Assessing selected natural and anthropogenic impacts on freshwater lens morphology on small barrier Islands: Dog Island and St. George Island, Florida, USA

Abstract The freshwater lens morphologies of the barrier islands Dog Island and St. George Island on the panhandle coast of Florida (FL), USA, are controlled to varying degrees by both natural and anthropogenic factors. Variable-density groundwater flow models confirm that spatial variability of recharge values can account for the observed lens asymmetry on these islands. The depth to the base of the lens does not vary significantly seasonally. Human development has altered recharge patterns in some areas, locally thinning the freshwater lens. Aqueduct water supply to St. George Island represents 7–25% of natural recharge; higher recharge rates are required to simulate the lens on St. George Island than on Dog Island. On both islands, coastal erosion rates are sufficiently rapid that the freshwater lens may not be in equilibrium with current boundary conditions.

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Resumen Las morfologías de los lentes de agua dulce en las islas de barrera: Islas Dog y St. George, en la costa alargada y estrecha de Florida, EUA, están controladas en diferentes grados por factores antropogénicos y naturales. Los modelos de flujo con densidad variable del agua subterránea, confirman que la variabilidad espacial de los valores de recarga, pueden ser la causa de la asimetría observada en los lentes de estas islas. La profundidad hasta la base de los lentes no varía significativamente con las estaciones climáticas. El desarrollo humano ha alterado las tendencias de recarga en algunas áreas, causando adelgazamiento local de los lentes de agua dulce. El abastecimiento de agua del acueducto en la Isla St. George, representa entre 7% y 25% de la recarga natural; por otro lado se necesitan cantidades mayores de recarga para simular los lentes en la Isla St. George que en la Isla Dog. En ambas islas, las tasas de erosión costera son tan rápidas, que las lentes de agua dulce podrían no estar en equilibrio con las condiciones actuales de frontera.

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Résumé La morphologie des lentilles deau douce des îles de Dog et de St. George, situés dans le district côtier de Florida-Etats Unis est contrôlé dans une mesure variable par des facteurs naturelles et humaines. Les modèles découlement à densité variable des eaux souterraines confirment que la variation spatiale de la recharge peut expliquer les asymétries observées des lentilles des cettes îles. La profondeur des lentilles ne présente pas des variations saisonnières importantes. Les activités humaines ont modifié la recharge dans certaines zones en amincissant localement les lentilles deau douce. Lalimentation en eaux de lîle de St. George représente 7–25% de la recharge naturelle; pour simuler les lentilles de lîle de Dog il a été nécessaire dintroduire des valeurs plus élevées de la recharge par rapport aux ceux utilisés pour lîle de St. George. Pour les deux îles lérosion côtière est assez rapide ainsi que les lentilles de eau douce ne sont pas en équilibre avec les conditions à la frontière.

     

Mechanisms of orthopyroxene dissolution in silica-undersaturated melts at 1 atmosphere and implications for the origin of silica-rich glass in mantle xenoliths

Experiments dissolving orthopyroxene (En₉₃) in a variety of Si-undersaturated alkaline melts at 1 atmosphere and variable f _O2 demonstrate that orthopyroxene dissolves to form olivine, Si-rich melt and clinopyroxene. These phases form a texturally and chemically distinct boundary layer around the partly dissolved orthopyroxene crystals. The occurrence of clinopyroxene in the boundary layer is due to inward diffusion of Ca from the solvent melt to the boundary layer causing clinopyroxene saturation. Compositional profiles through the solvent and the boundary layer for a number of experiments demonstrate rapid diffusion of cations across the boundary layer – solvent interface. SiO₂ diffuses outward from the boundary layer whereas CaO and Al₂O₃ diffuse toward the Si-enriched boundary layer melt. The rate of Al diffusion is slower under reducing conditions compared to the rates in experiments performed in air. Concentrations of FeO and MgO in the boundary layer and solvent are approximately equal indicating rapid diffusion and attainment of equilibrium despite ongoing crystallisation of clinopyroxene within the boundary layer. The behaviour of Na₂O and K₂O is strongly affected by f _O2. Under reducing conditions Na₂O and K₂O concentrations are approximately equal in the boundary layer and solvent indicating normal diffusion down the concentration gradient and attainment of equilibrium. Under oxidising conditions, K₂O and to a lesser extent Na₂O, have compositional profiles indicative of uphill diffusion likely due to their preference for more polymerised Si- and Al-rich melts. Under reduced conditions Al-enrichment in the boundary layer melt is not as extreme and uphill diffusion did not occur. The composition of the solvent melt after the experiments indicates that it was contaminated by the boundary layer by convective mixing due to the onset of hydrodynamic instabilities brought on by density and viscosity contrasts between the two melts. Despite using a wide variety of solvent melt compositions we find that the boundary layer melts converge toward a common composition at high SiO₂ contents. The composition of glass generated by orthopyroxene dissolution at 1 atmosphere is similar in many respects to Si-rich glass found in many orthopyroxene-rich mantle xenoliths that have been attributed to high pressure in situ processes including mantle metasomatism. The results of this study suggest that at least some Si-rich melts are likely to have formed by dissolution of xenolith orthopyroxene at low pressure possibly by their Si-undersaturated host magmas. Received: 30 August 1996 / Accepted: 15 April 1998     

The lunar geochemistry of chromium and vanadium

Crystal/liquid partition coefficients for Cr, V, Mn, and Fe have been determined experimentally between olivine, orthopyroxene, clinopyroxene and silicate melt possesing the composition of a primitive lunar green glass, at oxygen fugacities appropriate to the lunar interior. These species all behave essentially as compatible elements and possess crystal/liquid partition coefficients mostly between 0.3 and 0.9. Partition coefficients for Cr, V, and Mn are generally similar to those of Fe. This implies that crystal/liquid fractionation processes in the lunar interior which do not involve the participation of spinels would not have been effective in fractionating MnO, CrO, and VO from FeO. The well-known constancy of FeO/MnO ratios in nearly all lunar rocks is a reflection of this behaviour. It is shown that comparably strong correlations between CrO-;FeO and VO-;FeO exist for lunar highland breccias and soils from all sites and that these correlations extend to primitive lunar volcanic glasses associated with mare volcanism, strongly suggesting that the CrO/FeO and VO/FeO ratios so derived are of global importance. The observed ratios characterizing differentiated regions of the Moon can be combined with the corresponding ratios for residual refractory portions of the Moon, using measured partition coefficients for Fe, Mg, Cr, V, and Mn between olivine, orthopyroxene and liquid. Bulk Moon abundances for Cr and V have been calculated for a range of reasonable assumptions concerning the petrogenetic relationships between differentiated portions of the Moon and complementary refractory residua consisting of olivine and orthopyroxene mineralogies. Because of the small differences in crystal liquid partition coefficients between FeO, CrO, and VO, these estimates are insensitive to large variations in the models. The bulk Moon is accordingly estimated to contain 2190–2463 ppm Cr and 79–95 ppm V. These values are very similar to the Cr and V contents of the Earth's mantle, estimated as 3010 ppm Cr and 81 ppm V by Sun (1982). The geochemical implications of these similarities are discussed.     

Catchment precipitation processes in the San Francisco valley in southern Ecuador: combined approach using high-resolution radar images and in situ observations

The precise estimation of precipitation quantities in tropical mountain regions is in great demand by ecological and hydrological studies, due to the heterogeneity of the rainfall distribution and the lack of meteorological station data. This study uses radar images and ground station data to provide the required high-resolution precipitation maps. Also wind data are taken into account, due to its influence on the precipitation formation and to demonstrate the relation between synoptic wind, topography and the precipitation distribution inside small mountain valleys. The study analyses the rainfall distribution and amounts of 4 days inside the San Francisco Valley, a small catchment in the tropical Andes of southern Ecuador, representing different seasons and the typical atmospheric flows, which are correlated to the annual precipitation map. The results show that the rainfall distribution and amounts are generally defined by the wind direction and velocity, besides the topographic location in relation to the main barriers and pathways. The dominant wind direction causes a division of the catchment in a wetter eastern and a dryer western part. Moreover, the annual seasons are reversed; the main rainy season for the eastern part occurs between June and August, while the western part reaches the precipitation maximum between January and March. This may have influence on the species composition at the different slopes and the annual hydrological cycle inside the catchment.     

Book review

The behavior and natural history of the Caribbean reef squid Sepioteuthis sepioidea. By Martin Moynihan and Arcadio F. Rodaniche, 1982. Advances in Ethology, No. 25. Berlin and Hamburg, Verlag Paul Parey. 150 p., 42 figures, 9 tables. ISBN 3 ‐ 489 ‐ 61936 ‐ 6 (soft cover). Price DM 48, approximately US$21.60.     

Regolith Surface Reflectance: A New Attempt to Model

The reflectance coefficient of the regolith layer of celestial bodies has been studied in relation to the physical properties of regolith particles (size, refractive index, and packing density) on the basis of an accurate numerical radiative-transfer algorithm for a semi-infinite flat layer. Using the geometric-optics approximation, we have found that a shape mixture of randomly oriented spheroids can successfully model the single-scattering phase function of independent soil grains. In order to take into account the effect of packing density in a regolith layer, the concept of the so-called static structure factor was used. The main effect of increasing packing density is to suppress the forward-scattering peak of the phase function and to increase the albedo of the reflecting surface. We also investigated the influence of fine dust on the reflected light. An addition of small particles not only increases the surface albedo, but also changes the brightness profile and enhances the backscattering. Although the problem of unique solution, which is inherent in the retrieval of the properties of a medium from the measurements of the intensity of light scattered by this media, cannot be removed in the proposed model, the procedure used here, in contrast to widely used approximations, allows us to fit observational data with a set of real characteristics of the regolith. Semiempirical approaches are able to fit the measurements well with a small number of free parameters, but they do not explicitly contain crucial physical characteristics of the regolith such as grain sizes or the refractive index. We compared the numerical solution of the radiative-transfer equation with the Hapke approximation, which is most often used by investigators. The errors introduced by the Hapke model are small only for near-isotropic scattering by isolated particles. However, independent regolith grains are known to scatter light mainly in the forward direction.     

Some observations on the geochemistry of gold mineralization in the weathered zone at Norseman, Western Australia

At Norseman Au mineralization is hosted by parallel easterly dipping quartz reefs in a westerly dipping sequence of Archaean basaltic flows and As is strongly correlated with this mineralization. Near-surface exploration is hampered by an extensive cover of deeply weathered soils and a veneer of silty calcareous material, probably of aeolian origin, which, because of its low Fe content of < 5%, has a very low (< 10 ppm) and often indiscernible As signature over mineralization. At a test traverse over the southern end of the Mararoa quartz reef, drill sampling to 10 m depth in highly weathered in situ material beneath the calcareous veneer produced As anomalies which are strongly correlated with the extrapolation to surface of a shear zone hosting Au mineralization which is probably blind. The As anomalies can be extended into the surface horizon by manipulating the data to compensate for the low Fe content of the calcareous layer.The Au values in the drill samples were very low and poorly correlated with the extrapolation to surface of the Mararoa shear. However, the absence of a Au halo (at a 10 ppb detection limit) may be due to the shear being barren near surface, or may be due to the samples being taken from the strongly leached zones of a laterite profile. In the area of the test traverse at the southern Mararoa area, the upper horizons of the original laterite profile have been eroded away and the remaining horizons covered by a veneer of calcareous material. There is a better correlation of the Au values of the shallow drill samples with the projection to surface of a porphyry, which hosts minor low-grade Au mineralization.The results for Au dispersion around the Mararoa shear contrast with dispersion at the nearby Hinemoa Mine where gold mineralization crops out. Channel sampling in costeans showed that an Au anomaly (threshold 40 ppb) extends 50 to 150 m into oxidized wall rocks. This well defined halo may be due to the secondary dispersion of Au from the quartz reef into the ferruginous zone of the laterite profile.Gold in the leaves and twigs of Melaleuca pauperiflora F. Muell. from the traverse at the southern end of the Mararoa shear was determined by neutron activation analysis and found to be broadly correlated with the projected Au mineralization. However, the lack of correlation with the soil Au values to 10 m may be due to the plants taking up most of their water from below the depth of sampling.     

Could baseline establishment be counterproductive for emissions reduction? Insights from Vietnam’s building sector

This article provides insights into the role of institutions involved in climate governance working towards a future low-carbon society at the national level, within the global climate change governance architecture. Specifically, it contributes to understanding the fragmented governance of energy efficiency policy in developing countries by focussing on Vietnam’s building sector, identifying key institutions related to underlying discourses, national and international power relations, resource distribution and coalitions. It uses the case of baseline setting in developing Nationally Appropriate Mitigation Actions (NAMAs) to illustrate institutional dynamics, nationally and transnationally, as well as to question whether demands for baseline setting achieve the ideal trade-off between actual GHG emissions reduction and institutionalized demands for accountability. The analysis reveals that, in addition to domestic efforts and challenges, the international agenda greatly influences the energy efficiency policy arena. The article presents lessons to be learnt about policy processes from the specific Vietnamese case, reflecting on the role of international actors and discourses in it. Finally, it argues for the abolition of baselines in favour of adequate monitoring and evaluation, from the perspective that requirement for deviation from fictitious baselines is unproductive and only serves an international techno-managerial discourse.

POLICY RELEVANCE

Baseline establishment is commonly considered an initial step in developing NAMAs, in order to facilitate the demonstration of a deviation from such baselines. The requirement to produce baselines is traditionally not questioned by policy practitioners. Thus, significant development resources are allocated to the establishment of baselines and the bridging of data gaps, often without consideration as to whether baselines are a necessary instrument for NAMA implementation. We suggest omitting the lengthy and resource-consuming practice of establishing baselines and recommend proceeding forthwith to the planning and implementation of mitigation and energy efficiency policies. As conditions vary significantly in different contexts, it would be more appropriate to measure the initial situation, establishing the ‘base point’, and monitor development from that point. The present article might serve as motivation for policymakers to question traditional approaches to policy development and consider alternatives to maximize the cost efficacy of NAMA programmes and facilitate their implementation.     

Pulsar Wind Nebulae in Egret Error Boxes

A remarkable number of pulsar wind nebulae (PWN) are coincident with EGRET γ-ray sources. X-ray and radio imaging studies of unidentified EGRET sources have resulted in the discovery of at least six new pulsar wind nebulae (PWN). Stationary PWN (SPWN) appear to be associated with steady EGRET sources with hard spectra, typical for γ-ray pulsars. Their toroidal morphologies can help determine the geometry of the pulsar which is useful for constraining models of pulsed γ-ray emission. Rapidly moving PWN (RPWN) with more cometary morphologies seem to be associated with variable EGRET sources in regions where the ambient medium is dense compared to what is typical for the ISM.