for the loops inoculated with 3.9 × 10¹¹ and 3.9 × 10¹³ DHC showed similar timeframes for dechlorination, as evaluated at a monitoring well approximately 10 feet downgradient of the DHC injection well. Application of a recently developed one-dimensional bioaugmentation fate and transport screening model provided a reasonable prediction of the data in these two loops. Overall, these results suggest that increasing bioaugmentation dosage does not necessarily result in decreased dechlorination timeframes in the field. The ability to predict results suggests that modeling potentially can serve as an effective tool for determining bioaugmentation dosage and predicting overall remedial timeframes.     

Including spatial distribution in a data‐driven rainfall‐runoff model to improve reservoir inflow forecasting in Taiwan

Multi‐step ahead inflow forecasting has a critical role to play in reservoir operation and management in Taiwan during typhoons as statutory legislation requires a minimum of 3‐h warning to be issued before any reservoir releases are made. However, the complex spatial and temporal heterogeneity of typhoon rainfall, coupled with a remote and mountainous physiographic context, makes the development of real‐time rainfall‐runoff models that can accurately predict reservoir inflow several hours ahead of time challenging. Consequently, there is an urgent, operational requirement for models that can enhance reservoir inflow prediction at forecast horizons of more than 3 h. In this paper, we develop a novel semi‐distributed, data‐driven, rainfall‐runoff model for the Shihmen catchment, north Taiwan. A suite of Adaptive Network‐based Fuzzy Inference System solutions is created using various combinations of autoregressive, spatially lumped radar and point‐based rain gauge predictors. Different levels of spatially aggregated radar‐derived rainfall data are used to generate 4, 8 and 12 sub‐catchment input drivers. In general, the semi‐distributed radar rainfall models outperform their less complex counterparts in predictions of reservoir inflow at lead times greater than 3 h. Performance is found to be optimal when spatial aggregation is restricted to four sub‐catchments, with up to 30% improvements in the performance over lumped and point‐based models being evident at 5‐h lead times. The potential benefits of applying semi‐distributed, data‐driven models in reservoir inflow modelling specifically, and hydrological modelling more generally, are thus demonstrated. Copyright © 2012 John Wiley & Sons, Ltd.     

Evolution of the Kivu Rift,East Africa: interplay among tectonics,sedimentation and magmatism

The seismically and volcanically active Kivu Rift, in the western branch of the East African Rift System, is a type locale for studies of high‐elevation, humid‐climate rift basins, as well as magmatic basin development. Interpretations of offshore multi‐channel seismic (MCS) reflection data, terrestrial radar topography, lake bathymetry and seismicity data recorded on a temporary array provide new insights into the structure, stratigraphy and evolution of the Kivu rift. The Kivu rift is an asymmetric graben controlled on its west side by a ca. 110 km‐long, N‐S striking border fault. The southern basins of the lake and the upper Rusizi river basin are an accommodation zone effectively linking 1470 m‐high Lake Kivu to 770 m‐high Lake Tanganyika. MCS data in the eastern Kivu lake basin reveal a west‐dipping half graben with at least 1.5 km of sedimentary section; most of the ca. 2 km of extension in this sub‐basin is accommodated by the east‐dipping Iwawa normal fault, which bounds an intrabasinal horst. Lake Kivu experienced at least three periods of near desiccation. The two most recent of these approximately correlate to the African Megadrought and Last Glacial Maximum. There was a rapid lake level transgression of at least 400 m in the early Holocene. The line load of the Virunga volcanic chain enhances the fault‐controlled basin subsidence; simple elastic plate models suggest that the line load of the Virunga volcanic chain depresses the basin by more than 1 km, reduces flank uplift locally and broadens the depocentre. Not only do the voluminous magmatism and degassing to the lake pose a hazard to the riparian population, but our studies demonstrate that magmatism has important implications for short‐term processes such as lake levels, inflow and outlets, as well as long term modification of classic half‐graben basin morphology.     

Stable isotope evidence for the atmospheric origin of CO2 involved in carbonation of MSWI bottom ash

Stable isotopes were used to constrain the origin of CO₂ involved in the ageing process of municipal solid waste incineration (MSWI) bottom ash under open-air conditions. The δ¹³C and δ¹⁸O values of CaCO₃ occurring in MSWI bottom ash samples of variable age and the δ¹³C of the residual organic matter content were measured, and laboratory assessments made of the isotopic fractionation accompanying CaCO₃ neo-formation during accelerated carbonation experiments of bottom ash or pure lime with atmospheric or industrial CO₂. The results indicate that stable isotopic compositions exhibited by fresh and aged bottom ash samples reflect non-equilibrium processes resembling those described in the carbonation of concrete and mortar. They also lead to conclusions on the prevalent involvement of atmospheric CO₂ in the open-air carbonation of MSWI bottom ash.     

Isotope Constraints on the Aquatic Carbon Budget: Langat Watershed,Malaysia

Langat River drains a tropical watershed in the southwest of the Malaysian Peninsula. The watershed is heavily urbanized in its downstream portion. Water samples were collected from May 2010 to December 2011, at three localities along the main stem river, 1 location at its Semenyih tributary and from an upstream groundwater source. Concentration and δ¹³C data of riverine DIC and DOC indicate the dominance of C3 plant-derived material as the primary source of carbon, with δ¹³C_DIC values enriched in ¹³C relative to that of the C3 source. This enrichment is likely due to CO₂ outgassing, as calculated concentrations of riverine CO₂ are significantly higher than ambient atmospheric values, with methanogenic activity a theoretically possible contributing factor, particularly at the upstream location. The Langat River therefore acts as a net source of CO₂, with a total sub-basin flux of 19.7 × 10³ t C year^?1. This is comparable to the sum of riverine DOC, DIC and POC loss rates from the sub-basin, calculated as 24.5 × 10³ t C year^?1, and highlights the significance of CO₂ evasion from water bodies to the atmosphere for balancing the budget of the terrestrial carbon cycle. The DIC and DOC concentration and δ¹³C data also suggests that in the more urbanized downriver areas, much of the organic carbon input may be anthropogenicaly derived due to ubiquity of sewage treatment plants and landfill sites. Such human-induced perturbations to riverine carbon cycling should be taken into account in future studies of urbanized watersheds.     

Geochemistry of the Adamello massif (northern Italy)

The Tertiary Adamello massif, outcropping over an area of more than 550 km² in the southern Alps (northern Italy) is composed mainly of granitoid rocks (granodiorite, tonalite, quartz diorite) with minor amounts of diorite and gabbro. The major and trace element composition of these rocks is comparable to calc-alkaline volcanic rocks of continental margins. The granitoid rocks display spatial and temporal variations in their composition, particularly in Na, P, Sr, La, Nb and Y contents and ⁸⁷Sr/⁸⁶Sr ratios. The variations were probably produced by concurrent contamination/wall-rock assimilation and fractional crystallization of high-alumina basaltic magma.     

Radiometric characteristics of heavy mineral deposits along the west coast of South Africa

During the last decade, exploration and mining of modern-Tertiary heavy mineral beach and raised beach sands along the west coast of South Africa has developed into a major industry. High resolution radiometric techniques have demonstrated their use as a quantitative indicator of total heavy mineral concentration (THM) and also have the ability to discriminate between sediments derived from different provenance terrains. Results indicate that it is possible to calculate the total heavy mineral concentration from high resolution radiometric measurements, but the ability to quantify the concentration of individual mineral fractions, such as ilmenite, requires further refinement of the method. Radiometric characteristics of the light mineral fraction made it possible to distinguish between sediments from mixed marine-aeolian palaeoplacers and active present beach placers. The effects of in situ alteration of the ilmenite fraction in the palaeoplacers were also reflected by subtle contrasts in the radiometric character of the deposits. Furthermore, the uniform radiometric character of the sample population indicates a common provenance for the heavy mineral suite and supports previous results which indicate the metamorphites of the mid-Proterozoic Namaqua Province as the primary source terrain. The high resolution radiometric techniques discussed offer a broad spectrum of applications in sedimentology and have the potential to aid heavy mineral exploration. With further refinement it can possibly be used quantitatively in grade control during mining and beneficiation of heavy mineral deposits. Received: 19 July 1996 / Accepted: 7 January 1997